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1. 发明授权

US07816559B2 Method of producing unsaturated acid from olefin 有权
标题翻译：从烯烃生产不饱和酸的方法
公开(公告)号：US07816559B2
公开(公告)日：2010-10-19
申请号：US11378438
申请日：2006-03-17
申请人： Boo Gon Woo , Jun Seok Ko , Kyoung Su Ha , Seong Pil Kang , Seok Hwan Choi , Young Bae Kim
发明人： Boo Gon Woo , Jun Seok Ko , Kyoung Su Ha , Seong Pil Kang , Seok Hwan Choi , Young Bae Kim
IPC分类号： C07C51/16
CPC分类号： B01J8/067 , B01J2208/00212 , B01J2208/025 , C07C51/215 , C07C51/252 , C07C57/04
摘要： Disclosed is a shell-and-tube heat exchanger type reactor that can be used for a process of producing unsaturated acids from olefins via fixed-bed catalytic partial oxidation, which comprises at least one reaction tube, each including at least one first-step catalyst layer, in which olefins are oxidized by a first-step catalyst to mainly produce unsaturated aldehydes, and at least two second-step catalyst layers, in which the unsaturated aldehydes are oxidized by a second-step catalyst to produce unsaturated acids, wherein a first catalyst layer of the second-step catalyst layers, disposed right adjacent to the first-step catalyst layer, has an activity corresponding to 5˜30% of the activity of the catalyst layer having a highest activity among the second-step catalyst layers. A method of producing unsaturated acids from olefins by using the reactor is also disclosed.
摘要翻译：公开了一种壳管式热交换器型反应器，其可用于通过固定床催化部分氧化由烯烃生产不饱和酸的方法，其包括至少一个反应管，每个反应管包含至少一个第一步催化剂层，其中烯烃被第一步催化剂氧化以主要产生不饱和醛，以及至少两个第二步催化剂层，其中不饱和醛被第二步催化剂氧化以产生不饱和酸，其中第一与第一级催化剂层相邻设置的第二级催化剂层的催化剂层的活性相当于第二级催化剂层中活性最高的催化剂层的活性的5〜30％的活性。还公开了通过使用反应器由烯烃生产不饱和酸的方法。

2. 发明授权

US07262324B2 Method of producing unsaturated acid in fixed-bed catalytic partial oxidation reactor with enhanced heat control system 有权
标题翻译：固定床催化部分氧化反应器生产不饱和酸的方法，采用增强型热控系统
公开(公告)号：US07262324B2
公开(公告)日：2007-08-28
申请号：US11019363
申请日：2004-12-23
申请人： Kyoung Su Ha , Geon Yong Kim , Seong Pil Kang , Boo Gon Woo
发明人： Kyoung Su Ha , Geon Yong Kim , Seong Pil Kang , Boo Gon Woo
IPC分类号： C07C51/16 , B01J8/04
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： The present invention provides a process of producing unsaturated acids from unsaturated aldehydes by fixed-bed catalytic partial oxidation in a shell-and-tube heat exchanger-type reactor, as well as a shell-and-tube heat exchanger-type reactor for use in the process. In the invention, second-stage reaction zone of mainly producing unsaturated acids by the catalytic vapor phase oxidation of an unsaturated aldehyde-containing gas mixture produced in a first-stage reaction zone with molecular oxygen is divided into two or more shell spaces by at least one partition. Each of the divided shell spaces is filled with a heat transfer medium, and the heat transfer medium in each shell space is maintained at isothermal temperature or a temperature difference of 0-5° C. Also, in order to protect catalyst layers from a highly exothermic reaction, the process is performed at a limited temperature difference between the temperature at a hot spot and the temperature of the heat transfer medium. Also, in order to facilitate the removal of heat generation at a location where the partition is placed, a reaction inhibition layer is disposed in that location. The improved heat control system for reactors provided according to the present invention can secure the heat stability of the catalyst layer, reduce the amount of byproducts, and increase the yield of a final product.
摘要翻译：本发明提供了一种在壳管式热交换器型反应器中通过固定床催化部分氧化由不饱和醛生成不饱和酸的方法，以及用于在管式热交换器型反应器中使用的管壳式热交换器型反应器的过程。在本发明中，通过在分子氧的第一阶段反应区中产生的不饱和醛的气体混合物的催化气相氧化主要生成不饱和酸的第二阶段反应区至少分成两个或更多个壳层空间一个分区。每个分开的壳体空间填充有传热介质，并且每个壳体空间中的传热介质保持在等温温度或0-5℃的温差。此外，为了保护催化剂层免受高温放热反应，该过程在热点温度与传热介质的温度之间的有限温度差下进行。此外，为了便于在隔离物的位置除去发热，在该位置设置反应抑制层。根据本发明提供的用于反应器的改进的热控制系统可以确保催化剂层的热稳定性，减少副产物的量，并且提高最终产品的产率。

3. 发明授权

US07073519B2 Facility parts cleaning solution for processing of (meth)acrylic acid and/or (meth)acrylic esters and cleaning method using said cleaning solution 有权
标题翻译：用于加工（甲基）丙烯酸和/或（甲基）丙烯酸酯的设备部件清洁溶液和使用所述清洁溶液的清洁方法
公开(公告)号：US07073519B2
公开(公告)日：2006-07-11
申请号：US11131264
申请日：2005-05-18
申请人： Seok-Hwan Choi , Seong-Pil Kang , Kyoung-Su Ha , Geon-Yong Kim , Boo-Gon Woo
发明人： Seok-Hwan Choi , Seong-Pil Kang , Kyoung-Su Ha , Geon-Yong Kim , Boo-Gon Woo
IPC分类号： B08B3/04 , B08B9/027 , C11D7/06 , C11D7/32
CPC分类号： C11D7/06 , C11D7/32 , C11D7/3245 , C11D7/3263 , C11D11/0041 , F28G9/00
摘要： The present invention relates to a facility parts cleaning solution for the processing of (meth)acrylic acid and/or (meth)acrylic esters and a cleaning method using the cleaning solution. An aqueous cleaning composition comprising 5 to 50 wt % of at least one alkali metal hydroxide selected from the group consisting of sodium hydroxide and potassium hydroxide, 0.01 to 1 wt % of a water-soluble amino acid, 0.001 to 0.05 wt % of N,N′-methylene bisacrylamide, and 0.001 to 0.05 wt % of azobisisobutyronitrile is used to clean facility parts for manufacturing (meth)acrylic acid and/or (meth)acrylic esters in order to easily remove polymers and deposits.
摘要翻译：本发明涉及用于处理（甲基）丙烯酸和/或（甲基）丙烯酸酯的设备部件清洗液和使用该清洗溶液的清洗方法。一种水性清洁组合物，其包含5至50重量％的至少一种选自氢氧化钠和氢氧化钾的碱金属氢氧化物，0.01至1重量％的水溶性氨基酸，0.001至0.05重量％的N， N'-亚甲基双丙烯酰胺和0.001〜0.05重量％的偶氮二异丁腈用于清洗用于制造（甲基）丙烯酸和/或（甲基）丙烯酸酯的设备部件，以便容易地除去聚合物和沉积物。

4. 发明授权

US08308913B2 Apparatus for recovering acrylic acid 有权
标题翻译：丙烯酸回收设备
公开(公告)号：US08308913B2
公开(公告)日：2012-11-13
申请号：US12565359
申请日：2009-09-23
申请人： Seong Pil Kang , Seok Kwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
发明人： Seong Pil Kang , Seok Kwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
IPC分类号： B01D1/22 , B01D3/10 , B01D3/28 , C07C51/44
CPC分类号： C07C51/44 , B01J2219/00006 , C07C51/487 , C07C57/04
摘要： Disclosed is an apparatus for recovering an acrylic acid from a mixture containing acrylic acid, acrylic acid dimer and impurities with high boiling point, including: an acrylic acid recovering device that comprises an acrylic acid distillation unit being present within an acrylic acid dimer pyrolysis tank, and is operated under reduced pressure; a separation column for removing impurities with high boiling point from the mixture which is introduced into the acrylic acid recovering device; and a line for introducing the mixture into the acrylic acid recovering device.
摘要翻译：公开了一种用于从含有丙烯酸，丙烯酸二聚体和高沸点杂质的混合物中回收丙烯酸的装置，包括：丙烯酸回收装置，其包含存在于丙烯酸二聚体热解罐内的丙烯酸蒸馏单元，并在减压下运行; 用于从引入丙烯酸回收装置的混合物中除去高沸点杂质的分离塔; 以及用于将混合物引入丙烯酸回收装置的管线。

5. 发明授权

US08142742B2 Method of producing unsaturated acid from olefin 有权
标题翻译：从烯烃生产不饱和酸的方法
公开(公告)号：US08142742B2
公开(公告)日：2012-03-27
申请号：US12884950
申请日：2010-09-17
申请人： Boo Gon Woo , Jun Seok Ko , Kyoung Su Ha , Seong Pil Kang , Seok Hwan Choi , Young Bae Kim
发明人： Boo Gon Woo , Jun Seok Ko , Kyoung Su Ha , Seong Pil Kang , Seok Hwan Choi , Young Bae Kim
IPC分类号： B01J8/06 , C07C57/02
CPC分类号： B01J8/067 , B01J2208/00212 , B01J2208/025 , C07C51/215 , C07C51/252 , C07C57/04
摘要： Disclosed is a shell-and-tube heat exchanger type reactor that can be used for a process of producing unsaturated acids from olefins via fixed-bed catalytic partial oxidation, which comprises at least one reaction tube, each including at least one first-step catalyst layer, in which olefins are oxidized by a first-step catalyst to mainly produce unsaturated aldehydes, and at least two second-step catalyst layers, in which the unsaturated aldehydes are oxidized by a second-step catalyst to produce unsaturated acids, wherein a first catalyst layer of the second-step catalyst layers, disposed right adjacent to the first-step catalyst layer, has an activity corresponding to 5˜30% of the activity of the catalyst layer having a highest activity among the second-step catalyst layers. A method of producing unsaturated acids from olefins by using the reactor is also disclosed.
摘要翻译：公开了一种壳管式热交换器型反应器，其可用于通过固定床催化部分氧化由烯烃生产不饱和酸的方法，其包括至少一个反应管，每个反应管包含至少一个第一步催化剂层，其中烯烃被第一步催化剂氧化以主要产生不饱和醛，以及至少两个第二步催化剂层，其中不饱和醛被第二步催化剂氧化以产生不饱和酸，其中第一与第一级催化剂层相邻设置的第二级催化剂层的催化剂层的活性相当于第二级催化剂层中活性最高的催化剂层的活性的5〜30％的活性。还公开了通过使用反应器由烯烃生产不饱和酸的方法。

6. 发明授权

US07612231B2 Method for recovering acrylic acid 有权
标题翻译：回收丙烯酸的方法
公开(公告)号：US07612231B2
公开(公告)日：2009-11-03
申请号：US11116367
申请日：2005-04-28
申请人： Seong Pil Kang , Seok Hwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
发明人： Seong Pil Kang , Seok Hwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
IPC分类号： C07C51/42
CPC分类号： C07C51/44 , B01J2219/00006 , C07C51/487 , C07C57/04
摘要： Disclosed is a simplified method for recovering acrylic acid from a mixture containing acrylic acid, acrylic acid dimer and impurities with high boiling point, in a stable and efficient manner. The method comprises the steps of: introducing the mixture into an acrylic acid recovering device comprising an acrylic distillation unit integrated with an acrylic acid dimer pyrolysis tank; carrying out decomposition of acrylic acid dimmer under reduced pressure and recovering acrylic acid. The method optionally further comprises a step of recycling a portion of the solution obtained from the bottom of the acrylic acid recovering device to the acrylic acid recovering device.
摘要翻译：公开了一种以稳定且有效的方式从含有丙烯酸，丙烯酸二聚物和高沸点杂质的混合物中回收丙烯酸的简化方法。该方法包括以下步骤：将混合物引入丙烯酸回收装置中，该装置包括与丙烯酸二聚物热解罐结合的丙烯酸蒸馏装置; 在减压下进行丙烯酸二聚体的分解并回收丙烯酸。所述方法还包括将从丙烯酸回收装置的底部获得的溶液的一部分再循环到丙烯酸回收装置的步骤。

7. 发明授权

US07591585B2 Temperature measuring device 有权
标题翻译：温度测量装置
公开(公告)号：US07591585B2
公开(公告)日：2009-09-22
申请号：US11453117
申请日：2006-06-14
申请人： Kyoung Su Ha , Boo Gon Woo , Jun Seok Ko , Seong Pil Kang , Seok Hwan Choi , Sang Youn Lee , Young Bae Kim
发明人： Kyoung Su Ha , Boo Gon Woo , Jun Seok Ko , Seong Pil Kang , Seok Hwan Choi , Sang Youn Lee , Young Bae Kim
IPC分类号： G01K1/14 , G01K13/00 , G01K7/02
CPC分类号： G01K3/14 , G01K1/14 , G01K7/02
摘要： Disclosed is a temperature measuring device. The temperature measuring device includes: a thermo-well tube; and a cable or wire type temperature measuring means which is installed in a thermo-well tube, wherein temperature measuring means has temperature detecting sensors disposed at an intermediate portion thereof, and the temperature detecting sensors can be moved axially in the thermo-well tube by applying tension to both ends of the cable or wire type temperature measuring means. The present invention also provides a reaction tube in which the temperature measuring device is disposed axially, and a reactor including at least one temperature measuring device or reaction tube as described above.
摘要翻译：公开了一种温度测量装置。所述温度测量装置包括：热井管; 以及安装在热井管中的电缆或线型温度测量装置，其中温度测量装置具有设置在其中间部分的温度检测传感器，并且温度检测传感器可以在热井管中轴向移动，对电缆或电线式温度测量装置的两端施加张力。本发明还提供一种反应管，其中温度测量装置轴向设置，反应器包括如上所述的至少一个温度测量装置或反应管。

8. 发明授权

US07517147B2 Device and method for measuring temperature in a tubular fixed-bed reactor 有权
标题翻译：用于测量管式固定床反应器中温度的装置和方法
公开(公告)号：US07517147B2
公开(公告)日：2009-04-14
申请号：US11562706
申请日：2006-11-22
申请人： Sung Soo Park , Kyoung Su Ha , Jun Seok Ko , Seong Pil Kang , Se Won Baek , Eun Ju Kim
发明人： Sung Soo Park , Kyoung Su Ha , Jun Seok Ko , Seong Pil Kang , Se Won Baek , Eun Ju Kim
IPC分类号： G01K1/14
CPC分类号： G01K1/146 , B01J8/008 , B01J8/06 , B01J2208/00061 , B01J2219/00009 , B01J2219/00011 , G01K13/10
摘要： Disclosed is a structure for guiding the installation of a thermowell for temperature sensor, which is used to measure the axial temperature inside a fixed-bed catalyst reaction tube when it is filled with a catalyst, at a predetermined location in the reaction tube. In addition, a method for installing a thermowell for temperature sensor is provided. The method includes the steps of installing a structure for guiding the installation of a thermowell for temperature sensor in a reaction tube and fixing the thermowell for temperature sensor while filling the reaction tube with a catalyst.
摘要翻译：公开了一种用于引导安装温度传感器的套管的结构，其用于在反应管中的预定位置处测量固定床催化剂反应管内的催化剂时的轴向温度。另外，提供了一种用于安装温度传感器的热套管的方法。该方法包括以下步骤：在用催化剂填充反应管的同时，安装用于将温度传感器的热套管安装在反应管中的结构，并固定温度传感器的热套管。

9. 发明授权

US08961656B2 Gas hydrate inhibitor and method of inhibiting gas hydrate formation 有权
标题翻译：天然气水合物抑制剂和气体水合物形成抑制方法
公开(公告)号：US08961656B2
公开(公告)日：2015-02-24
申请号：US13169538
申请日：2011-06-27
申请人： Seong-Pil Kang
发明人： Seong-Pil Kang
IPC分类号： C07C7/20 , C07D207/08 , C07F5/02 , C07D207/06 , C09K8/52 , C10L3/10
CPC分类号： C07D207/08 , C07D207/06 , C09K8/52 , C09K2208/22 , C10L3/107
摘要： The present invention relates to an ionic liquid compound that inhibits a formation of a gas hydrate. The compound of the present invention changes an equilibrium temperature and pressure of a gas hydrate in small quantity into a lower temperature and/or a higher pressure, and simultaneously retards the formation of the gas hydrate under the same environment. Thus, the compound of the present invention is used in oil and natural gas industries to effectively inhibit or delay the formation of the gas hydrate under the condition having a low temperature and a high pressure.
摘要翻译：本发明涉及抑制气体水合物形成的离子液体化合物。本发明的化合物将气体水合物的平衡温度和压力少量地改变为较低的温度和/或更高的压力，同时在相同的环境下延缓了天然气水合物的形成。因此，本发明的化合物用于石油和天然气工业中，以在低温和高压的条件下有效地抑制或延迟气体水合物的形成。

10. 发明申请

US20100012476A1 APPARATUS FOR RECOVERING ACRYLIC ACID 有权
标题翻译：恢复丙烯酸的装置
公开(公告)号：US20100012476A1
公开(公告)日：2010-01-21
申请号：US12565359
申请日：2009-09-23
申请人： Seong Pil KANG , Seok Kwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
发明人： Seong Pil KANG , Seok Kwan Choi , Kyoung Su Ha , Jun Seok Ko , Boo Gon Woo , Young Bae Kim
IPC分类号： B01D3/10
CPC分类号： C07C51/44 , B01J2219/00006 , C07C51/487 , C07C57/04
摘要： Disclosed is a simplified apparatus for recovering acrylic acid from a mixture containing acrylic acid, acrylic acid dimer and impurities with high boiling point, in a stable and efficient manner. An apparatus for recovering an acrylic acid from a mixture containing acrylic acid, acrylic acid dimer and impurities with high boiling point, which comprises: an acrylic acid recovering device that comprises an acrylic acid distillation unit being present within an acrylic acid dimer pyrolysis tank, and is operated under reduced pressure; and a line for introducing the mixture into the acrylic acid recovering device, wherein decomposition of the acrylic acid dimer is carried out under reduced pressure at a lower part of the acrylic acid recovering device, while the acrylic acid is recovered by distillation under reduced pressure from a top of the acrylic acid recovering device.
摘要翻译：公开了一种用于以稳定且有效的方式从含有丙烯酸，丙烯酸二聚物和高沸点杂质的混合物中回收丙烯酸的简化装置。一种用于从含有丙烯酸，丙烯酸二聚物和高沸点杂质的混合物中回收丙烯酸的装置，其包括：丙烯酸回收装置，其包含存在于丙烯酸二聚物热解罐内的丙烯酸蒸馏单元，以及在减压下运行; 以及用于将混合物引入丙烯酸回收装置的管线，其中丙烯酸二聚物的分解在丙烯酸回收装置的下部在减压下进行，同时通过减压蒸馏回收丙烯酸，丙烯酸回收装置的顶部。

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