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    • 1. 发明申请
    • PROCESS FOR LIQUEFACTION OF NATURAL GAS
    • 自然气体液化过程
    • WO2012172281A3
    • 2013-12-05
    • PCT/GB2012000502
    • 2012-06-11
    • GASCONSULT LTDMAUNDER ANTHONY DWIGHTSKINNER GEOFFREY FREDERICK
    • MAUNDER ANTHONY DWIGHTSKINNER GEOFFREY FREDERICK
    • F25J1/00
    • F25J1/0022F25J1/0035F25J1/0037F25J1/004F25J1/0202F25J1/023F25J1/0254F25J2220/62F25J2220/64F25J2270/06
    • A process comprising: cooling natural gas with a heat exchanger and a first expander. The heat exchanger cools the feed natural gas to temperature higher than the outlet temperature of the expander, reheating the expander outlet stream in a first cold passage of the heat exchanger to slightly below the temperature of the feed natural gas to the heat exchanger, passing the cold outlet stream from the heat exchanger into a second expander wherein it is partly liquefied, separating the outlet stream of second expander into liquid and vapour fractions, collecting the liquid fraction for use as LNG product, reheating the vapour fraction in a second cold side passage of the heat exchanger to substantially the same temperature as the temperature of the feed natural gas to the heat exchanger, recycling the reheated vapour fraction partly as feed to the first expander and partly as feed to the heat exchanger.
    • 一种方法,包括:用热交换器和第一膨胀器冷却天然气。 热交换器将进料天然气冷却至高于膨胀器的出口温度的温度,将热交换器的第一冷通道中的膨胀器出口流重新加热到略低于进入热交换器的进料天然气的温度, 冷热出口流从热交换器进入第二膨胀器,其中部分液化,将第二膨胀机的出口流分离成液体和蒸气馏分,收集用作LNG产品的液体馏分,在第二冷侧通道中再加热蒸气馏分 的热交换器的温度与进入到热交换器的进料天然气的温度基本相同的温度,将再加热的蒸汽馏分部分地作为进料再循环到第一膨胀器,并且部分地作为进料到热交换器。
    • 2. 发明申请
    • PROCESS FOR LIQUEFACTION OF NATURAL GAS
    • 自然气体液化过程
    • WO2012172281A2
    • 2012-12-20
    • PCT/GB2012/000502
    • 2012-06-11
    • GASCONSULT LIMITEDMAUNDER, Anthony, DwightSKINNER, Geoffrey, Frederick
    • MAUNDER, Anthony, DwightSKINNER, Geoffrey, Frederick
    • F25J1/02
    • F25J1/0022F25J1/0035F25J1/0037F25J1/004F25J1/0202F25J1/023F25J1/0254F25J2220/62F25J2220/64F25J2270/06
    • A process comprising: cooling natural gas with a heat exchanger and a first expander. The heat exchanger cools the feed natural gas to temperature higher than the outlet temperature of the expander, reheating the expander outlet stream in a first cold passage of the heat exchanger to slightly below the temperature of the feed natural gas to the heat exchanger, passing the cold outlet stream from the heat exchanger into a second expander wherein it is partly liquefied, separating the outlet stream of second expander into liquid and vapour fractions, collecting the liquid fraction for use as LNG product, reheating the vapour fraction in a second cold side passage of the heat exchanger to substantially the same temperature as the temperature of the feed natural gas to the heat exchanger, recycling the reheated vapour fraction partly as feed to the first expander and partly as feed to the heat exchanger.
    • 一种方法,包括:用热交换器和第一膨胀器冷却天然气。 热交换器将进料天然气冷却至高于膨胀器的出口温度的温度,将热交换器的第一冷通道中的膨胀器出口流重新加热到略低于进入热交换器的进料天然气的温度, 冷热出口流从热交换器进入第二膨胀器,其中部分液化,将第二膨胀机的出口流分离成液体和蒸气馏分,收集用作LNG产品的液体馏分,在第二冷侧通道中再加热蒸气馏分 的热交换器的温度与进入到热交换器的进料天然气的温度基本相同的温度,将再加热的蒸汽馏分部分地作为进料再循环到第一膨胀器,并且部分地作为进料到热交换器。
    • 3. 发明申请
    • PROCESS FOR GENERATING HYDROGEN AND CARBON DIOXIDE FROM A HYDROCARBON FEEDSTOCK
    • 从碳氢化合物产生二氧化碳和二氧化碳的方法
    • WO2010109184A1
    • 2010-09-30
    • PCT/GB2010/000542
    • 2010-03-23
    • HYDROGEN ENERGY INTERNATIONAL LIMITEDSKINNER, Geoffrey FrederickZHANG, Ning
    • SKINNER, Geoffrey FrederickZHANG, Ning
    • C01B3/36C01B3/50
    • C01B3/52C01B3/36C01B3/506C01B3/56C01B2203/025C01B2203/0255C01B2203/0415C01B2203/043C01B2203/046C01B2203/047C01B2203/0475C01B2203/06C01B2203/0894C01B2203/145C01B2203/148C01B2203/86F01K3/188F25J3/04533F25J3/04539F25J3/04575F25J3/0625F25J3/0655F25J3/0665F25J2215/02F25J2245/02F25J2260/80Y02P20/129Y02P30/30
    • A process is described for generating hydrogen and carbon dioxide from a hydrocarbon feedstock. In some examples, the carbon dioxide is sequestered and/or used in a chemical process. In an example, the process comprises the steps of: (a) introducing (1) a fuel feed stream comprising a hydrocarbon feedstock, and (2) an first oxidant feed stream comprising at least 90 mole % oxygen to a non catalytic partial oxidation reactor unit (POx) for the production of synthesis gas wherein (i) the temperature of the fuel feed stream is in the range 100 to 7000C, and (ii) the molar ratio of oxygen contained in the first oxidant feed stream to carbon (in hydrocarbons) in the fuel feed stream is from 0.5 : 1 to 1.0: 1; (b) withdrawing a synthesis gas stream comprising hydrogen, carbon dioxide and carbon monoxide from the partial oxidation reactor unit and introducing the synthesis gas stream to a heat exchanger where heat generated in the partial oxidation reactor is used for the generation of steam and/or superheated steam; (c) withdrawing a cooled synthesis gas stream from the heat exchanger and introducing the cooled synthesis gas stream to a carbon oxides separation facility where it is separated into (1) a carbon oxides stream comprising carbon dioxide and carbon monoxide, and (2) a hydrogen stream comprising hydrogen and optionally nitrogen; (d) introducing the carbon oxides stream and a second oxidant feed stream comprising at least 90 mole% oxygen (based on the total moles of oxygen and of any nitrogen • in the second oxidant feed stream) to an oxycombustion boiler for the production of a carbon dioxide stream and using the heat generated by combustion of the carbon oxides stream in the boiler for the production of steam and/or superheated steam. The carbon dioxide stream and hydrogen stream may be exported from the process. The process may further include sequestering the carbon dioxide stream and/or using the carbon dioxide in a chemical process.
    • 描述了从烃原料产生氢气和二氧化碳的方法。 在一些实例中,二氧化碳被隔离和/或在化学过程中使用。 在一个实例中,该方法包括以下步骤:(a)引入(1)包含烃原料的燃料进料流,和(2)包含至少90摩尔%氧气的第一氧化剂进料流至非催化部分氧化反应器 用于生产合成气的单元(POx),其中(i)燃料进料流的温度在100至700℃的范围内,和(ii)第一氧化剂进料流中包含的氧与碳的摩尔比(在烃中 )为0.5:1至1.0:1; (b)从部分氧化反应器单元中取出包含氢气,二氧化碳和一氧化碳的合成气流,并将合成气流引入热交换器,其中在部分氧化反应器中产生的热量用于产生蒸汽和/或 过热蒸汽 (c)从热交换器中取出冷却的合成气流,并将冷却的合成气流引入到碳氧化物分离设备中,在此将其分离为(1)包含二氧化碳和一氧化碳的碳氧化物流,和(2) 氢气流包含氢气和任选的氮气; (d)将碳氧化物流和第二氧化剂进料流引入氧燃烧锅炉中,所述第二氧化剂进料流包含至少90摩尔%的氧(基于氧的总摩尔数和第二氧化剂进料流中的任何氮) 二氧化碳流,并使用由锅炉中的碳氧化物流燃烧产生的热量来生产蒸汽和/或过热蒸汽。 二氧化碳流和氢气流可以从该方法输出。 该方法还可以包括在化学过程中隔离二氧化碳流和/或使用二氧化碳。
    • 4. 发明申请
    • PRODUCTION OF CARBON DIOXIDE AND POWER FROM A HYDROCARBON FEEDSTOCK
    • 二氧化碳和二氧化碳的生产来自一个碳氢化合物
    • WO2010109181A1
    • 2010-09-30
    • PCT/GB2010/000539
    • 2010-03-23
    • HYDROGEN ENERGY INTERNATIONAL LIMITEDGIBSON, ChrisSKINNER, Geoffrey, FrederickZHANG, Ning
    • GIBSON, ChrisSKINNER, Geoffrey, FrederickZHANG, Ning
    • C01B3/38C01B3/48C01B3/50
    • C01B3/382C01B3/48C01B3/50C01B3/501C01B3/506C01B3/52C01B2203/0244C01B2203/0283C01B2203/04C01B2203/0405C01B2203/0415C01B2203/042C01B2203/046C01B2203/0475C01B2203/0495C01B2203/06C01B2203/0894C01B2203/1235C01B2203/127C01B2203/148C01B2203/84F01K3/188Y02E20/344Y02P20/13Y02P30/30
    • A process for the production of carbon dioxide in concentrated form and electricity from a hydrocarbon feedstock said process comprising the steps of: a) introducing an oxidant feed stream comprising oxygen or enriched air comprising at least 25 mole% oxygen (on a dry basis) and optionally steam and a fuel feed stream comprising methane and optionally hydrogen and/or steam to an autothermal reactor unit (ATR) for the production of synthesis gas wherein (i) the temperature of the fuel feed stream is in the range 350 to 700°C; and (ii) the molar ratio of oxygen contained in the oxidant feed stream to carbon (in hydrocarbons) in the fuel feed stream is from 0.45:1 to 0.85:1, preferably 0.55:1 to 0.7: 1; b) withdrawing a synthesis gas stream comprising methane, hydrogen, carbon monoxide, carbon dioxide, steam and optionally nitrogen from the ATR and heat exchanging the synthesis gas stream with at least one process stream selected from the group consisting of a water stream for the production of steam, a hydrocarbon feedstock, a pre-reformer feed stream, the fuel feed stream, a hydrogen stream, boiler feed water, a condensate stream, and steam for the production of superheated steam; c) if necessary, introducing steam to the synthesis gas stream before passing at least a portion of the synthesis gas stream to a shift converter unit where the synthesis gas reacts with steam to generate additional carbon dioxide and hydrogen; d) withdrawing a shift converted gas stream from the shift converter unit and heat exchanging the shift converted gas stream with at least one process stream selected from the group consisting of a hydrocarbon feedstock, a pre-reformer feed stream, the fuel feed stream, a hydrogen stream, boiler feed water, a condensate stream, water for the production of steam and steam for the production of superheated steam; e) passing the shift converted gas stream to a carbon dioxide separation unit for the separation of a concentrated carbon dioxide stream from a hydrogen stream comprising hydrogen and optionally nitrogen; f) combusting at least part of the hydrogen stream in a gas turbine wherein the gas turbine drives an electric generator thereby producing electricity and wherein combustion of the hydrogen stream generates an exhaust gas.
    • 一种用于从碳氢化合物原料生产浓缩二氧化碳和电的方法,所述方法包括以下步骤:a)引入包含氧气或富含空气的氧化剂进料流,所述氧气或富含空气包含至少25摩尔%的氧气(以干基计)和 任选的蒸汽和包含甲烷和任选的氢气和/或蒸汽的燃料进料流到用于生产合成气的自热反应器单元(ATR),其中(i)燃料进料流的温度在350-700℃的范围内 ; 和(ii)燃料进料流中氧化剂进料流中的氧与碳(在烃中)的摩尔比为0.45:1至0.85:1,优选0.55:1至0.7:1; b)从ATR中取出包含甲烷,氢气,一氧化碳,二氧化碳,蒸汽和任选的氮的合成气流,并用至少一种工艺流将所述合成气流热交换,所述工艺流选自用于生产的水流 蒸汽,烃原料,预重整器进料流,燃料进料流,氢气流,锅炉给水,冷凝物流和用于生产过热蒸汽的蒸汽; c)如果需要,在将至少一部分合成气流送入转化器单元之前将合成气流引入合成气流中,其中合成气与蒸汽反应产生额外的二氧化碳和氢气; d)从所述换档转换器单元中取出换档转换气流并用至少一种选自烃原料,预重整器进料流,所述燃料进料流, 氢气流,锅炉给水,冷凝水,用于生产蒸汽和蒸汽的水生产过热蒸汽; e)将转移后的气流送入二氧化碳分离装置,用于从浓氢气和任选的氮气分离浓缩的二氧化碳流; f)在燃气轮机中燃烧至少部分氢气流,其中燃气轮机驱动发电机从而产生电力,并且其中氢气流的燃烧产生废气。
    • 10. 发明申请
    • PROCESS FOR LIQUEFACTION OF NATURAL GAS
    • 自然气体液化过程
    • WO2012172281A4
    • 2014-01-09
    • PCT/GB2012000502
    • 2012-06-11
    • GASCONSULT LTDMAUNDER ANTHONY DWIGHTSKINNER GEOFFREY FREDERICK
    • MAUNDER ANTHONY DWIGHTSKINNER GEOFFREY FREDERICK
    • F25J1/00
    • F25J1/0022F25J1/0035F25J1/0037F25J1/004F25J1/0202F25J1/023F25J1/0254F25J2220/62F25J2220/64F25J2270/06
    • A process comprising: cooling natural gas with a heat exchanger and a first expander. The heat exchanger cools the feed natural gas to temperature higher than the outlet temperature of the expander, reheating the expander outlet stream in a first cold passage of the heat exchanger to slightly below the temperature of the feed natural gas to the heat exchanger, passing the cold outlet stream from the heat exchanger into a second expander wherein it is partly liquefied, separating the outlet stream of second expander into liquid and vapour fractions, collecting the liquid fraction for use as LNG product, reheating the vapour fraction in a second cold side passage of the heat exchanger to substantially the same temperature as the temperature of the feed natural gas to the heat exchanger, recycling the reheated vapour fraction partly as feed to the first expander and partly as feed to the heat exchanger.
    • 一种方法,包括:用热交换器和第一膨胀器冷却天然气。 热交换器将进料天然气冷却至高于膨胀器的出口温度的温度,将热交换器的第一冷通道中的膨胀器出口流重新加热到略低于进入热交换器的进料天然气的温度, 冷热出口流从热交换器进入第二膨胀器,其中部分液化,将第二膨胀机的出口流分离成液体和蒸气馏分,收集用作LNG产品的液体馏分,在第二冷侧通道中再加热蒸气馏分 的热交换器的温度与进入到热交换器的进料天然气的温度基本相同的温度,将再加热的蒸汽馏分部分地作为进料再循环到第一膨胀器,并且部分地作为进料到热交换器。