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    • 1. 发明授权
    • Monomers for preparing arylamine-substituted poly(arylene-vinylenes)
    • 用于制备芳基胺取代的聚(亚芳基 - 烯烃)的单体
    • US6372881B2
    • 2002-04-16
    • US91292701
    • 2001-07-24
    • STANFORD RES INST INT
    • PEI QIBING
    • C07C211/56C08G61/02H01L27/32H01L51/30H01L51/50C08G61/00C08G12/02
    • H01L51/5012C07C211/56C08G61/02H01L51/0036H01L51/0038H01L51/0059Y02E10/549Y10S428/917
    • The invention provides novel conjugated polymers comprised of arylamine-substituted poly(arylene vinylenes). The polymers have the general structure (I)wherein: Ar is arylene, heteroarylene, substituted arylene or substituted heteroarylene containing one to three aromatic rings; R1 is an arylamine substituent having the formula -Ar1-N(R4R5) wherein Ar1 is as defined for Ar and R4 and R5 are independently hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, or substituted heteroatom-containing hydrocarbyl, or together form a cyclic group; and R2 and R3 are independently selected from the group consisting of hydrido, halo and cyano, or may be as defined for R4 and R5, or may together form a triple bond. Monomeric precursors and methods of synthesizing the precursors are also provided, as are electroluminescence and other devices containing a polymer of the invention.
    • 本发明提供由芳基胺取代的聚(亚芳基乙烯基)构成的新型共轭聚合物。 聚合物具有通式(I),其中:Ar是亚芳基,亚杂芳基,取代的亚芳基或含1至3个芳环的取代的亚杂芳基; R1是具有式-Ar1-N(R4R5)的芳基胺取代基,其中Ar1如对Ar和R4所定义,R5独立地是烃基,取代的烃基,含杂原子的烃基或取代的含杂原子的烃基,或一起形成环状 组; 并且R 2和R 3独立地选自氢,卤素和氰基,或可以如R4和R5所定义,或者可以一起形成三键。 还提供单体前体和合成前体的方法,电致发光和含有本发明聚合物的其它装置也是如此。