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1. 发明申请

WO2019165062A1 POLYCARBONATE COPOLYMER BLENDS, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE 审中-公开
公开(公告)号：WO2019165062A1
公开(公告)日：2019-08-29
申请号：PCT/US2019/018941
申请日：2019-02-21
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , YAMAGUCHI, Norimitsu , OBERHOLTZER, Jacob Lee , MAHOOD, James Alan
IPC分类号： C08L79/08
摘要： A polymer blend including 5 to 95 weight percent of a poly(ester-carbonate-carbonate) comprising 40 to 95 mole percent of ester units comprising low heat bisphenol groups and high heat bisphenol groups, wherein the ester units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of ester units in the poly(ester-carbonate-carbonate), and 5 to 60 mole percent of carbonate units comprising the low heat bisphenol groups and the high heat bisphenol groups, wherein the carbonate units comprise 20 to 80 mole percent of the low heat bisphenol groups and 20 to 80 mole percent of the high heat bisphenol groups, based on the total moles of carbonate units in the poly(ester-carbonate-carbonate); and 5 to 95 weight percent of a poly(etherimide), wherein the weight percent of each polymer is based on the total weight of the polymers in the blend, and a molded 0.125-inch thick ASTM tensile bar comprising the polymer blend has a haze value of less than 25% as determined according to ASTM D1003 using the color space CIE1931 with Illuminant C and a 2° observer.

2. 发明申请

WO2015106208A1 COMPATIBILIZED COMPOSITIONS, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE THEREOF 审中-公开
标题翻译：兼容组合物，其形成的制品及其制备方法
公开(公告)号：WO2015106208A1
公开(公告)日：2015-07-16
申请号：PCT/US2015/011042
申请日：2015-01-12
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , VAN DER MEE, Mark Adrianus Johannes , ASSINK, Roland Sebastian , VAN DE GRAMPEL, Robert Dirk , NARAYANAN, Aditya , FENG, Cao , SHETH, Kapil Chandrakant , ZHOU, Hao , SUN, Xiaoyu , WIRTZ, Remco
IPC分类号： C08L69/00 , C08L79/08 , C08K3/22
CPC分类号： C08L69/00 , B32B27/08 , C08J5/00 , C08J2369/00 , C08J2469/00 , C08J2479/08 , C08K3/22 , C08K5/526 , C08K2003/2241 , C08L69/005 , C08L79/08 , C08L2201/08 , C08L2203/12 , C08L2203/14 , C08L2205/02 , C08L2205/025 , C08L2205/03 , C08L2205/035 , C08L2205/06 , C08L2207/04 , C25D11/02
摘要： A thermoplastic composition comprises, based on the total weight of the thermoplastic composition, 10 to 45 wt.% of a poly(etherimide); 35 to 90 wt.% of a poly(carbonate-siloxane); 0.5 to 20 wt.% of compatibilizer polycarbonate component comprising a poly(carbonate-arylate ester); up to 15 wt.% of an ultraviolet light stabilizer; and 0 to 30 wt.% of TiO2; wherein a sample of the composition has a notched Izod impact energy of at least 200 J/m at 23°C measured in accordance to ASTM D256; and an at least 50% higher notched Izod impact energy value compared to the composition without the compatibilizer component measured in accordance to ASTM D256.
摘要翻译：基于热塑性组合物的总重量，热塑性组合物包含10至45重量％的聚（醚酰亚胺）; 35〜90重量％的聚（碳酸酯 - 硅氧烷）; 0.5至20重量％的包含聚（碳酸酯 - 芳基酯）的增容剂聚碳酸酯组分; 高达15重量％的紫外光稳定剂; 和0〜30重量％的TiO 2; 其中所述组合物的样品具有根据ASTM D256测量的在23℃下的至少200J / m的缺口伊佐德冲击能量; 并且与根据ASTM D256测量的不具有增容剂组分的组合物相比，具有至少50％以上的缺口伊佐德冲击能量值。

3. 发明申请

WO2013130802A1 THERMOPLASTIC POLYCARBONATE COPOLYMER COMPOSITIONS, METHODS OF THEIR MANUFACTURE, AND USES THEREOF 审中-公开
标题翻译：热塑性聚碳酸酯共聚物组合物，其制造方法及其用途
公开(公告)号：WO2013130802A1
公开(公告)日：2013-09-06
申请号：PCT/US2013/028316
申请日：2013-02-28
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , VAN DER MEE, Mark Adrianus Johannes , VAN DE GRAMPEL, Robert Dirk , ASSINK, Roland Sebastian
IPC分类号： C08K5/523 , C08L69/00
CPC分类号： B32B5/00 , C08K5/523 , C09K21/12 , C09K21/14 , Y10T428/1397
摘要： This disclosure relates to thermoplastic compositions comprising a polycarbonate copolymer, the polycarbonate copolymer comprising first repeating carbonate units and second repeating units selected from carbonate units that are different from the first carbonate units, polysiloxane units, and a combination comprising at least one of the foregoing unit; and an organophosphorus flame retardant in an amount effective to provide 0.1 to 1.0 wt% phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after 4 minutes (Ds-4) of less than or equal to 600 determined according to ISO 5659-2 on a 3 mm thick plaque, and a material heat release of less than or equal to 160 kW/m 2 determined according to ISO 5660-1 on a 3 mm thick plaque.
摘要翻译：本公开涉及包含聚碳酸酯共聚物的热塑性组合物，聚碳酸酯共聚物包含第一重复碳酸酯单元和选自不同于第一碳酸酯单元的碳酸酯单元的第二重复单元，聚硅氧烷单元，以及包含至少一个上述单元 ; 和有机磷阻燃剂，其量有效地提供0.1至1.0重量％的磷，基于组合物的总重量，其中由该组合物模制的制品在4分钟后具有小于或等于4分钟的烟密度（Ds-4）至600根据ISO 5659-2测定，厚度为3毫米厚，根据ISO 5660-1测定的材料放热量小于或等于160千瓦/平方米，厚度为3毫米厚。

4. 发明申请

WO2014201086A3 INTERIOR AIRCRAFT COMPONENTS AND METHODS OF MANUFACTURE 审中-公开
公开(公告)号：WO2014201086A3
公开(公告)日：2014-12-18
申请号：PCT/US2014/041856
申请日：2014-06-11
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , VAN DER MEE, Mark Adrianus Johannes , VAN DE GRAMPEL, Robert Dirk , ASSINK, Roland Sebastian
IPC分类号： C08G63/19 , C08G63/195 , C08G63/60 , C08G63/64 , C08G63/695 , C08L83/10 , C08L83/12 , C08K5/49 , C08K5/521 , C08K5/523 , C08K5/5393 , C08G77/445 , C08G77/448
摘要： Interior aircraft components comprise a thermoplastic composition comprising: a first polymer comprising bisphenol A carbonate units and monoaryl arylate units, or a second polymer comprising bisphenol A carbonate units, monoaryl arylate units, and siloxane units, or a combination comprising at least one of the foregoing polymers; and an organophosphorus compound; wherein a sample of the thermoplastic composition has: an OSU integrated 2 minute heat release test value of less than 65 kW-min/m 2 and a peak heat release rate of less than 65 kW/m 2 , an E662 smoke test DsMax value of less than 200, a flame time of less than 15 seconds, a burn length of less than 6 inches, and a drip extinguishing time of less than 5 seconds, an energy in multiaxial impact of 100 J or more and a ductility in multiaxial impact of 100%.

5. 发明申请

WO2014179209A1 INTERIOR TRAIN COMPONENTS HAVING LOW SMOKE AND LOW HEAT RELEASE, AND METHODS OF THEIR MANUFACTURE 审中-公开
标题翻译：具有低烟和低热释放的内部火车部件及其制造方法
公开(公告)号：WO2014179209A1
公开(公告)日：2014-11-06
申请号：PCT/US2014/035660
申请日：2014-04-28
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , VAN DER MEE, Mark Adrianus Johannes , ASSINK, Roland Sebastian , VAN DE GRAMPEL, Robert Dirk
IPC分类号： B61D33/00 , C08K5/00 , C08K5/53 , C08L69/00 , C08L79/08 , C08L83/10
CPC分类号： C08L69/005 , C08G77/448 , C08K5/0066 , C08K5/523 , C08L79/08 , C08L83/10 , C08L69/00 , C08L79/00
摘要： Interior railway components (seat components and claddings) comprise a thermoplastic composition comprising: a first polymer comprising bisphenol A carbonate units and monoaryl arylate units, or a second polymer comprising bisphenol A carbonate units, monoaryl arylate units, and siloxane units, or a combination comprising at least one of the foregoing; and a polyetherimide; wherein a sample of the thermoplastic composition has: a smoke density after 4 minutes (Ds-4) of ≤ 150 measured in accordance with ISO 5659-2 on a 3 mm thick plaque, an integral of the smoke density as a function of time up to 4 minutes (VOF4) ≤ 300 measured in accordance with ISO 5659-2, a maximum average heat release (MAHRE) of ≤ 300 90 kW/m 2 measured in accordance with ISO 5660-1 on a 3 mm thick plaque, and a ductility in multiaxial impact of 80 to 100%, measured in accordance with ISO 6603.
摘要翻译：室内铁路部件（座椅部件和包层）包括热塑性组合物，其包括：包含双酚A碳酸酯单元和单芳基芳基化物单元的第一聚合物，或包含双酚A碳酸酯单元，单芳基芳基化合物单元和硅氧烷单元的第二聚合物，或包含上述的至少一个; 和聚醚酰亚胺; 其中所述热塑性组合物的样品具有：根据ISO 5659-2在3mm厚的板上测量的4分钟（Ds-4）≤150之后的烟雾密度，作为时间的函数的烟浓度的积分至4分钟（VOF4）≤300，根据ISO 5659-2测量，根据ISO 5660-1在3mm厚的板上测量的最大平均放热量（MAHRE）≤30090 kW / m2，延展性在多轴冲击下80〜100％，按照ISO 6603测量。

6. 发明申请

WO2014144304A1 PROCESSES FOR ENHANCING FLAME RETARDANCE AND CHEMICAL RESISTANCE OF POLYMERS 审中-公开
标题翻译：提高聚合物阻燃性和耐化学性的方法
公开(公告)号：WO2014144304A1
公开(公告)日：2014-09-18
申请号：PCT/US2014/028651
申请日：2014-03-14
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , MORIZUR, Jean-Francois
IPC分类号： C08G64/14 , C08L69/00
CPC分类号： C08J7/123 , C08G64/14 , C08L69/00 , C08L101/00
摘要： Processes for increasing the chemical resistance of a surface of a formed product are disclosed. The formed product is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a dihydroxybenzophenone. The surface of the formed product is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.
摘要翻译：公开了用于提高成形产品的表面的耐化学性的方法。形成的产品由包含含有衍生自二羟基二苯甲酮的光活性基团的光活性添加剂的聚合物组合物制备。然后将形成的产品的表面暴露于紫外线以引起光活性添加剂的交联并产生交联表面。交联增强了表面的耐化学性。还讨论了用于控制交联深度的各种手段。

7. 发明申请

WO2013130805A1 THERMOPLASTIC POLYCARBONATE COPOLYMER COMPOSITIONS, METHODS OF THEIR MANUFACTURE, AND ARTICLES THEREOF 审中-公开
标题翻译：热塑性聚碳酸酯共聚物组合物，其制造方法及其制品
公开(公告)号：WO2013130805A1
公开(公告)日：2013-09-06
申请号：PCT/US2013/028320
申请日：2013-02-28
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , VAN DER MEE, Mark Adrianus Johannes , VAN DE GRAMPEL, Robert Dirk , ASSINK, Roland Sebastian
IPC分类号： C08L69/00
CPC分类号： C08K5/523 , B32B5/00 , C08J9/0038 , C08J2369/00 , C08K3/04 , C08K5/5393 , C08K5/5397 , C08K5/5399 , C08K9/00 , C08K2003/2241 , C08L69/00 , C08L83/10 , Y10T428/1397
摘要： A thermoplastic composition includes a poly(carbonate-arylate ester); and an organophosphorus compound in an amount effective to provide 0.1 to 1.0 wt% phosphorus based on the total weight of the composition, wherein an article molded from the composition has a smoke density after four minutes (Ds-4) of less than or equal to 300 determined according to ISO 5659-2 on a 3 mm thick plaque and a maximum average rate of heat release emission (MAHRE) of less than or equal to 90 kW/m 2 determined according to ISO 5660-1 on a 3 mm thick plaque.
摘要翻译：热塑性组合物包括聚（碳酸酯 - 芳基酯）; 和有机磷化合物，其量有效地提供基于组合物总重量的0.1至1.0重量％的磷，其中由组合物模制的制品在四分钟之后具有小于或等于 300根据ISO 5659-2测定，厚度为3毫米厚，最大平均放热量（MAHRE）小于或等于90千瓦/平方米，根据ISO 5660-1确定，厚度为3毫米厚。

8. 发明申请

WO2012135788A1 FLAME RETARD ANT POLY(SILOXANE) COPOLYMER COMPOSITIONS, METHODS OF MANUFACTURE, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：阻燃聚氨酯（硅氧烷）共聚物组合物，制造方法及其形成的制品
公开(公告)号：WO2012135788A1
公开(公告)日：2012-10-04
申请号：PCT/US2012/031731
申请日：2012-03-30
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul Dean , EVANS, Thomas L. , HOOVER, James Franklin
发明人： SYBERT, Paul Dean , EVANS, Thomas L. , HOOVER, James Franklin
IPC分类号： C08L83/10 , C08L69/00
CPC分类号： C08L83/10 , C08L63/00 , C08L69/00 , C08L2201/02 , C08L2205/03 , Y10T428/1352 , Y10T428/31663
摘要： A marine vehicle component wherein the component is a partition or a light cover, and wherein the marine vehicle component is molded or formed from a thermoplastic polymer composition including a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt% of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt% of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt% of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt%, and 0.05 to 10 wt% of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.
摘要翻译：一种船用车辆部件，其中所述部件是隔板或灯罩，并且其中所述船用车辆部件由热塑性聚合物组合物模制或形成，所述热塑性聚合物组合物包含含有硅氧烷的共聚物，其量有效地提供总计为0.2至6.5重量％的基于热塑性聚合物组合物中的聚合物总重量的硅氧烷单元，基于热塑性聚合物组合物中聚合物的总重量，有效提供9至13重量％溴的含溴聚合物，和任选的第三聚合物，其中基于所述第三聚合物，所述含硅氧烷的共聚物，含溴聚合物和任选的第三聚合物的总重量为100重量％，和0.05至10重量％的光漫射添加剂热塑性聚合物组合物中聚合物的总重量。

9. 发明申请

WO2007108867A1 THERMOPLASTIC COMPOSITION, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：热塑性组合物，制备方法和形成的制品
公开(公告)号：WO2007108867A1
公开(公告)日：2007-09-27
申请号：PCT/US2007/003317
申请日：2007-02-07
申请人： GENERAL ELECTRIC COMPANY , DI, Jianbo , MULLEN, Brian , SYBERT, Paul, Dean
发明人： DI, Jianbo , MULLEN, Brian , SYBERT, Paul, Dean
IPC分类号： C08G64/18
CPC分类号： C08G64/18 , C08F293/005 , C08L53/00 , C08L69/00 , Y10T428/31504 , Y10T428/31507 , C08L2666/14 , C08L2666/02 , C08L2666/18
摘要： A polyacrylate-polycarbonate copolymer comprises a polycarbonate block comprising aromatic carbonate units, and a polyacrylate block derived from a difunctional polyacrylate polymer having the formula: Z 1 -(M) x -Z 2 , wherein M is an acrylate block unit comprising a reaction residue of a (meth)acrylate monomer, a non-(meth)acrylate monomer, or a. combination comprising a (meth)acrylate and a non-(meth)acrylate monomer, at least one acrylate block unit is a (meth)acrylate monomer; x is greater than one; and Z 1 and Z 2 are each independently functionalized terminal groups of the formula: -(A 3 ) y -B, wherein B is a reactive group comprising a hydroxy or non-hydroxy group, A 3 an aliphatic group, an aromatic group, or an aliphatic-aromatic group, y is 0 or 1, A 3 is free of hydrogen atoms beta to B when B is a hydroxy group, and B and A 3 are each free of sulfur atoms. A method of making, a thermoplastic composition, and articles are also disclosed.
摘要翻译：聚丙烯酸酯 - 聚碳酸酯共聚物包括含有芳族碳酸酯单元的聚碳酸酯嵌段和衍生自具有下式的双官能聚丙烯酸酯聚合物的聚丙烯酸酯嵌段：（Z） - （M） Z 2，其中M是包含（甲基）丙烯酸酯单体，非（甲基）丙烯酸酯单体，或（甲基）丙烯酸酯单体的反应残基的丙烯酸酯嵌段单元。包含（甲基）丙烯酸酯和非（甲基）丙烯酸酯单体的组合物，至少一种丙烯酸酯嵌段单元是（甲基）丙烯酸酯单体; x大于1; 和Z 1和Z 2各自独立地是下式的官能化的末端基团： - （A 3 S 3） -B，其中B是包含羟基或非羟基的反应性基团，脂族基团，芳族基团或脂族 - 芳族基团，y为0或1，A < 当B是羟基时，SUP 3不含有B的氢原子，B和A 3都不含硫原子。还公开了制备方法，热塑性组合物和制品。

10. 发明申请

WO2020112591A1 SULFUR-STABILIZED THERMOPLASTIC COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
公开(公告)号：WO2020112591A1
公开(公告)日：2020-06-04
申请号：PCT/US2019/062920
申请日：2019-11-25
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , MAHOOD, James Alan , HOOVER, James Franklin , CALVERAS, Jordi
IPC分类号： C08L69/00
摘要： A copolycarbonate included 2-95 mole percent of high heat carbonate units derived from a high heat aromatic dihydroxy monomer, wherein a polycarbonate homopolymer derived from the high heat aromatic dihydroxy monomer has a glass transition temperature of 175-330C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, and 5-98 mole percent of a low heat carbonate units derived from a low heat aromatic monomer, wherein a polycarbonate homopolymer derived from the low heat aromatic monomer has a glass transition temperature of less than 170C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, each based on the sum of the moles of the carbonate units; and a sulfur-containing stabilizer compound, wherein the sulfur-containing stabilizer compound is a thioether carboxy compound, a thioether dicarboxy compound, a thioether ester compound, or a combination thereof, wherein the sulfur-containing stabilizer compound is present in an amount effective to provide 5-50 parts per million by weight of added sulfur, based on the total parts by weight of the copolycarbonate, wherein a source of the added sulfur is the sulfur-containing stabilizer.

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