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1. 发明申请

WO2012160574A3 CONTROLLED MORPHOLOGY HIGH ACTIVITY POLYOLEFIN CATALYST SYSTEM 审中-公开
标题翻译：控制形态高活性聚烯烃催化剂体系
公开(公告)号：WO2012160574A3
公开(公告)日：2013-03-14
申请号：PCT/IN2012000350
申请日：2012-05-15
申请人： RELIANCE IND LTD , SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
发明人： SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
IPC分类号： B01J31/02 , B01J27/138 , B01J35/08 , C08F10/00
CPC分类号： C08F4/76 , B01J27/138 , B01J31/02 , B01J35/08 , C08F10/00 , C08F4/651 , C08F4/6543 , C08F4/6545
摘要： A high activity polyolefin catalyst system comprising titanium containing pro- catalyst component, a co-catalyst component and an external electron donor compound is provided wherein the high activity polyolefin catalyst system is having controlled morphology and less fines. The present invention is more directed to provide a method for the preparation of titanium containing pro- catalyst component from solid spherical shaped magnesium containing pro- catalyst precursor wherein the spherical morphology of the pro-catalyst precursor is maintained through out the reaction in order to achieve titanium-containing pro- catalyst having controlled morphology. The polymerization of lower olefins in the presence of high activity polyolefin catalyst having controlled morphology provides polyolefins with minimal polymer fines.
摘要翻译：提供了一种包含钛的催化剂组分，助催化剂组分和外部电子给体化合物的高活性聚烯烃催化剂体系，其中高活性聚烯烃催化剂体系具有受控的形态和较少的细粉。本发明更有针对性地提供一种从固体球形含镁催化剂前体制备含钛催化剂组分的方法，其中前催化剂前体的球形形态通过反应维持以实现具有受控形态的含钛催化剂。在具有受控形态的高活性聚烯烃催化剂存在下，低级烯烃的聚合提供具有最小聚合物细粉的聚烯烃。

2. 发明申请

WO2011077447A2 A SEMI-CONTINUOUS PROCESS FOR THE SYNTHESIS OF A CATALYST FOR USE IN THE MANUFACTURE OF POLYOLEFINS 审中-公开
标题翻译：用于合成聚烯烃用催化剂的半连续方法
公开(公告)号：WO2011077447A2
公开(公告)日：2011-06-30
申请号：PCT/IN2010/000809
申请日：2010-12-14
申请人： RELIANCE INDUSTRIES LIMITED , SINGALA, Kamlesh , SINGH, Saurabh , GUPTA, Virendrakumar
发明人： SINGALA, Kamlesh , SINGH, Saurabh , GUPTA, Virendrakumar
IPC分类号： C08F4/652
CPC分类号： C08F10/06 , C01G23/0536 , C01P2004/51 , C08F110/06 , Y10S526/908 , C08F4/651 , C08F2/14 , C08F2/00 , C08F2500/12
摘要： This invention provides a semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins comprising of following steps: (a) mixing a reaction mixture essentially consisting of titanium compound having at least one titanium halogen bond and a chlorinated solvent in feed section; (b) charging a first reactor with said reaction mixture; (c) continuously removing excess reactants from said first reactor as a filtrate through a filtrate section placed at the bottom of said first reactor; (d) feeding said filtrate to at least one further reactor connected to said first reactor to retain the carried over fine particles from said first reactor; continuously removing excess reactants from said at least further reactor as a filtrate through a filtrate section placed at the bottom of said at least one further reactor and, if desired, feeding said filtrate to next said at least one further reactor; (e) repeating step (d) for n number of times in series, wherein reactors are arranged in series or parallel; (f) subjecting the said filtrate from the last of said at least one further reactor to a distillation section to remove impurities and recover the distillate; and continuously charging the distillate from the distillation section to the feed section; wherein a desired equilibrium between fresh and recovered distillate and a desired resultant concentration of reactant feed are maintained; and (g) optionally treating the residue from distillation section with an alkali to obtain titanium hydroxide and calcining said titanium hydroxide to obtain titanium oxide as a by product.
摘要翻译：本发明提供了用于合成用于制造聚烯烃的窄粒径分布齐格勒纳塔主催化剂的半连续方法及其系统，其包括以下步骤：（a）将反应混合物在进料段中主要由具有至少一个钛卤素键的钛化合物和氯化溶剂组成的混合物; （b）用所述反应混合物装入第一反应器; （c）通过位于所述第一反应器底部的滤液部分作为滤液连续地从所述第一反应器中除去过量的反应物; （d）将所述滤液加入到与所述第一反应器连接的至少一个另外的反应器中以保留来自所述第一反应器的所述携带的细颗粒; 作为滤液通过放置在所述至少一个其他反应器底部的滤液部分连续地从所述至少另一个反应器中除去过量的反应物，并且如果需要，将所述滤液进料到下一个所述至少一个另外的反应器中; （e）重复步骤（d）n次串联，其中反应器串联或并联排列; （f）将来自所述至少一个另外的反应器的最后一个的所述滤液置于蒸馏段以除去杂质并回收馏出物; 并将来自蒸馏部分的馏出物连续加入进料部分; 其中维持新鲜馏分和回收馏分之间的期望平衡以及期望的反应物进料的所得浓度; 和（g）任选地用碱处理来自蒸馏段的残余物以获得氢氧化钛并煅烧所述氢氧化钛以获得作为副产物的氧化钛。

3. 发明申请

WO2009130707A3 SPHEROIDAL PARTICLES FOR OLEFIN POLYMERIZATION CATALYST 审中-公开
公开(公告)号：WO2009130707A3
公开(公告)日：2009-10-29
申请号：PCT/IN2008/000555
申请日：2008-09-01
申请人： RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , SINGH, Saurabh , MAKWANA, Umesh , JOSEPH, Jomichan , SINGALA, Kamlesh , RAJESH, Smitha , PATEL, Vallabhbhai , YADAV, Mukeshkumar , SINGH, Gurmeet
发明人： GUPTA, Virendrakumar , SINGH, Saurabh , MAKWANA, Umesh , JOSEPH, Jomichan , SINGALA, Kamlesh , RAJESH, Smitha , PATEL, Vallabhbhai , YADAV, Mukeshkumar , SINGH, Gurmeet
IPC分类号： C07C29/70 , C07C31/30 , B01J35/08
摘要： The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step- wise heating first in the range of 40°C to 65°C for a period of 2 hours and then in the range of 65°C to 80°C for a period of 1 hour, further by maintaining reaction temperature at 80°C for a period of 6 - 10 hours, the vapours of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesised using the procatalyst.

4. 发明申请

WO2009130707A2 SPHEROIDAL PARTICLES FOR OLEFIN POLYMERIZATION CATALYST 审中-公开
标题翻译：用于烯烃聚合催化剂的SPHEROIDAL PARTICLES
公开(公告)号：WO2009130707A2
公开(公告)日：2009-10-29
申请号：PCT/IN2008000555
申请日：2008-09-01
申请人： RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , SINGH SAURABH , MAKWANA UMESH , JOSEPH JOMICHAN , SINGALA KAMLESH , RAJESH SMITHA , PATEL VALLABHBHAI , YADAV MUKESHKUMAR , SINGH GURMEET
发明人： GUPTA VIRENDRAKUMAR , SINGH SAURABH , MAKWANA UMESH , JOSEPH JOMICHAN , SINGALA KAMLESH , RAJESH SMITHA , PATEL VALLABHBHAI , YADAV MUKESHKUMAR , SINGH GURMEET
IPC分类号： C07C29/70 , B01J35/08 , C07C31/30
CPC分类号： C07C31/28 , C07C29/70 , C08F10/00 , C07C31/30 , C08F4/6494 , C08F4/6548
摘要： The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step- wise heating first in the range of 40°C to 65°C for a period of 2 hours and then in the range of 65°C to 80°C for a period of 1 hour, further by maintaining reaction temperature at 80°C for a period of 6 - 10 hours, the vapours of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesised using the procatalyst.
摘要翻译：本发明涉及一种合成具有改善的机械强度和窄粒度分布的球形镁醇盐的方法，该方法包括在碘存在下使镁金属与醇的混合物反应，首先在该范围内逐步加热在40℃至65℃下进行2小时，然后在65℃至80℃的范围内，持续1小时，此外，通过将反应温度保持在80℃持续6-10分钟在反应过程中产生的混合物的蒸气在塔顶冷凝器中冷凝，反应过程中产生的氢气被排出，反应后留下的醇的混合物被过滤并重复使用。本发明还涉及通过该方法合成的球形烷醇镁颗粒，使用通过使用醇盐合成的齐格勒纳塔催化剂和使用前催化剂合成的聚合物树脂。

5. 发明申请

WO2012160574A8 CONTROLLED MORPHOLOGY HIGH ACTIVITY POLYOLEFIN CATALYST SYSTEM 审中-公开
标题翻译：控制形态高活性聚烯烃催化体系
公开(公告)号：WO2012160574A8
公开(公告)日：2013-02-14
申请号：PCT/IN2012000350
申请日：2012-05-15
申请人： RELIANCE INDUSRIES LTD , SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
发明人： SINGH SAURABH , GUPTA VIRENDRAKUMAR , SINGALA KAMLESH J , PATEL VALLABHBHAI S
CPC分类号： C08F4/76 , B01J27/138 , B01J31/02 , B01J35/08 , C08F10/00 , C08F4/651 , C08F4/6543 , C08F4/6545
摘要： A high activity polyolefin catalyst system comprising titanium containing pro- catalyst component, a co-catalyst component and an external electron donor compound is provided wherein the high activity polyolefin catalyst system is having controlled morphology and less fines. The present invention is more directed to provide a method for the preparation of titanium containing pro- catalyst component from solid spherical shaped magnesium containing pro- catalyst precursor wherein the spherical morphology of the pro-catalyst precursor is maintained through out the reaction in order to achieve titanium-containing pro- catalyst having controlled morphology. The polymerization of lower olefins in the presence of high activity polyolefin catalyst having controlled morphology provides polyolefins with minimal polymer fines.
摘要翻译：提供包含含钛前催化剂组分，助催化剂组分和外电子给体化合物的高活性聚烯烃催化剂体系，其中高活性聚烯烃催化剂体系具有可控的形态和较少的细粒。本发明更具针对性地提供了一种由固体球形含镁前体催化剂前体制备含钛前体催化剂组分的方法，其中前体催化剂前体的球形形态在整个反应过程中保持以实现具有受控形态的含钛前体催化剂。在具有可控形态的高活性聚烯烃催化剂存在下，低级烯烃的聚合反应提供了具有最小聚合物细粒的聚烯烃。

6. 发明申请

WO2012160574A2 CONTROLLED MORPHOLOGY HIGH ACTIVITY POLYOLEFIN CATALYST SYSTEM 审中-公开
标题翻译：控制形态高活性聚烯烃催化剂体系
公开(公告)号：WO2012160574A2
公开(公告)日：2012-11-29
申请号：PCT/IN2012/000350
申请日：2012-05-15
申请人： RELIANCE INDUSRIES LTD. , SINGH, Saurabh , GUPTA, Virendrakumar , SINGALA, Kamlesh, J. , PATEL, Vallabhbhai, S.
发明人： SINGH, Saurabh , GUPTA, Virendrakumar , SINGALA, Kamlesh, J. , PATEL, Vallabhbhai, S.
CPC分类号： C08F4/76 , B01J27/138 , B01J31/02 , B01J35/08 , C08F10/00 , C08F4/651 , C08F4/6543 , C08F4/6545
摘要： A high activity polyolefin catalyst system comprising titanium containing pro- catalyst component, a co-catalyst component and an external electron donor compound is provided wherein the high activity polyolefin catalyst system is having controlled morphology and less fines. The present invention is more directed to provide a method for the preparation of titanium containing pro- catalyst component from solid spherical shaped magnesium containing pro- catalyst precursor wherein the spherical morphology of the pro-catalyst precursor is maintained through out the reaction in order to achieve titanium-containing pro- catalyst having controlled morphology. The polymerization of lower olefins in the presence of high activity polyolefin catalyst having controlled morphology provides polyolefins with minimal polymer fines.
摘要翻译：提供了一种包含钛的催化剂组分，助催化剂组分和外部电子给体化合物的高活性聚烯烃催化剂体系，其中高活性聚烯烃催化剂体系具有受控的形态和较少的细粉。本发明更有针对性地提供一种从固体球形含镁催化剂前体制备含钛催化剂组分的方法，其中前催化剂前体的球形形态通过反应维持以实现具有受控形态的含钛催化剂。在具有受控形态的高活性聚烯烃催化剂存在下，低级烯烃的聚合提供具有最小聚合物细粉的聚烯烃。

7. 发明申请

WO2012007963A3 ATTRITION RESISTANT CATALYST SYSTEM FOR MANUFACTURE OF POLYOLEFINS 审中-公开
标题翻译：用于聚烯烃制备的抗吸附催化剂体系
公开(公告)号：WO2012007963A3
公开(公告)日：2012-11-29
申请号：PCT/IN2011000460
申请日：2011-07-11
申请人： RELIANCE IND LTD , GUPTA VIRENDRAKUMAR , SINGH SAURABH , JOSEPH JOMICHAN , SINGALA KAMLESH J , DESAI BHAVESH K
发明人： GUPTA VIRENDRAKUMAR , SINGH SAURABH , JOSEPH JOMICHAN , SINGALA KAMLESH J , DESAI BHAVESH K
IPC分类号： C08F4/654 , C08F4/02 , C08F10/00
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/651 , C08F4/6548 , C08F2500/12 , C08F2500/24 , C08F4/6494
摘要： The present invention relates to regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins. More particularly, the present invention relates to a process for the synthesis of a said precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content. In particular, the present invention relates to process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the said procatalysts.
摘要翻译：本发明涉及含有耐磨损前体和前催化剂的规则形状的镁颗粒及其合成方法及其在制造聚烯烃中的用途。更具体地说，本发明涉及一种合成所述前体颗粒的方法，该前体颗粒提供高活性和改进的表面积前催化剂，用于生产含有低细颗粒并能够掺入高橡胶含量的高松密度聚烯烃树脂。具体而言，本发明涉及合成耐磨前体以制备通过使用前体合成的耐磨的齐格勒纳塔前催化剂和使用所述前催化剂合成的聚烯烃树脂的方法。

8. 发明申请

WO2012007963A2 ATTRITION RESISTANT CATALYST SYSTEM FOR MANUFACTURE OF POLYOLEFINS 审中-公开
标题翻译：用于制造聚烯烃的耐腐蚀催化剂体系
公开(公告)号：WO2012007963A2
公开(公告)日：2012-01-19
申请号：PCT/IN2011/000460
申请日：2011-07-11
申请人： RELIANCE INDUSTRIES LIMITED , GUPTA, Virendrakumar , SINGH, Saurabh , JOSEPH, Jomichan , SINGALA, Kamlesh, J. , DESAI, Bhavesh, K.
发明人： GUPTA, Virendrakumar , SINGH, Saurabh , JOSEPH, Jomichan , SINGALA, Kamlesh, J. , DESAI, Bhavesh, K.
IPC分类号： C08F4/654
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F10/00 , C08F110/02 , C08F110/06 , C08F4/651 , C08F4/6548 , C08F2500/12 , C08F2500/24 , C08F4/6494
摘要： The present invention relates to regular shaped magnesium particles containing attrition resistant precursors and procatalysts thereof and processes for their synthesis and their use in the manufacture of polyolefins. More particularly, the present invention relates to a process for the synthesis of a said precursor particles which give highly active and improved surface area procatalysts for producing high bulk density polyolefin resins containing low fines and capable of incorporating high rubber content. In particular, the present invention relates to process for the synthesis of an attrition resistant precursors to prepare an attrition resistant Zeigler Natta procatalysts synthesized by using the precursors and to the polyolefin resin synthesized using the said procatalysts.
摘要翻译：本发明涉及含有抗磨损前体及其前催化剂的规则形状的镁颗粒及其合成方法及其在制备聚烯烃中的用途。更具体地说，本发明涉及一种合成所述前体颗粒的方法，该方法得到高活性和改进的表面积原催化剂，用于生产含低细粉和能掺入高橡胶含量的高体积密度聚烯烃树脂。特别地，本发明涉及合成耐磨前体以制备通过使用前体合成的耐磨Zeigler Natta前催化剂和使用所述前催化剂合成的聚烯烃树脂的方法。

9. 发明申请

WO2011077447A3 A SEMI-CONTINUOUS PROCESS FOR THE SYNTHESIS OF A CATALYST FOR USE IN THE MANUFACTURE OF POLYOLEFINS 审中-公开
标题翻译：用于合成在聚烯烃制造中的催化剂的半连续方法
公开(公告)号：WO2011077447A3
公开(公告)日：2011-08-11
申请号：PCT/IN2010000809
申请日：2010-12-14
申请人： RELIANCE IND LTD , SINGALA KAMLESH , SINGH SAURABH , GUPTA VIRENDRAKUMAR
发明人： SINGALA KAMLESH , SINGH SAURABH , GUPTA VIRENDRAKUMAR
IPC分类号： C08F4/652 , B01J27/08 , C08F4/649 , C08F10/00
CPC分类号： C08F10/06 , C01G23/0536 , C01P2004/51 , C08F110/06 , Y10S526/908 , C08F4/651 , C08F2/14 , C08F2/00 , C08F2500/12
摘要： This invention provides a semi-continuous process and system thereof, for the synthesis of a narrow particle size distribution Zeigler Natta procatalyst for use in the manufacture of polyolefins comprising of following steps: (a) mixing a reaction mixture essentially consisting of titanium compound having at least one titanium halogen bond and a chlorinated solvent in feed section; (b) charging a first reactor with said reaction mixture; (c) continuously removing excess reactants from said first reactor as a filtrate through a filtrate section placed at the bottom of said first reactor; (d) feeding said filtrate to at least one further reactor connected to said first reactor to retain the carried over fine particles from said first reactor; continuously removing excess reactants from said at least further reactor as a filtrate through a filtrate section placed at the bottom of said at least one further reactor and, if desired, feeding said filtrate to next said at least one further reactor; (e) repeating step (d) for n number of times in series, wherein reactors are arranged in series or parallel; (f) subjecting the said filtrate from the last of said at least one further reactor to a distillation section to remove impurities and recover the distillate; and continuously charging the distillate from the distillation section to the feed section; wherein a desired equilibrium between fresh and recovered distillate and a desired resultant concentration of reactant feed are maintained; and (g) optionally treating the residue from distillation section with an alkali to obtain titanium hydroxide and calcining said titanium hydroxide to obtain titanium oxide as a by product.
摘要翻译：本发明提供了一种半连续方法及其系统，用于合成用于制备聚烯烃的窄粒径分布Zeigler Natta主催化剂，包括以下步骤：（a）将基本上由钛化合物进料段中最少一个钛卤素键和氯化溶剂; （b）向所述反应混合物中加入第一反应器; （c）通过放置在所述第一反应器底部的滤液段连续地从所述第一反应器中除去过量的反应物作为滤液，（d）将所述滤液进料至连接到所述第一反应器的至少一个另外的反应器，以保留所述第一反应器中承载的细颗粒; 通过置于所述至少一个另外的反应器底部的滤液部分连续地从所述至少另外的反应器中除去过量的反应物，并且如果需要，将所述滤液进料到下一个所述至少一个另外的反应器中; （e）重复步骤（d）n次串联，其中反应器串联或并联排列; （f）将来自所述至少一个其它反应器中的最后一个的所述滤液经蒸馏部分除去杂质并回收馏出物; 并将馏出物从蒸馏段连续地装入进料部分; 其中保持新鲜和回收的馏出物之间所需的平衡和所需的反应物进料浓度; 和（g）任选地用碱处理来自蒸馏段的残余物以获得氢氧化钛并煅烧所述氢氧化钛以获得作为副产物的氧化钛。

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