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1. 发明授权

US08399057B2 Ordered vertically oriented porous inorganic films produced through solution processing 有权
标题翻译：通过溶液处理生产的有序垂直取向的多孔无机膜
公开(公告)号：US08399057B2
公开(公告)日：2013-03-19
申请号：US11449465
申请日：2006-06-08
申请人： Sarah H. Tolbert , Erik K. Richman
发明人： Sarah H. Tolbert , Erik K. Richman
IPC分类号： B05D3/00
CPC分类号： C04B35/62218 , C04B35/14 , C04B35/46 , C04B35/62655 , C04B35/6269 , C04B38/0022 , C04B2235/441 , H01G9/2031 , C04B38/0054
摘要： Porous films with straight pores oriented normal to the plane of the films are produced through solution processing techniques. The production takes advantage of inorganic-surfactant or inorganic-polymer co-assembly and a patterned substrate. The patterned substrate, which is also produced via solution phase self-assembly, forces vertical orientation in a hexagonal cylinder system with no practical limits in substrate size or type. This provides a route to vertically oriented inorganic pores with a pitch ranging from 3 nm to over 15 nm and pore sizes ranging from 2 nm to over 12 nm. The size is tuned by choice the choice of organic templating agents and the deposition conditions. The pores can be produced with or without a capping layer which can be used to seal the nanopores.
摘要翻译：通过溶液处理技术产生具有垂直于膜平面的直孔的多孔膜。该生产利用无机 - 表面活性剂或无机 - 聚合物共组合物和图案化基底。也通过溶液相自组装产生的图案化衬底迫使六角形气缸系统中的垂直取向，而衬底尺寸或类型没有实际限制。这提供了以3nm至15nm以上的间距为范围从2nm到12nm以上的垂直取向的无机孔的途径。通过选择来调整大小有机模板剂的选择和沉积条件。孔可以在有或没有可用于密封纳米孔的封盖层的情况下生产。

2. 发明授权

US08431102B2 Rhenium boride compounds and uses thereof 有权
标题翻译：硼化铼化合物及其用途
公开(公告)号：US08431102B2
公开(公告)日：2013-04-30
申请号：US12423949
申请日：2009-04-15
申请人： Richard B. Kaner , Sarah H. Tolbert , Abby Kavner , Jenn-Ming Yang , Michelle B. Weinberger , Robert W. Cumberland , John J. Gilman , Hsiu-Ying Chung , Jonathan B. Levine
发明人： Richard B. Kaner , Sarah H. Tolbert , Abby Kavner , Jenn-Ming Yang , Michelle B. Weinberger , Robert W. Cumberland , John J. Gilman , Hsiu-Ying Chung , Jonathan B. Levine
IPC分类号： C01B35/02 , B32B5/16 , B32B9/00 , C09K3/14
CPC分类号： C01B35/04 , B24D3/00 , C09K3/1409 , Y10T428/12576 , Y10T428/256 , Y10T428/26 , Y10T428/2982
摘要： Described herein are rhenium boride compounds having desirable characteristics for a variety of applications, ranging from abrasives and cutting tools to protective coatings.
摘要翻译：本文描述的是硼化铼化合物，其具有从研磨剂和切削工具到保护涂层的各种应用的所需特性。

3. 发明申请

US20120026644A1 MESOPOROUS NANOCRYSTALLINE FILM ARCHITECTURE FOR CAPACITIVE STORAGE DEVICES 有权
标题翻译：用于电容存储设备的多孔纳米薄膜电影架构
公开(公告)号：US20120026644A1
公开(公告)日：2012-02-02
申请号：US13177401
申请日：2011-07-06
申请人： Bruce S. Dunn , Sarah H. Tolbert , John Wang , Torsten Brezesinski
发明人： Bruce S. Dunn , Sarah H. Tolbert , John Wang , Torsten Brezesinski
IPC分类号： H01G9/155
CPC分类号： H01G11/84 , B82Y99/00 , H01G11/24 , H01G11/26 , H01G11/36 , H01G11/46 , Y02E60/13 , Y10S977/948
摘要： A mesoporous, nanocrystalline, metal oxide construct particularly suited for capacitive energy storage that has an architecture with short diffusion path lengths and large surface areas and a method for production are provided. Energy density is substantially increased without compromising the capacitive charge storage kinetics and electrode demonstrates long term cycling stability. Charge storage devices with electrodes using the construct can use three different charge storage mechanisms immersed in an electrolyte: (1) cations can be stored in a thin double layer at the electrode/electrolyte interface (non-faradaic mechanism); (2) cations can interact with the bulk of an electroactive material which then undergoes a redox reaction or phase change, as in conventional batteries (faradaic mechanism); or (3) cations can electrochemically adsorb onto the surface of a material through charge transfer processes (faradaic mechanism).
摘要翻译：提供了特别适用于具有短扩散路径长度和大表面积的结构的电容性能量存储的介孔纳米晶体金属氧化物构造以及生产方法。能量密度大大增加，而不损害电容性电荷存储动力学，电极表现出长期的循环稳定性。带电极的电荷存储装置可以使用浸入电解质中的三种不同的电荷存储机构：（1）阳离子可以存储在电极/电解质界面（非法拉第机制）的薄双层中; （2）如常规电池（法拉第机制），阳离子可与电活性材料的主体相互作用，然后电活性材料经历氧化还原反应或相变。或（3）阳离子可以通过电荷转移过程（法拉第机制）电化学吸附在材料的表面上。

4. 发明授权

US10125412B2 Compositional variations of tungsten tetraboride with transition metals and light elements 有权
公开(公告)号：US10125412B2
公开(公告)日：2018-11-13
申请号：US14112903
申请日：2012-04-23
申请人： Richard B. Kaner , Sarah H. Tolbert , Reza Mohammadi , Andrew T. Lech , Miao Xie
发明人： Richard B. Kaner , Sarah H. Tolbert , Reza Mohammadi , Andrew T. Lech , Miao Xie
IPC分类号： C22C27/04 , C22C1/02 , C23C30/00 , C22C29/14 , B22F9/04 , C22C1/04 , C22C1/10 , B22F5/00
摘要： A composition includes tungsten (W); at least one element selected form the group of elements consisting of boron (B), beryllium (Be) and silicon (Si); and at least one element selected from the group of elements consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Hf), tantalum (Ta), rhenium (Re), osmium (Os), iridium (Ir), lithium (Li) and aluminum (Al). The composition satisfies the formula W1-xMxXy wherein X is one of B, Be and Si; M is at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Hf, Ta, Re, Os, Ir, Li and Al; x is at least 0.001 and less than 0.999; and y is at least 4.0. A tool is made from or coated with this composition.

5. 发明授权

US09142833B2 Lithium ion batteries based on nanoporous silicon 有权
标题翻译：基于纳米多孔硅的锂离子电池
公开(公告)号：US09142833B2
公开(公告)日：2015-09-22
申请号：US13702990
申请日：2011-06-07
申请人： Sarah H. Tolbert , Eric J. Nemanick , Chris Byung-Hwa Kang
发明人： Sarah H. Tolbert , Eric J. Nemanick , Chris Byung-Hwa Kang
IPC分类号： H01M4/38 , H01M4/134 , H01M4/62 , H01M10/0525 , H01M10/0561 , B82Y30/00
CPC分类号： H01M4/134 , B82Y30/00 , H01M4/38 , H01M4/386 , H01M4/625 , H01M10/0525 , H01M10/0561 , Y02E60/122
摘要： A lithium ion battery that incorporates an anode formed from a Group IV semiconductor material such as porous silicon is disclosed. The battery includes a cathode, and an anode comprising porous silicon. In some embodiments, the anode is present in the form of a nanowire, a film, or a powder, the porous silicon having a pore diameters within the range between 2 nm and 100 nm and an average wall thickness of within the range between 1 nm and 100 nm. The lithium ion battery further includes, in some embodiments, a non-aqueous lithium containing electrolyte. Lithium ion batteries incorporating a porous silicon anode demonstrate have high, stable lithium alloying capacity over many cycles.
摘要翻译：公开了一种包含由IV族半导体材料如多孔硅形成的阳极的锂离子电池。电池包括阴极和包含多孔硅的阳极。在一些实施方案中，阳极以纳米线，薄膜或粉末的形式存在，多孔硅的孔径在2nm至100nm的范围内，平均壁厚在1nm 和100nm。在一些实施方案中，锂离子电池还包括非水性含锂电解质。结合多孔硅阳极的锂离子电池在许多周期内具有高稳定的锂合金化能力。

6. 发明申请

US20110171518A1 Three dimensional Battery Architectures and Methods of Making Same 审中-公开
标题翻译：三维电池结构及其制作方法
公开(公告)号：US20110171518A1
公开(公告)日：2011-07-14
申请号：US13052596
申请日：2011-03-21
申请人： Bruce Dunn , Jeffrey W. Long , Debra R. Rolison , Henry S. White , Fred Wudl , Sarah H. Tolbert , Chang-Jin Kim
发明人： Bruce Dunn , Jeffrey W. Long , Debra R. Rolison , Henry S. White , Fred Wudl , Sarah H. Tolbert , Chang-Jin Kim
IPC分类号： H01M4/32 , H01M4/38 , H01M2/02 , H01M10/04
CPC分类号： H01M10/0525 , H01M4/04 , H01M4/244 , H01M4/32 , H01M4/75 , H01M10/0436 , H01M10/058 , H01M2300/0025 , H01M2300/0085 , Y10T29/49108
摘要： A three-dimensional electrode structure for use in a battery comprising a porous three-dimensional substrate formed from a first electrically conductive material, an ion-conducting dielectric material disposed on the porous three dimensional substrate, and a second electrically conductive material disposed on the ion-conducting dielectric material, wherein the ion-conducting dielectric material separates the first electrically conductive material from the second electrically conductive material.
摘要翻译：一种用于电池的三维电极结构，包括由第一导电材料形成的多孔三维基板，设置在多孔三维基板上的离子传导电介质材料和设置在离子上的第二导电材料导电介电材料，其中所述离子传导电介质材料将所述第一导电材料与所述第二导电材料分离。

7. 发明授权

US09231214B2 Photovoltaic devices including self-assembling fullerene derivatives for improved efficiencies 有权
标题翻译：光伏器件包括自组装富勒烯衍生物，以提高效率
公开(公告)号：US09231214B2
公开(公告)日：2016-01-05
申请号：US12419936
申请日：2009-04-07
申请人： Sarah H. Tolbert , Benjamin J. Schwartz , Yves Rubin , Merissa Halim , Darcy Wanger , Christopher J. Tassone , Alexander L. Ayzner , Robert D. Kennedy , Christopher Day
发明人： Sarah H. Tolbert , Benjamin J. Schwartz , Yves Rubin , Merissa Halim , Darcy Wanger , Christopher J. Tassone , Alexander L. Ayzner , Robert D. Kennedy , Christopher Day
IPC分类号： H01L25/00 , H01L31/00 , H01L51/00 , B82Y10/00 , H01L51/42
CPC分类号： H01L51/0047 , B82Y10/00 , H01L51/4253 , Y02E10/549
摘要： Described herein are photovoltaic devices including self-assembling fullerene derivatives. In one embodiment, a photovoltaic device includes a first electrode layer, a second electrode layer, and an active layer disposed between the first electrode layer and the second electrode layer. The active layer is configured to absorb incident light to produce a first type of charge carrier that is transported to the first electrode layer and a second type of charge carrier that is transported to the second electrode layer. The active layer includes self-assembled molecules of a fullerene derivative to provide a conductive path through at least a portion of the active layer.
摘要翻译：这里描述的是包括自组装富勒烯衍生物的光伏器件。在一个实施例中，光伏器件包括第一电极层，第二电极层和设置在第一电极层和第二电极层之间的有源层。有源层被配置为吸收入射光以产生被传输到第一电极层的第一类型的电荷载体和被传输到第二电极层的第二类型的电荷载体。有源层包括富勒烯衍生物的自组装分子，以提供穿过有源层的至少一部分的导电路径。

8. 发明申请

US20140041313A1 COMPOSITIONAL VARIATIONS OF TUNGSTEN TETRABORIDE WITH TRANSITION METALS AND LIGHT ELEMENTS 审中-公开
标题翻译：铁素体与过渡金属和光元素的组成变化
公开(公告)号：US20140041313A1
公开(公告)日：2014-02-13
申请号：US14112903
申请日：2012-04-23
申请人： Richard B. Kaner , Sarah H. Tolbert , Reza Mohammadi , Andrew T. Lech , Miao Xie
发明人： Richard B. Kaner , Sarah H. Tolbert , Reza Mohammadi , Andrew T. Lech , Miao Xie
IPC分类号： C22C27/04
CPC分类号： C22C27/04 , B22F9/04 , B22F2005/001 , B22F2009/041 , C22C1/02 , C22C1/045 , C22C1/1084 , C22C29/14 , C23C30/00 , C23C30/005
摘要： A composition includes tungsten (W); at least one element selected form the group of elements consisting of boron (B), beryllium (Be) and silicon (Si); and at least one element selected from the group of elements consisting of titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), zirconium (Zr), niobium (Nb), molybdenum (Mo), ruthenium (Ru), hafnium (Hf), tantalum (Ta), rhenium (Re), osmium (Os), iridium (Ir), lithium (Li) and aluminum (Al). The composition satisfies the formula W1-xMxXy wherein X is one of B, Be and Si; M is at least one of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Nb, Mo, Ru, Hf, Ta, Re, Os, Ir, Li and Al; x is at least 0.001 and less than 0.999; and y is at least 4.0. A tool is made from or coated with this composition.
摘要翻译：组合物包括钨（W）; 选自由硼（B），铍（Be）和硅（Si）组成的元素组中的至少一种元素; 以及选自由钛（Ti），钒（V），铬（Cr），锰（Mn），铁（Fe），钴（Co），镍（Ni），铜（ Cu），锌（Zn），锆（Zr），铌（Nb），钼（Mo），钌（Ru），铪（Hf），钽（Ta），铼（Re），锇（Os） Ir），锂（Li）和铝（Al）等。该组成满足式W1-xMxXy其中X是B，Be和Si之一; M是Ti，V，Cr，Mn，Fe，Co，Ni，Cu，Zn，Zr，Nb，Mo，Ru，Hf，Ta，Re，Os，Ir，Li和Al中的至少一种; x至少为0.001且小于0.999; y至少为4.0。工具由该组合物制成或涂覆。

9. 发明申请

US20090202712A1 POLARIZED LIGHT-EMITTING FILM AND METHOD FOR PRODUCING THE SAME 审中-公开
标题翻译：极化发光膜及其制造方法
公开(公告)号：US20090202712A1
公开(公告)日：2009-08-13
申请号：US12403084
申请日：2009-03-12
申请人： Hirokatsu Miyata , Sarah H. Tolbert , William C Molenkamp , Benjamin Joel Schwartz , Ignacio Bartolome Martini
发明人： Hirokatsu Miyata , Sarah H. Tolbert , William C Molenkamp , Benjamin Joel Schwartz , Ignacio Bartolome Martini
IPC分类号： B05D5/06
CPC分类号： H01L51/5012 , H01L51/0038 , H01L51/5293 , H01S3/094034 , H01S3/168 , Y10T428/249969 , Y10T428/249975
摘要： A polarized light-emitting layer that comprises a porous silica film formed on a substrate and a conjugated polymer held in the uniaxially oriented, tubular mesopores in the porous silica film. The film can emit fluorescence polarized in a direction parallel to the alignment direction of the mesopores. The film can act as a lasing layer with a low excitation threshold.
摘要翻译：一种偏振发光层，其包含在基板上形成的多孔二氧化硅膜和保持在多孔二氧化硅膜中的单轴取向的管状介孔中的共轭聚合物。该膜可以在平行于介孔的排列方向的方向发射偏振的荧光。该膜可以作为具有低激发阈值的激光层。

10. 发明授权

US08675346B2 Mesoporous nanocrystalline film architecture for capacitive storage devices 有权
标题翻译：用于电容式存储设备的介孔纳米晶膜结构
公开(公告)号：US08675346B2
公开(公告)日：2014-03-18
申请号：US13177401
申请日：2011-07-06
申请人： Bruce S. Dunn , Sarah H. Tolbert , John Wang , Torsten Brezesinski
发明人： Bruce S. Dunn , Sarah H. Tolbert , John Wang , Torsten Brezesinski
IPC分类号： H01G9/00
CPC分类号： H01G11/84 , B82Y99/00 , H01G11/24 , H01G11/26 , H01G11/36 , H01G11/46 , Y02E60/13 , Y10S977/948
摘要： A mesoporous, nanocrystalline, metal oxide construct particularly suited for capacitive energy storage that has an architecture with short diffusion path lengths and large surface areas and a method for production are provided. Energy density is substantially increased without compromising the capacitive charge storage kinetics and electrode demonstrates long term cycling stability. Charge storage devices with electrodes using the construct can use three different charge storage mechanisms immersed in an electrolyte: (1) cations can be stored in a thin double layer at the electrode/electrolyte interface (non-faradaic mechanism); (2) cations can interact with the bulk of an electroactive material which then undergoes a redox reaction or phase change, as in conventional batteries (faradaic mechanism); or (3) cations can electrochemically adsorb onto the surface of a material through charge transfer processes (faradaic mechanism).
摘要翻译：提供了特别适用于具有短扩散路径长度和大表面积的结构的电容性能量存储的介孔纳米晶体金属氧化物构造以及生产方法。能量密度大大增加，而不损害电容性电荷存储动力学，电极表现出长期的循环稳定性。带电极的电荷存储装置可以使用浸入电解质中的三种不同的电荷存储机构：（1）阳离子可以存储在电极/电解质界面（非法拉第机制）的薄双层中; （2）如常规电池（法拉第机制），阳离子可与电活性材料的主体相互作用，然后电活性材料经历氧化还原反应或相变。或（3）阳离子可以通过电荷转移过程（法拉第机制）电化学吸附在材料的表面上。

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