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    • 2. 发明授权
    • Method for preparing cerium carbonate powder using urea
    • 使用尿素制备碳酸铈粉末的方法
    • US08303918B2
    • 2012-11-06
    • US12531452
    • 2008-03-14
    • Myoung-Hwan OhSeung-Beom ChoJun-Seok NhoJong-Pil KimJang-Yul KimDong-Mok Shin
    • Myoung-Hwan OhSeung-Beom ChoJun-Seok NhoJong-Pil KimJang-Yul KimDong-Mok Shin
    • C01F17/00C09K3/14
    • C01F17/005C01P2002/72
    • In a method for preparing cerium carbonate powder by mixing a cerium precursor solution with a urea solution and carrying out a precipitation reaction, wherein the cerium carbonate powder has a hexagonal crystal structure, by using at least one type of organic solvent as a solvent for either or both the cerium precursor solution and the urea solution, and adjusting temperature of the precipitation reaction within a range of 120° C. to 300° C. Also, the method can yield cerium carbonate powder, cerium oxide powder from the cerium carbonate powder, and CMP slurry including the cerium oxide powder as an abrasive. In the method, urea as a precipitant can improve the uniformity of a reaction, and thus it is possible to easily and inexpensively obtain cerium carbonate powder with a hexagonal crystal structure without the danger by high-temperature high-pressure and the need for an expensive system in hydrothermal synthesis.
    • 在通过将铈前体溶液与尿素溶液混合并进行沉淀反应制备碳酸铈粉末的方法中,其中所述碳酸铈粉末具有六方晶系结构,通过使用至少一种有机溶剂作为溶剂用于任一种 或铈前体溶液和尿素溶液两者,并将沉淀反应的温度调节在120℃至300℃的范围内。此外,该方法可以从碳酸铈粉末中得到碳酸铈粉末,氧化铈粉末, 和包括氧化铈粉末作为研磨剂的CMP浆料。 在该方法中,作为沉淀剂的尿素可以提高反应的均匀性,因此可以容易且廉价地获得六方晶系结构的碳酸铈粉末,而不会受到高温高压的危险,并且需要昂贵的 水热合成系统。
    • 4. 发明授权
    • Method for preparing cerium carbonate powder
    • 碳酸铈粉末的制备方法
    • US07976810B2
    • 2011-07-12
    • US12531450
    • 2008-03-14
    • Myoung-Hwan OhSeung-Beom ChoJun-Seok NhoJong-Pil KimJang-Yul Kim
    • Myoung-Hwan OhSeung-Beom ChoJun-Seok NhoJong-Pil KimJang-Yul Kim
    • C01B31/24
    • C01F17/0043C01F17/005C01P2002/72C01P2002/76C09K3/1409C09K3/1463
    • In a method for preparing cerium carbonate powder by mixing a cerium precursor solution with a carbonate precursor solution and carrying out a precipitation reaction, wherein cerium carbonate is controlled to have an orthorhombic crystal structure, a hexagonal crystal structure or an orthorhombic/hexagonal mixed crystal structure, by using at least one type of organic solvent comprising at least two hydroxyl groups (OH) in molecular formula as a solvent for either or both the cerium precursor solution and the carbonate precursor solution, and varying a number of carbons or hydroxyl groups (OH) included in the molecular formula of the organic solvent. The method can easily and inexpensively obtain cerium carbonate powder with a desired crystal structure without the danger by high-temperature high-pressure and the need for an expensive system in hydrothermal synthesis.
    • 在通过将铈前体溶液与碳酸酯前体溶液混合并进行沉淀反应制备碳酸铈粉末的方法中,其中将碳酸铈控制为具有正交晶体结构,六方晶系结构或正交/六方晶系混合晶体结构 通过使用包含分子式中的至少两个羟基(OH)的至少一种类型的有机溶剂作为铈前体溶液和碳酸酯前体溶液中的任一种或两者的溶剂,并且改变多个碳或羟基(OH )包括在有机溶剂的分子式中。 该方法可以容易且廉价地获得具有所需晶体结构的碳酸铈粉末,而没有高温高压的危险和需要昂贵的水热合成系统。