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    • 2. 发明申请
    • HETEROJUNCTION DEVICE
    • 异位设备
    • WO2011030117A1
    • 2011-03-17
    • PCT/GB2010/001728
    • 2010-09-13
    • ISIS INNOVATION LIMITEDSNAITH, Henry, J.
    • SNAITH, Henry, J.
    • H01L51/42
    • H01L51/4226H01L51/0036H01L51/0039H01L51/0059H01L51/0071H01L51/0078H01L51/0086H01L51/422Y02E10/549
    • A solid-state p-n heterojunction comprising an organic p-type material in contact with an n-type material wherein said n-type material is surface-sensitised by at least two sensitizing agents comprising an energy donor sensitizing agent and an energy acceptor sensitizing agent and optionally at least one intermediate sensitizing agent, wherein the emission spectrum of the donor sensitizing agent overlaps with the absorption spectrum of the acceptor sensitizing agent and/or at least one intermediate sensitizing agent where present, and the emission spectrum of at least one intermediate sensitizing agent where present overlaps with the absorption spectrum of the acceptor sensitizing agent and wherein the acceptor sensitizing agent individually has a maximum Absorbed Photon to electron Conversion Efficiency of no less than 40% in an equivalent heterojunction when used as sole sensitizing agent.. The invention also provides optoelectronic devices such as solar cells or photo sensors comprising such a p-n heterojunction, and methods for the manufacture of such a heterojunction or device.
    • 一种固态pn异质结,包括与n型材料接触的有机p型材料,其中所述n型材料由至少两种包含能量供体敏化剂和能量受体敏化剂的敏化剂表面敏化, 任选的至少一种中间敏化剂,其中供体增感剂的发射光谱与受体敏化剂和/或至少一种中间增感剂的吸收光谱重叠,并且至少一种中间敏化剂的发射光谱 其中存在与受体敏化剂的吸收光谱重叠,并且其中当用作唯一敏化剂时,受体敏化剂在等效异质结中分别具有不小于40%的最大吸收光子至电子转换效率。本发明还提供 光电器件如太阳能电池或光电传感器 唱这样的p-n异质结,以及制造这种异质结或器件的方法。