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1. 发明申请

US20150291788A1 DURABLE POLYHYDROXYALKANOATE COMPOSITIONS 审中-公开
标题翻译：耐久性聚羟基烷基酯组合物
公开(公告)号：US20150291788A1
公开(公告)日：2015-10-15
申请号：US14379810
申请日：2013-02-21
申请人： SO.F.TER.SPA
发明人： Alessandro Carfagnini , Leonardo Bellomo
IPC分类号： C08L67/04
CPC分类号： C08L67/04 , C08L23/0869 , C08L23/0884 , C08L51/04 , C08L75/04 , C08L2201/06 , C08L2203/12 , C08L2203/16 , C08L2207/04
摘要： A polyhydroxyalkanoate composition, having a an elongation at break (ASTM D648) greater than 3%, an impact resistance (IS0179 1 eA, 23° C., unnotched) greater than 18 KJ/m2 and a flexural modulus of at least 950 MPa, includes at least 25% wt of a polyhydroxyalkanoate component (I); from 5 to 40% wt of one or more thermoplastic polymers as a non-polyhydroxyalkanoate component (II); from 0 to 40% wt of one or more fillers (III); from 0 to 20% wt of one or more plasticizers (IV); and from 0 to 10% wt of one or more additives (V). The polyhydroxyalkanoate composition can be used for the preparation of durable goods that may be labelled as containing more than 20% non-fossil carbon, and for articles prepared therefrom.
摘要翻译：具有大于3％的断裂伸长率（ASTM D648），大于18KJ / m 2的抗冲击性（IS01791eA，23℃，无缺口）和至少950MPa的弯曲模量的聚羟基链烷酸酯组合物，包括至少25重量％的聚羟基链烷酸酯组分（I）; 一种或多种作为非聚羟基链烷酸酯组分（II）的热塑性聚合物的重量百分比为5-40％ 0至40重量％的一种或多种填料（III）; 0至20重量％的一种或多种增塑剂（IV）; 和0至10重量％的一种或多种添加剂（V）。聚羟基链烷酸酯组合物可用于制备可标记为含有超过20％非化石碳的耐用品，以及由其制备的制品。

2. 发明申请

WO2011092071A1 THERMOFUSIBLE COMPOSITION FOR SLUSH MOULDING 审中-公开
标题翻译：用于SLUSH模制的可热成分组合物
公开(公告)号：WO2011092071A1
公开(公告)日：2011-08-04
申请号：PCT/EP2011/050538
申请日：2011-01-17
申请人： SO.F.TER.SPA , BELLOMO, Leonardo , CARFIGNINI, Alessandro , STOL, Marianne , VERVOORT, Freddy M.A. , KRATON POLYMERS U.S. LLC
发明人： BELLOMO, Leonardo , CARFIGNINI, Alessandro , STOL, Marianne , VERVOORT, Freddy M.A.
IPC分类号： C08L53/02 , B29C41/04 , B60K37/00
CPC分类号： C08L53/025 , B29C41/003 , B29C41/18 , B29K2105/0085 , C08L23/10 , C08L23/20 , Y10T428/2982 , C08L2666/02 , C08L2666/06
摘要： A thermofusible composition in the form of pellets and/or powder, with a particle size of 1400 μm or less comprising from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC), and from about 1 to about 30 weight percent of a butylene homopolymer, a butylene copolymer, or a combination of the butylene homopolymer and the copolymer, wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B) n , (A-B-A) n , (A-B-A) n X, (A-B) n X or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein: a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene; b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced; c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total number average molecular weight from about 70 to about 150 kg/mol and the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units; e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent; f. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent; g. each B block has a styrene blockiness index of less than 10 percent; and h. the weight percent of vinyl in each B block is at least about 40 weight percent.
摘要翻译：粒径为1400μm或更小的颗粒和/或粉末形式的热熔组合物，包含约40至约70重量％的选择性氢化苯乙烯嵌段共聚物（HSBC）和约1至约30重量％丁烯均聚物，丁烯共聚物或丁烯均聚物和共聚物的组合的百分比，其中HSBC（i）是具有通式ABA，（AB）n，（ABA）n的直链或支链氢化嵌段共聚物，（ABA）nX，（AB）nX或其混合物，其中n为2至约30的整数，X为偶联剂残基，其中：a。在氢化之前，每个A嵌段是单烯基芳烃聚合物嵌段，并且每个B嵌段是至少一种共轭二烯和至少一个单烯基芳烃的受控分布共聚物嵌段; 湾在氢化后约0-10％的芳烃双键已经被还原，并且至少约90％的共轭二烯双键已经被还原; C。每个A嵌段具有约5.0至约7.5kg / mol的数均分子量，并且其中线性HSBC具有约70至约150kg / mol的总数均分子量，并且分支HSBC具有总表观数均分子量每臂约35至约75kg / mol的分子量d。每个B嵌段包括与富含共轭二烯单元的A嵌段相邻的末端区域和不与A链段相邻且富含单烯基芳烃单元的一个或多个区域; 即氢化嵌段共聚物中单烯基芳烃的总量为约20至约45重量％; F。每个B嵌段中单烯基芳烃的重量百分比为约10至约40重量％; G。每个B嵌段的苯乙烯嵌段指数小于10％; 和h。每个B嵌段中乙烯基的重量百分比为至少约40重量％。

3. 发明申请

WO2013124361A1 DURABLE POLYHYDROXYALKANOATE COMPOSITIONS 审中-公开
标题翻译：耐久性聚羟基烷基酯组合物
公开(公告)号：WO2013124361A1
公开(公告)日：2013-08-29
申请号：PCT/EP2013/053468
申请日：2013-02-21
申请人： SO.F.TER.SPA
发明人： CARFAGNINI, Alessandro , BELLOMO, Leonardo
IPC分类号： C08L67/04
CPC分类号： C08L67/04 , C08L23/0869 , C08L23/0884 , C08L51/04 , C08L75/04 , C08L2201/06 , C08L2203/12 , C08L2203/16 , C08L2207/04
摘要： A polyhydroxyalkanoate composition, suitably having a an elongation at break (ASTM D648) greater than 3%, an impact resistance (IS0179 1 eA, 23°C, unnotched) greater than 18 KJ/m2 and a flexural modulus of at least 950 MPa, comprising: - at least 25 %wt of a polyhydroxyalkanoate component (I), comprising one or more hydroxyalkanoate copolymers and wherein the content of poly(3-hydroxybutyrate) homopolymer is less than 5 %wt; - from 5 to 40 %wt of one or more thermoplastic polymers as a non- polyhydroxyalkanoate component (II), selected from the group consisting of (lla) a thermoplastic polyurethane; a mixture of a thermoplastic polyurethane (lla) and (lib) an acrylic polymer; an acrylic block copolymer (I Ib1 ) with a core that is butadiene based and/or acrylic based rubber and that is crosslinked; an acrylic terpolymer (Ilb2) containing glycidyl and/or maleic groups; and mixtures thereof, comprising no more than 5 %wt biodegradable polymers (ASTM D6400); - from 0 to 40 %wt of one or more fillers (III); - from 0 to 20 %wt of one or more plasticizers (IV); and - from 0 to 10 %wt of one or more additives (V), wherein component (I) and (II) together comprise at least 40 %wt of the composition, and the %wt of the components is calculated on the total weight of components (I) to (V) of the composition and adds up to 100 %wt. The polyhydroxyalkanoate composition can be used for the preparation of durable goods that may be labelled as containing more than 20% non-fossil carbon, and for articles prepared therefrom.
摘要翻译：合适地具有大于3％的断裂伸长率（ASTM D648），大于18KJ / m 2的抗冲击性（IS01791eA，23℃，无缺口）和至少950MPa的弯曲模量的聚羟基链烷酸酯组合物，包括： - 至少25重量％的聚羟基链烷酸酯组分（I），其包含一种或多种羟基链烷酸酯共聚物，并且其中聚（3-羟基丁酸酯）均聚物的含量小于5重量％ - 5至40重量％的一种或多种作为非聚羟基链烷酸酯组分（II）的热塑性聚合物，其选自（Ia）热塑性聚氨酯; 热塑性聚氨酯（11a）和（lib）丙烯酸类聚合物的混合物; 具有基于丁二烯和/或丙烯酸系橡胶的芯的交联的丙烯酸系嵌段共聚物（I Ib1）含有缩水甘油基和/或马来酸基团的丙烯酸三元共聚物（IIb2）和其混合物，包含不超过5重量％的可生物降解的聚合物（ASTM D6400）; - 0至40重量％的一种或多种填料（III）; - 0至20重量％的一种或多种增塑剂（IV）; 和 - 0至10重量％的一种或多种添加剂（V），其中组分（I）和（II）一起包含至少40重量％的组合物，并且组分的重量％按总重量计算的组分（I）至（V），并加入至100重量％聚羟基链烷酸酯组合物可用于制备可标记为含有20％以上非化石碳的耐用品，以及由其制备的制品。

4. 发明公开

EP2817372A1 DURABLE POLYHYDROXYALKANOATE COMPOSITIONS 有权转让
标题翻译：耐用COMPOSITIONS聚羟基脂肪酸
公开(公告)号：EP2817372A1
公开(公告)日：2014-12-31
申请号：EP13705194.2
申请日：2013-02-21
申请人： SO.F.TER.SPA
发明人： CARFAGNINI, Alessandro , BELLOMO, Leonardo
IPC分类号： C08L67/04
CPC分类号： C08L67/04 , C08L23/0869 , C08L23/0884 , C08L51/04 , C08L75/04 , C08L2201/06 , C08L2203/12 , C08L2203/16 , C08L2207/04
摘要： A polyhydroxyalkanoate composition, having a an elongation at break (ASTM D648) greater than 3%, an impact resistance (IS0179 1 eA, 23° C., unnotched) greater than 18 KJ/m2 and a flexural modulus of at least 950 MPa, includes at least 25% wt of a polyhydroxyalkanoate component (I); from 5 to 40% wt of one or more thermoplastic polymers as a non-polyhydroxyalkanoate component (II); from 0 to 40% wt of one or more fillers (III); from 0 to 20% wt of one or more plasticizers (IV); and from 0 to 10% wt of one or more additives (V). The polyhydroxyalkanoate composition can be used for the preparation of durable goods that may be labelled as containing more than 20% non-fossil carbon, and for articles prepared therefrom.

5. 发明授权

EP2406315B1 THERMOFUSIBLE COMPOSITION FOR SLUSH MOULDING 有权转让
标题翻译：热熔组成FOR壳型铸造
公开(公告)号：EP2406315B1
公开(公告)日：2012-07-04
申请号：EP11700281.6
申请日：2011-01-17
申请人： SO.F.TER.SPA , Kraton Polymers US LLC
发明人： BELLOMO, Leonardo , CARFAGNINI, Alessandro , STOL, Marianne , VERVOORT, Freddy M.A.
IPC分类号： C08L53/02 , B29C41/00 , B29C41/18
CPC分类号： C08L53/025 , B29C41/003 , B29C41/18 , B29K2105/0085 , C08L23/10 , C08L23/20 , Y10T428/2982 , C08L2666/02 , C08L2666/06
摘要： A thermofusible composition in the form of pellets and/or powder, with a particle size of 1400 μm or less comprising from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC), and from about 1 to about 30 weight percent of a butylene homopolymer, a butylene copolymer, or a combination of the butylene homopolymer and the copolymer, wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B)
n , (A-B-A)
n , (A-B-A)
n X, (A-B)
n X or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein: a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene; b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced; c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total number average molecular weight from about 70 to about 150 kg/mol and the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units; e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent; f. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent; g. each B block has a styrene blockiness index of less than 10 percent; and h. the weight percent of vinyl in each B block is at least about 40 weight percent.

6. 发明公开

EP2406315A1 THERMOFUSIBLE COMPOSITION FOR SLUSH MOULDING 有权转让
标题翻译：热熔组成FOR壳型铸造
公开(公告)号：EP2406315A1
公开(公告)日：2012-01-18
申请号：EP11700281.6
申请日：2011-01-17
申请人： SO.F.TER.SPA , Kraton Polymers US LLC
发明人： BELLOMO, Leonardo , CARFAGNINI, Alessandro , STOL, Marianne , VERVOORT, Freddy M.A.
IPC分类号： C08L53/02 , B29C41/04 , B60K37/00
CPC分类号： C08L53/025 , B29C41/003 , B29C41/18 , B29K2105/0085 , C08L23/10 , C08L23/20 , Y10T428/2982 , C08L2666/02 , C08L2666/06
摘要： A thermofusible composition in the form of pellets and/or powder, with a particle size of 1400 μm or less comprising from about 40 to about 70 weight percent of a selectively hydrogenated styrenic block copolymer (HSBC), and from about 1 to about 30 weight percent of a butylene homopolymer, a butylene copolymer, or a combination of the butylene homopolymer and the copolymer, wherein the HSBC (i) is a linear or branched hydrogenated block copolymer having the general configuration A-B-A, (A-B)
n , (A-B-A)
n , (A-B-A)
n X, (A-B)
n X or mixtures thereof, where n is an integer from 2 to about 30, and X is coupling agent residue and wherein: a. prior to hydrogenation each A block is a mono alkenyl arene polymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene; b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced; c. each A block has a number average molecular weight from about 5.0 to about 7.5 kg/mol and, wherein the linear HSBC has a total number average molecular weight from about 70 to about 150 kg/mol and the branched HSBC has a total apparent number average molecular weight from about 35 to about 75 kg/mol per arm d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units; e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 to about 45 weight percent; f. the weight percent of mono alkenyl arene in each B block is from about 10 to about 40 weight percent; g. each B block has a styrene blockiness index of less than 10 percent; and h. the weight percent of vinyl in each B block is at least about 40 weight percent.

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