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1. 发明授权

US09138729B2 Catalyst and method for producing maleic anhydride 有权
标题翻译：用于生产马来酸酐的催化剂和方法
公开(公告)号：US09138729B2
公开(公告)日：2015-09-22
申请号：US13141139
申请日：2009-12-21
申请人： Cornelia Katharina Dobner , Stefan Altwasser , Hagen Wilmer , Frank Rosowski
发明人： Cornelia Katharina Dobner , Stefan Altwasser , Hagen Wilmer , Frank Rosowski
IPC分类号： C07D307/34 , B01J27/198 , B01J35/02 , B01J35/10 , B01J37/00 , C07C51/215 , B01J35/00
CPC分类号： B01J35/023 , B01J27/198 , B01J35/002 , B01J35/02 , B01J35/026 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0018 , C07C51/215 , Y10T428/2975 , C07C57/145
摘要： The invention relates to a catalyst molded body for preparing maleic anhydride by gas-phase oxidation of a hydrocarbon having at least four carbon atoms using a catalytically active composition contains vanadium, phosphorus and oxygen, where the shaped catalyst body has an essentially cylindrical body having a longitudinal axis, wherein the cylindrical body has at least two parallel internal holes which are essentially parallel to the cylinder axis of the body and go right through the body. The catalyst molded body has a large outer surface area, a lower pressure loss and sufficient mechanical stability.
摘要翻译：本发明涉及一种用于通过使用含有钒，磷和氧的催化活性组合物通过气相氧化具有至少四个碳原子的烃来制备马来酸酐的催化剂成型体，其中成形催化剂体具有基本上圆柱形的体，其具有其中所述圆柱体具有至少两个平行的内孔，所述至少两个平行的内孔基本上平行于所述主体的气缸轴线并且直接穿过所述主体。催化剂成型体具有大的外表面积，较低的压力损失和足够的机械稳定性。

2. 发明申请

US20120071688A1 PROCESS FOR PREPARING ACRYLIC ACID FROM METHANOL AND ACETIC ACID 有权
标题翻译：从甲醇和乙酸制备丙烯酸的方法
公开(公告)号：US20120071688A1
公开(公告)日：2012-03-22
申请号：US13233560
申请日：2011-09-15
申请人： Stefanie HERZOG , Stefan Altwasser , Klaus Joachim Mueller-Engel
发明人： Stefanie HERZOG , Stefan Altwasser , Klaus Joachim Mueller-Engel
IPC分类号： C07C57/04 , C07C51/36
CPC分类号： C07C45/38 , B01J23/002 , B01J23/881 , B01J27/198 , B01J35/0006 , B01J35/023 , B01J37/0009 , B01J37/0045 , B01J2523/00 , C07B2200/05 , C07C51/353 , C07C51/44 , C07C57/04 , C07C47/04 , B01J2523/51 , B01J2523/55 , B01J2523/842
摘要： A process for preparing acrylic acid from methanol and acetic acid, in which, in a reaction zone A, the methanol is partially oxidized to formaldehyde in a heterogeneously catalyzed gas phase reaction, the product gas mixture A obtained and an acetic acid source are used to obtain a reaction gas input mixture B which comprises acetic acid and formaldehyde and has the acetic acid in excess over the formaldehyde, and the formaldehyde present in reaction gas input mixture B is aldol-condensed to acrylic acid under heterogeneous catalysis in a reaction zone B with acetic acid present in reaction gas input mixture B, and unconverted acetic acid still present alongside the acrylic acid target product in the product gas mixture B obtained is removed therefrom, and the acetic acid removed is recycled into the production of reaction gas input mixture B.
摘要翻译：一种从甲醇和乙酸制备丙烯酸的方法，其中在反应区A中甲醇在异质催化气相反应中部分氧化成甲醛，得到的产物气体混合物A和乙酸源用于得到包含乙酸和甲醛并且乙酸超过甲醛的反应气体输入混合物B，反应气体输入混合物B中存在的甲醛在反应区B内的非均相催化下醛醇缩合成丙烯酸，存在于反应气体输入混合物B中的乙酸和从得到的产物气体混合物B中仍然存在于丙烯酸目标产物旁边的未转化的乙酸，将除去的乙酸循环到反应气体输入混合物B的生产中。

3. 发明申请

US20080177105A1 PROCESS FOR PREPARING SHAPED CATALYST BODIES WHOSE ACTIVE COMPOSITION IS A MULTIELEMENT OXIDE 有权
标题翻译：活性成分为多种氧化物制备形成催化剂体的方法
公开(公告)号：US20080177105A1
公开(公告)日：2008-07-24
申请号：US12015741
申请日：2008-01-17
申请人： Andreas Raichle , Frank Rosowski , Sabine Huber , Ulrich Cremer , Stefan Altwasser , Klaus Joachim Mueller-Engel
发明人： Andreas Raichle , Frank Rosowski , Sabine Huber , Ulrich Cremer , Stefan Altwasser , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/16 , C07C51/235 , C07C45/27 , B01J21/18 , B01J35/08
CPC分类号： B01J32/00 , B01J21/18 , B01J23/002 , B01J23/8885 , B01J27/186 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C51/215 , C07C51/252 , C07C57/04 , C07C57/145 , B01J2523/13 , B01J2523/27 , B01J2523/41 , B01J2523/51 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/845 , B01J2523/15 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/62 , B01J2523/69
摘要： A process for preparing shaped catalyst bodies whose active composition is a multielement oxide, in which a finely divided precursor mixture with addition of graphite having a specific particle size is shaped to the desired geometry and then treated thermally.
摘要翻译：一种制备活性组合物为多元素氧化物的成形催化剂体的方法，其中加入具有特定粒度的石墨的细碎前体混合物成形为所需几何形状，然后热处理。

4. 发明授权

US08901320B2 Process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride 有权
标题翻译：控制气相氧化反应器制备邻苯二甲酸酐的方法
公开(公告)号：US08901320B2
公开(公告)日：2014-12-02
申请号：US13085537
申请日：2011-04-13
申请人： Stefan Altwasser , Jürgen Zühlke , Hao Chen , Cornelia Katharina Dobner , Frank Rosowski
发明人： Stefan Altwasser , Jürgen Zühlke , Hao Chen , Cornelia Katharina Dobner , Frank Rosowski
IPC分类号： C07D307/89
CPC分类号： C07D307/89
摘要： In a process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride, by passing a gas stream which comprises an aromatic hydrocarbon and molecular oxygen through a multitude of reaction tubes arranged in the gas phase oxidation reactor, each of which comprises a bed of at least one catalyst and the temperature of which can be controlled by means of a heat transfer medium, at least one control parameter is measured and correcting interventions for control of the control parameter are determined, the at least one control parameter comprising the phthalic anhydride yield and the correcting parameter used being the temperature of the heat carrier medium. Over at least 90% of the lifetime of the catalyst, the change in the correcting parameter is limited to a maximum of 0.5 K within a period of 30 days. In this way, the cumulated phthalic anhydride yield over the lifetime of the catalyst is maximized.
摘要翻译：在控制用于制备邻苯二甲酸酐的气相氧化反应器的方法中，通过将包含芳族烃和分子氧的气流通过布置在气相氧化反应器中的多个反应管通过，每个反应管包括一个床至少一种催化剂，其温度可以通过传热介质控制，测量至少一个控制参数，并且确定用于控制控制参数的校正干预，所述至少一个控制参数包括邻苯二甲酸酐产率并且所使用的校正参数是热载体介质的温度。在催化剂寿命的至少90％之内，校正参数的变化在30天的时间内被限制为最大0.5K。以这种方式，在催化剂寿命期间累积的邻苯二甲酸酐产率最大化。

5. 发明申请

US20140213801A1 MULTILAYER CATALYST HAVING VANADIUM ANTIMONATE IN AT LEAST ONE CATALYST LAYER FOR PREPARING CARBOXYLIC ACIDS AND/OR CARBOXYLIC ANHYDRIDES AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE HAVING A LOW HOT SPOT TEMPERATURE 审中-公开
标题翻译：用于制备碳羧酸和/或羧酸酐的至少一种催化剂层中的抗氧化剂的多层催化剂和用于制备具有低热点温度的苯基氢醌的方法
公开(公告)号：US20140213801A1
公开(公告)日：2014-07-31
申请号：US14242979
申请日：2014-04-02
申请人： Stefan Altwasser , Jürgen Zühlke , Frank Rosowski , Cornelia Katharina Dobner
发明人： Stefan Altwasser , Jürgen Zühlke , Frank Rosowski , Cornelia Katharina Dobner
IPC分类号： C07D307/89
CPC分类号： C07D307/89 , B01J23/002 , B01J23/22 , B01J35/0006 , B01J2523/00 , C07C51/265 , C07C63/16 , B01J2523/53 , B01J2523/55
摘要： The present invention relates to a catalyst system for preparing carboxylic acids and/or carboxylic anhydrides, which system comprises a plurality of superposed catalyst layers arranged in a reaction tube, where vanadium antimonate is introduced into the active material in at least one of the catalyst layers. The present invention further relates to a process for gas-phase oxidation, in which a gaseous stream comprising at least one hydrocarbon and molecular oxygen is passed through a plurality of catalyst layers and the maximum hot spot temperature is below 425° C.
摘要翻译：本发明涉及一种用于制备羧酸和/或羧酸酐的催化剂体系，该系统包括布置在反应管中的多个重叠的催化剂层，其中锑酸锑在至少一个催化剂层中被引入到活性材料中。本发明还涉及一种用于气相氧化的方法，其中包含至少一种烃和分子氧的气流通过多个催化剂层，最大热点温度低于425℃。

6. 发明授权

US08546295B2 Process for preparing shaped catalyst bodies whose active composition is a multielement oxide 有权
标题翻译：制备活性组合物为多元素氧化物的成型催化剂体的方法
公开(公告)号：US08546295B2
公开(公告)日：2013-10-01
申请号：US12015741
申请日：2008-01-17
申请人： Andreas Raichle , Frank Rosowski , Sabine Huber , Ulrich Cremer , Stefan Altwasser , Klaus Joachim Mueller-Engel
发明人： Andreas Raichle , Frank Rosowski , Sabine Huber , Ulrich Cremer , Stefan Altwasser , Klaus Joachim Mueller-Engel
IPC分类号： B01J23/00 , C07C51/16
CPC分类号： B01J32/00 , B01J21/18 , B01J23/002 , B01J23/8885 , B01J27/186 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C51/215 , C07C51/252 , C07C57/04 , C07C57/145 , B01J2523/13 , B01J2523/27 , B01J2523/41 , B01J2523/51 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/845 , B01J2523/15 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/62 , B01J2523/69
摘要： A process for preparing shaped catalyst bodies whose active composition is a multielement oxide, in which a finely divided precursor mixture with addition of graphite having a specific particle size is shaped to the desired geometry and then treated thermally.
摘要翻译：一种制备活性组合物为多元素氧化物的成形催化剂体的方法，其中加入具有特定粒径的石墨的细碎前体混合物成形为所需几何形状，然后热处理。

7. 发明申请

US20120149919A1 MALEIC ANHYDRIDE SYNTHESIS CATALYST PRECURSOR AND PROCESS FOR ITS PREPARATION 审中-公开
标题翻译：马来酸酐合成催化剂前体及其制备方法
公开(公告)号：US20120149919A1
公开(公告)日：2012-06-14
申请号：US13391958
申请日：2010-08-23
申请人： Stefan Altwasser , Cornelia Katharina Dobner , Hagen Wilmer , Frank Rosowski
发明人： Stefan Altwasser , Cornelia Katharina Dobner , Hagen Wilmer , Frank Rosowski
IPC分类号： B01J27/198 , C07D307/60 , C01B25/37
CPC分类号： B01J27/198 , B01J23/002 , B01J35/002 , B01J35/023 , B01J35/026 , B01J37/0009 , B01J37/031 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C57/145 , B01J2523/51 , B01J2523/55
摘要： A process for preparing a vanadium, phosphorus, and oxygen comprising catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms, which comprises (a) reacting vanadium pentoxide with 102% to 110% strength phosphoric acid in the presence of isobutanol and optionally of a primary or secondary, noncyclic or cyclic, unbranched or branched, saturated alcohol having 3 to 6 carbon atoms in a temperature range from 80 to 160° C.; (b) isolating the precipitate formed; (c) (i) drying the isolated precipitate down to a residual isobutanol content of less than 5% by weight; (ii) then passing a gas which in addition to one or more inert gases comprises 0.1% to 9% by volume of oxygen through the dried precipitate, directly or after isolation, in the temperature range from 130° C. to 200° C.
摘要翻译：一种制备钒，磷和氧的方法，包括通过异构催化气相氧化具有至少四个碳原子的烃来制备马来酸酐的催化剂前体，其包括（a）五氧化二钒与102％至110％的强度磷酸在异丁醇存在下和任选的在80至160℃的温度范围内具有3至6个碳原子的伯或仲，非环或环状，无支链或支链的饱和醇。（b）分离形成的沉淀物; （c）（i）将分离的沉淀物干燥至低于5重量％的残余异丁醇含量; （ii）然后在130℃至200℃的温度范围内直接或分离后通过除一种或多种惰性气体外还含有0.1％至9％（体积）氧气的气体。

8. 发明申请

US20110251405A1 PROCESS FOR CONTROLLING A GAS PHASE OXIDATION REACTOR FOR PREPARATION OF PHTHALIC ANHYDRIDE 有权
标题翻译：用于控制气相氧化反应器的方法，用于制备PHALALAL ANHYDRIDE
公开(公告)号：US20110251405A1
公开(公告)日：2011-10-13
申请号：US13085537
申请日：2011-04-13
申请人： Stefan Altwasser , Jürgen Zühlke , Hao Chen , Cornelia Katharina Dobner , Frank Rosowski
发明人： Stefan Altwasser , Jürgen Zühlke , Hao Chen , Cornelia Katharina Dobner , Frank Rosowski
IPC分类号： C07D307/89
CPC分类号： C07D307/89
摘要： In a process for controlling a gas phase oxidation reactor for preparation of phthalic anhydride, by passing a gas stream which comprises an aromatic hydrocarbon and molecular oxygen through a multitude of reaction tubes arranged in the gas phase oxidation reactor, each of which comprises a bed of at least one catalyst and the temperature of which can be controlled by means of a heat transfer medium, at least one control parameter is measured and correcting interventions for control of the control parameter are determined, the at least one control parameter comprising the phthalic anhydride yield and the correcting parameter used being the temperature of the heat carrier medium. Over at least 90% of the lifetime of the catalyst, the change in the correcting parameter is limited to a maximum of 0.5 K within a period of 30 days. In this way, the cumulated phthalic anhydride yield over the lifetime of the catalyst is maximized.
摘要翻译：在控制用于制备邻苯二甲酸酐的气相氧化反应器的方法中，通过将包含芳族烃和分子氧的气流通过布置在气相氧化反应器中的多个反应管通过，每个反应管包括一个床至少一种催化剂，其温度可以通过传热介质控制，测量至少一个控制参数，并且确定用于控制控制参数的校正干预，所述至少一个控制参数包括邻苯二甲酸酐产率并且所使用的校正参数是热载体介质的温度。在催化剂寿命的至少90％之内，校正参数的变化在30天的时间内被限制为最大0.5K。以这种方式，在催化剂寿命期间累积的邻苯二甲酸酐产率最大化。

9. 发明申请

US20110144387A1 PROCESS FOR PREPARING C1-C4-OXYGENATES BY PARTIAL OXIDATION OF HYDROCARBONS 有权
标题翻译：通过部分氧化制备C1-C4氧化剂的方法
公开(公告)号：US20110144387A1
公开(公告)日：2011-06-16
申请号：US12967337
申请日：2010-12-14
申请人： ANNEBART ENGBERT WENTINK , STEFAN ALTWASSER , YAN LI , MICHAEL KRÄMER , FRANK ROSOWSKI , CATHARINA HORSTMANN
发明人： ANNEBART ENGBERT WENTINK , STEFAN ALTWASSER , YAN LI , MICHAEL KRÄMER , FRANK ROSOWSKI , CATHARINA HORSTMANN
IPC分类号： C07C27/10
CPC分类号： C07C29/50 , C07C45/33 , C07C51/215 , C07C31/04 , C07C47/22 , C07C57/04
摘要： A process for preparing C1-C4-oxygenates from a reactant stream A which comprises essentially a C1-C4-alkane or a mixture of C1-C4-alkanes, by a) branching off a substream B of the reactant stream A and allowing it to react in a reactor with oxygen or an oxygenous gas stream C, which converts a portion of the C1-C4-alkane or a portion of the mixture which comprises C1-C4-alkanes to C1-C4-oxygenates, b) removing at least 90 mol % of the C1-C4-oxygenates formed from the product stream D resulting from step a) to form a remaining low boiler stream E, which comprises combining the low boiler stream E with the reactant stream A without further workup and without combination with the substream B down-stream of the branching site of the substream B.
摘要翻译： a）从反应物流A制备C1-C4-含氧化合物的方法，该反应物流A基本上包含C 1 -C 4烷烃或C 1 -C 4烷烃的混合物，a）将反应物流A的分支B分支，在反应器中与氧或有氧气流C反应，C将C1-C4烷烃的一部分或包含C1-C4烷烃的混合物的一部分转化为C1-C4-氧化物，b）除去至少90 由步骤a）产生的产物流D形成的C1-C4-含氧化合物的摩尔％，以形成剩余的低沸点物流E，其包括将低沸点物流E与反应物流A组合而不进一步处理，并且不与子流B的分支位点下游的子流B

10. 发明授权

US09212157B2 Catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride 有权
标题翻译：用于将邻二甲苯和/或萘氧化成邻苯二甲酸酐的催化剂
公开(公告)号：US09212157B2
公开(公告)日：2015-12-15
申请号：US13194126
申请日：2011-07-29
申请人： Stefan Altwasser , Jürgen Zühlke , Frank Rosowski , Michael Krämer
发明人： Stefan Altwasser , Jürgen Zühlke , Frank Rosowski , Michael Krämer
IPC分类号： B01J23/22 , C07D307/89 , B01J35/00 , B01J35/10 , B01J37/00 , B01J35/02
CPC分类号： C07D307/89 , B01J23/22 , B01J35/002 , B01J35/026 , B01J35/1014 , B01J37/0045
摘要： The present invention relates to a catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride, which has a plurality of catalyst zones which are arranged in series in the reaction tube and have been produced using an antimony trioxide which comprises a significant proportion of valentinite. The present invention further relates to a process for gas-phase oxidation, in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst produced using an antimony trioxide which comprises a significant proportion of valentinite.
摘要翻译：本发明涉及用于将邻二甲苯和/或萘氧化成邻苯二甲酸酐的催化剂，其具有多个催化剂区，其在反应管中串联排列并且已经使用三氧化锑生产，所述三氧化锑包含显着的百分比的比例。本发明还涉及一种用于气相氧化的方法，其中包含至少一种烃和分子氧的气流通过使用三氧化锑生成的催化剂，所述三氧化锑包含显着比例的极性。

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