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1. 发明授权

US5292890A Asymmetrical benzotriazolylphenols 失效
标题翻译：不对称苯并三唑酚
公开(公告)号：US5292890A
公开(公告)日：1994-03-08
申请号：US58012
申请日：1993-05-05
申请人： Semyon Moshchitsky , William E. Leistner
发明人： Semyon Moshchitsky , William E. Leistner
IPC分类号： C07D249/20
CPC分类号： C07D249/20
摘要： Provided are asymmetrical, ultraviolet stabilizers which are hydroxyphenyl benzotriazolylphenol compounds of the formula: ##STR1## wherein: R.sub.1 is C.sub.1 to C.sub.18 alkyl, C.sub.6 to C.sub.10 aryl, C.sub.7 to C.sub.16 arylalkyl, C.sub.1 to C.sub.12 alkoxy, C.sub.6 to C.sub.10 aryloxy, C.sub.7 to C.sub.16 arylalkoxy, cyclopentyl, cyclohexyl or cumyl;R.sub.2 is C.sub.1 to C.sub.18 alkyl, C.sub.6 to C.sub.10 aryl, C.sub.7 to C.sub.16 arylalkyl, C.sub.1 to C.sub.12 alkoxy, C.sub.6 to C.sub.10 aryloxy, C.sub.7 to C.sub.16 arylalkoxy, cyclopentyl, cyclohexyl or cumyl;R.sub.1 is different from R.sub.2 ; andX is selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.12 alkyl, and C.sub.1 to C.sub.12 alkoxy. The invention also pertains to a process for their preparation and stabilized polymer blends containing the stabilizers.
摘要翻译：提供的是不对称的紫外线稳定剂，它们是下式的羟基苯基苯并三唑基苯酚化合物：（*化学结构*）（*化学结构*）其中：R1为C1至C18烷基，C6至C10芳基，C7至C16芳基烷基，C1至C12烷氧基 C6至C10芳氧基，C7至C16芳基烷氧基，环戊基，环己基或枯基; R2是C1至C18烷基，C6至C10芳基，C7至C16芳烷基，C1至C12烷氧基，C6至C10芳氧基，C7至C16芳基烷氧基，环戊基，环己基或枯基; R1不同于R2; X选自氢，卤素，C 1至C 12烷基和C 1至C 12烷氧基。本发明还涉及其制备方法和含有稳定剂的稳定的聚合物共混物。

2. 发明授权

US5373037A Coupled benzotriazole and benzophenone UV absorbers 失效
标题翻译：偶联苯并三唑和二苯甲酮紫外吸收剂
公开(公告)号：US5373037A
公开(公告)日：1994-12-13
申请号：US246352
申请日：1994-05-19
申请人： William E. Leistner , Semyon Moshchitsky
发明人： William E. Leistner , Semyon Moshchitsky
IPC分类号： C07D249/20 , C08K5/3475
CPC分类号： C08K5/3475 , C07D249/20
摘要： Provided are ultraviolet stabilizers which are diphenylmethane compounds of the formula: ##STR1## wherein: R.sub.1 and R.sub.2 are independently C.sub.1 to C.sub.8 alkyl, cyclopentyl, cyclohexyl or cumyl; and X is selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.12 alkyl and C.sub.1 to C.sub.12 alkoxy. The invention also pertains to a process for their preparation and stabilized polymer blends containing the stabilizers.
摘要翻译：提供的是具有下式的二苯基甲烷化合物的紫外线稳定剂：其中：R 1和R 2独立地为C 1至C 8烷基，环戊基，环己基或枯基; 并且X选自氢，卤素，C 1至C 12烷基和C 1至C 12烷氧基。本发明还涉及其制备方法和含有稳定剂的稳定的聚合物共混物。

3. 发明授权

US5362881A Coupled benzotriazole and benzophenone UV absorbers 失效
公开(公告)号：US5362881A
公开(公告)日：1994-11-08
申请号：US69000
申请日：1993-05-27
申请人： William E. Leistner , Semyon Moshchitsky
发明人： William E. Leistner , Semyon Moshchitsky
IPC分类号： C07D249/20 , C08K5/3475
CPC分类号： C08K5/3475 , C07D249/20
摘要： Provided are ultraviolet stabilizers which are diphenylmethane compounds of the formula: ##STR1## wherein: R.sub.1 and R.sub.2 are independently C.sub.1 to C.sub.8 alkyl, cyclopentyl, cyclohexyl or cumyl; and X is selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.12 alkyl and C.sub.1 to C.sub.12 alkoxy. The invention also pertains to a process for their preparation and stabilized polymer blends containing the stabilizers.

4. 发明授权

US5466819A Coupled benzotriazole and benzophenone UV absorbers 失效
标题翻译：偶联苯并三唑和二苯甲酮紫外吸收剂
公开(公告)号：US5466819A
公开(公告)日：1995-11-14
申请号：US271155
申请日：1994-07-06
申请人： William E. Leistner , Semyon Moshchitsky
发明人： William E. Leistner , Semyon Moshchitsky
IPC分类号： C07D249/20 , C08K5/3475
CPC分类号： C08K5/3475 , C07D249/20
摘要： Provided are ultraviolet stabilizers which are diphenylmethane compounds of the formula: ##STR1## wherein: R.sub.1 and R.sub.2 are independently C.sub.1 to C.sub.8 alkyl, cyclopentyl, cyclohexyl or cumyl; and X is selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.12 alkyl and C.sub.1 to C.sub.12 alkoxy. The invention also pertains to a process for their preparation and stabilized polymer blends containing the stabilizers.
摘要翻译：提供的是具有下式的二苯基甲烷化合物的紫外线稳定剂：其中：R 1和R 2独立地为C 1至C 8烷基，环戊基，环己基或枯基; 并且X选自氢，卤素，C 1至C 12烷基和C 1至C 12烷氧基。本发明还涉及其制备方法和含有稳定剂的稳定的聚合物共混物。

5. 发明授权

US5237071A Process for preparing 2,2'-methylene-bis(6-(2H-benzotriazol-2-yl)-4-hydrocarbyl phenols) 失效
标题翻译：制备2,2'-亚甲基 - 双（6-（2H-苯并三唑-2-基）-4-烃基酚的方法）
公开(公告)号：US5237071A
公开(公告)日：1993-08-17
申请号：US644299
申请日：1991-01-22
申请人： William E. Leistner , Semyon Moshchitsky , Mahmut Levent
发明人： William E. Leistner , Semyon Moshchitsky , Mahmut Levent
IPC分类号： C07D249/20
CPC分类号： C07D249/20
摘要： A method for preparing 2,2'-methylene-bis-[6-(2H)-benzotriazol-2-yl)-4-hydrocarbyl phenols] is disclosed. According to the process(i) formaldehyde, a dialkylamine and a 4-hydrocarbyl-6-benzotriazolyl phenol as monomer are mixed;(ii) the mixture is heated to a temperature high enough to remove the water produced by the reaction of the mixture;(iii) thereafter an alkaline catalyst is added with heating for several hours;(iv) the phenol compound precipitates when the reaction mixture is neutralized and solvent for the salt product of the neutralization reaction is added in an amount sufficient to permit stirring.The solid product produced is 2,2'-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-hydrocarbyl phenol] having the formula I: ##STR1## in which each R group is an alkyl group of one to twelve carbons or a cycloalkyl group of five to eight carbons and X is chloro or hydrogen.
摘要翻译：公开了一种制备2,2'-亚甲基 - 双 - [6-（2H） - 苯并三唑-2-基）-4-烃基酚的方法]。根据方法（i）甲醛，将二烷基胺和作为单体的4-烃基-6-苯并三唑基苯酚混合; （ii）将混合物加热到足够高的温度以除去由混合物反应产生的水; （iii）然后加热碱性催化剂数小时; （iv）当反应混合物中和时，酚化合物沉淀，并且以足以允许搅拌的量加入中和反应的盐产物的溶剂。产生的固体产物是具有式I的2,2'-亚甲基 - 双[6-（2H-苯并三唑-2-基）-4-烃基苯酚]，其中每个R基团是一至十二个碳或五至八个碳的环烷基，X是氯或氢。

6. 发明授权

US5360850A Asymmetrical benzotriazolylphenols 失效
标题翻译：不对称苯并三唑酚
公开(公告)号：US5360850A
公开(公告)日：1994-11-01
申请号：US159376
申请日：1993-11-30
申请人： Semyon Moshchitsky , William E. Leistner
发明人： Semyon Moshchitsky , William E. Leistner
IPC分类号： C07D249/20 , C08K5/34
CPC分类号： C07D249/20
摘要： Provided are asymmetrical, ultraviolet stabilizers which are hydroxyphenyl benzotriazolylphenol compounds of the formula: ##STR1## wherein: R.sub.1 is C.sub.1 to C.sub.18 alkyl, C.sub.6 to C.sub.10 aryl, C.sub.7 to C.sub.16 arylalkyl, C.sub.1 to C.sub.12 alkoxy, C.sub.6 to C.sub.10 aryloxy, C.sub.7 to C.sub.16 arylalkoxy, cyclopentyl, cyclohexyl or cumyl;R.sub.2 is C.sub.1 to C.sub.18 alkyl, C.sub.6 to C.sub.10 aryl, C.sub.7 to C.sub.16 arylalkyl, C.sub.1 to C.sub.12 alkoxy, C.sub.6 to C.sub.10 aryloxy, C.sub.7 to C.sub.16 arylalkoxy, cyclopentyl, cyclohexyl or cumyl;R.sub.1 is different from R.sub.2 ; andX is selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.12 alkyl, and C.sub.1 to C.sub.12 alkoxy. The invention also pertains to a process for their preparation and stabilized polymer blends containing the stabilizers.
摘要翻译：提供的是不对称的紫外线稳定剂，它们是下式的羟基苯基苯并三唑基苯酚化合物：其中：R1是C1-C18烷基，C6-C10芳基，C7-C16芳烷基，C1-C12烷氧基，C6-C10芳氧基，C7-C16 芳基烷氧基，环戊基，环己基或枯基; R2是C1至C18烷基，C6至C10芳基，C7至C16芳烷基，C1至C12烷氧基，C6至C10芳氧基，C7至C16芳基烷氧基，环戊基，环己基或枯基; R1不同于R2; X选自氢，卤素，C 1至C 12烷基和C 1至C 12烷氧基。本发明还涉及其制备方法和含有稳定剂的稳定的聚合物共混物。

7. 发明授权

US5262541A Fluorenol catalyzed reduction of o-nitroazobenzenes and 2-aryl-2H-benzotriazole-N-oxides 失效
标题翻译：芴醇催化还原邻硝基偶氮和2-芳基-2H-苯并三唑-N-氧化物
公开(公告)号：US5262541A
公开(公告)日：1993-11-16
申请号：US990694
申请日：1992-12-15
申请人： Semyon Moshchitsky , William E. Leistner , Howard R. Leistner
发明人： Semyon Moshchitsky , William E. Leistner , Howard R. Leistner
IPC分类号： C07D249/20
CPC分类号： C07D249/20
摘要： A process for producing 2-aryl-2H-benzotriazole by reducing an o-nitroazobenzene with a saccharide having an aldehyde group as a reducing agent in the presence of fluorenol as a catalyst and a base in solution. The reaction is conducted at a temperature of from about 60.degree. C. to about 80.degree. C. The reaction time and amount of catalyst is significantly reduced compared to the use of an aromatic ketone catalyst. The invention also provides a method for producing 2-aryl-2H-benzotriazole by reducing a 2-aryl-2H-benzotriazole-N-oxide intermediate with a saccharide having an aldehyde group as a reducing agent, in the presence of fluorenol under similar conditions.
摘要翻译：通过在芴醇作为催化剂和碱溶液存在下，用具有醛基作为还原剂的糖类还原邻硝基偶氮苯来制备2-芳基-2H-苯并三唑的方法。反应在约60℃至约80℃的温度下进行。与使用芳族酮催化剂相比，催化剂的反应时间和量显着降低。本发明还提供了通过在类似条件下在芴醇存在下，用具有醛基作为还原剂的糖类还原2-芳基-2H-苯并三唑-N-氧化物中间体的方法来制备2-芳基-2H-苯并三唑。

8. 发明授权

US5166355A Process for preparing substituted 2,2'-methylene-bis-[6-(2H-benzotriazol-2-yl)-4-hydrocarbyl-phenols] 失效
标题翻译：取代的2,2'-亚甲基 - 双 - [6-（2H-苯并三唑-2-基）-4-烃基 - 酚]的制备方法]
公开(公告)号：US5166355A
公开(公告)日：1992-11-24
申请号：US649972
申请日：1991-02-04
申请人： William E. Leistner , Semyon Moshchitsky , Mahmut Levent
发明人： William E. Leistner , Semyon Moshchitsky , Mahmut Levent
IPC分类号： C07C45/72 , C07C49/84 , C07D249/20
CPC分类号： C07D249/20 , C07C45/72 , C07C49/84
摘要： A method is described for preparing compounds of Formula I and Formula II: ##STR1## R.sub.1 is an alkyl group of one to twelve carbon atoms or a cycloalkyl group of five to eight carbons, X is chloro or hydrogen, and R.sub.2 is an alkoxy group having one to twelve carbons. In accordance with the method:(a) a bis(dialkylamino)methane is formed, preferably by reacting a dialkylamine of the formula HNR.sub.3 R.sub.4 (wherein R.sub.3 and R.sub.4 are independently alkyl groups having three or more carbons) and a solid formaldehyde material to produce the corresponding bis(dialkylamino)methane,(b) a monomer of Formula III or IV ##STR2## in which R.sub.1 is an alkyl group of one to twelve carbons or a cycloalkyl group of five to eight carbons, X is chloro or hydrogen and R.sub.2 is an alkoxy group having one to twelve carbon atoms, is mixed with an alkaline catalyst with heating at a temperature high enough to drive off the liquid formed in the reaction,(c) the product of steps (a) and (b) are combined and stirred at a temperature sufficient to drive the reaction for six to fourteen hours, and(d) thereafter the resulting compound of Formula I is collected.
摘要翻译：描述了制备式I和式II化合物的方法：R 1是1至12个碳原子的烷基或5至8个碳的环烷基，X是氯或氢，以及 R2是具有1〜12个碳原子的烷氧基。根据以下方法：（a）形成双（二烷基氨基）甲烷，优选通过使式HNR 3 R 4的二烷基胺（其中R 3和R 4独立地为具有三个或更多个碳的烷基）和固体甲醛材料反应，生成对应的双（二烷基氨基）甲烷，（b）式III或IV的单体IV，其中R 1是1至12个碳的烷基或5至8个碳的环烷基，X是氯或氢，R2为具有1〜12个碳原子的烷氧基，与碱催化剂在足够高的温度下加热以除去反应中形成的液体，（c）步骤（a）和（ b）在足以驱动反应6至14小时的温度下混合并搅拌，然后收集所得到的式I化合物。

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