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    • 3. 发明申请
    • REACTION PRODUCTS FROM OLEFINICALLY UNSATURATED CARBOXYLIC ACIDS AND POLYETHEROLS AND THEIR USE AS DEMULSIFYING AGENTS FOR CRUDE OIL EMULSIONS
    • 反应产物烯属不饱和羧酸和聚醚醇及其作为破乳剂为原油乳液
    • WO1995004771A1
    • 1995-02-16
    • PCT/EP1994002487
    • 1994-07-28
    • BASF AKTIENGESELLSCHAFTFAUL, DieterROSER, JoachimHARTMANN, HeinrichVOGEL, Hans-HenningSLOTMAN, WilhelmusKONRAD, Gerd
    • BASF AKTIENGESELLSCHAFT
    • C08G65/32
    • B01D17/047C08F220/26C08G63/676C08G65/3322C08G2650/20C08L2312/00C09K8/36C10G33/04
    • Reactions products from olefinically unsaturated carboxylic acids and polyetherols suitable as demulsyfing agents for crude oil emulsions are obtained by (A) condensing one or several unsaturated C3-C10-carboxylic acids or their derivatives having general formula (I), in which R and R stand for hydrogen, C1-C4-alkyl or carboxyl and R stands for hydrogen or methyl, and R may form a 5- or 6-membered anhydride ring with the carboxyl group, with a polyetherol having general formula (II), in which R stands for the residue of monohydric or polyhydric alcohol, phenol or alkyl phenol with 7 to 30 carbon atoms, or for the residue of a condensation product of an alkyl phenol/formaldehyde or alkyl phenol/acetaldehyde; R stands for a branched or straight chain C2-C4-alkylene group, whereas different [R -O] units may be present within a polyalkylene oxide chain; and X stands for an integer from 5 to 120. The molar ratio between the compounds (II) and (I) lies between 2:1 and 10:1 and their weight ratio lies between 25:1 and 1000:1. In a second step (B), the thus obtained condensation product is polymerised with one or several unsaturated carboxylic acids (I), and if required with other olefinically unsaturated monomers capable of being copolymerised with the carboxylic acids (I). The proportion of carboxylic acids (I) in the amount of olefinically unsaturated monomers amounts to 50 to 100 % by moles. The molar ratio of polyetherol (II) to the sum of olefinically unsaturated monomers used in steps (A) and (B) of the process lies between 1:5 and 1:200. In a final step (C), the thus obtained reaction mixture is condensed, provided that not all hydroxyl groups are reacted. Also disclosed is a process for preparing these reaction products, mixtures of the reaction products with organic solvents, and the use of the reaction products and of the mixtures as demulsifying agents for crude oil emulsions.
    • 作为破乳剂对原油乳液的烯属不饱和羧酸和聚醚醇,由A中的一个或多个不饱和C 3 -C 10羧酸或它们的通式(I)的衍生物缩合,其中R <1>和R <2>是氢可获得)合适的反应产物 <1>可以是C1-C4烷基或羧基,且R <3>是氢或甲基,且R与羧基形成5-或6-元酸酐环,与通式的聚醚醇(II),在该 [R <4>是基团单 - 或多元醇,酚或含有7至30个碳原子,基团的烷基苯酚/甲醛或烷基酚/乙醛缩合物,R的<5>表示支链或直链C烷基酚的 C4亚烷基,其中不同的单元[R <5> -O]可以是聚环氧烷链中存在,并且X为从5到120的整数,在化合物(II)以摩尔比( 1至10:1和25的重量比:1至1000:从2 I)1因此具有一个或多个不饱和羧酸(I)和任选的其它烯属不饱和(具有羧酸得到的缩合产物的,B)聚合I) 可共聚的单体,其中,所述的羧酸(I),以烯属不饱和单体的量的比例为50〜100摩尔%,并且其中的总和在过程烯中使用的聚醚醇(II)的摩尔比的步骤A)和B)的不饱和 5至1:1的单体200,以及随后的C)由此得到的,条件是并非所有的羟基基团被转化条件反应混合物的缩合,以及它们的制备方法,该反应产物用有机溶剂,以及使用的反应产物的混合物和 共混物作为破乳剂对原油乳液。
    • 6. 发明申请
    • PROCESS FOR PRODUCING OLIGOAMINES OR POLYAMINES
    • 用于生产低聚或多胺
    • WO1996011225A1
    • 1996-04-18
    • PCT/EP1995003809
    • 1995-09-26
    • BASF AKTIENGESELLSCHAFTMOHR, JürgenKNAUF, WolfgangBALZER, Wolf-DieterOPPENLÄNDER, KnutSLOTMAN, Wilhelmus
    • BASF AKTIENGESELLSCHAFT
    • C08G73/02
    • B01D17/047C07C213/04C08G65/2696C08G73/0213C10G33/04
    • Production of oxalkylates of oligoamines or polyamines in a two-stage process in which, in the first stage, a molecule of alkylene oxide per NH group is added to the oligoamine or polyamine in the presence of water, alcohols or acids or a mixture thereof in the absence of a neutral or basic catalyst and, in the second, after the removal of water and acids, a reaction is conducted with further alkylene oxide in the presence of a conventional neutral or basic catalyst. According to this method, one adds before the second stage an organic solvent or diluting agent or a mixture of such agents from the group: (a) alcohols and phenols and their alkoxylates, (b) polyalcohols based on ethylene oxide, propylene oxide, butylene oxide or a mixture thereof, (c) N-substituted carboxylic acid amides, (d) alkanol monoamines and alkanol polyamines and their alkoxylates, (e) other oxalkylates of oligo or polyamines, (f) aromatic hydrocarbons, (g) aliphatic hydrocarbons, (h) ether and (i) sulphones or sulphoxides.
    • 低聚胺或多胺的烷氧基化物通过两步骤操作制备,其中在第一阶段中,除了每NH基团在水,醇或酸或它们的混合物存在下的低聚胺或聚胺的烯化氧中的一个分子在不存在中性或碱性催化剂的其 通过之前执行所述第二步骤中,有机溶剂或稀释剂或这类试剂的选自一混合物与另外的烯化氧的常规中性或碱性催化剂的存在下进行的,并且其中在第二阶段中实施,除去水和酸后 的(a)醇类和酚,以及它们的烷氧基化物,(b)中其基于环氧乙烷,环氧丙烷,环氧丁烷或它们的混合物,(C)多元醇的N-取代的羧酰胺,(d)中链烷醇单胺和alkanolpolyamines及其烷氧基化物,(e)其他 烷氧基化物低聚胺或多胺( F)芳香烃,(克)脂族烃,(H)醚和(i)砜或亚砜溶液。