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1. 发明申请

WO02053499A9 SAPO-11 MOLECULAR SIEVE, ITS SYNTHETIC METHOD AND A CATALYST CONTAINING THE MOLECULAR SIEVE 审中-公开
标题翻译： SAPO-11分子筛，其合成方法和含有分子筛的催化剂
公开(公告)号：WO02053499A9
公开(公告)日：2002-11-14
申请号：PCT/CN0100010
申请日：2001-01-05
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING , ZHANG FENGMEI , LIU YUEMING , SHU XINGTIAN , WANG WEIDONG , QIN FENGMING
发明人： ZHANG FENGMEI , LIU YUEMING , SHU XINGTIAN , WANG WEIDONG , QIN FENGMING
IPC分类号： B01J29/85 , B01J37/00 , C01B37/08 , C10G45/64 , C01B39/54 , C10G47/18
CPC分类号： C01B37/08 , B01J29/85 , B01J37/0009 , C10G45/64
摘要： The present invention relates to an SAPO-11 silocoaluminophosphate molecular sieve, its preparation and a catalyst containing the molecular sieve. After being calcinated to remove templating agent, the molecular composition of said molecular sieve has a empirical formula in the anhydrous oxides form: Al2O3 : yP2O5 : ZSiO2, wherein the value of y is 0.60∼1.20, the value of z is 0.05∼1.3; and it characterized in that: the data of XRD of said calculated molecular sieves is as that showed in table 3, the crystalline structure of said calcinated molecular sieve is essentially the same as that the of the synthesized molecular sieves is essentially the same as that of the synthesized molecular sieves which have not been subject to calcination to remove the templating agent. Said catalyst comprises 10∼85 wt.% of SAPO-11 molecular sieve, 0.05∼1.5 wt.% of Pd or Pt, with the balance of alumina. Comparing with the same catalyst of prior art, said catalyst has remarkably increased selectivity and product yield, when it is used in hydrocarbon isomerization.
摘要翻译：本发明涉及SAPO-11硅铝磷酸盐分子筛，其制备方法和含有分子筛的催化剂。煅烧后除去模板剂后，所述分子筛的分子组成为无水氧化物形式的经验式：Al2O3：yP2O5：ZSiO2，其中y值为0.60〜1.20，z值为0.05〜1.3; 其特征在于：所述计算分子筛的XRD数据如表3所示，所述煅烧分子筛的结晶结构基本上与合成分子筛基本上相同，未经煅烧的合成分子筛除去模板剂。所述催化剂包含10〜85重量％的SAPO-11分子筛，0.05〜1.5重量％的Pd或Pt，余量为氧化铝。与现有技术相同的催化剂相比，当用于烃异构化时，所述催化剂显着提高了选择性和产率。

2. 发明申请

WO2005085391A8 A PROCESS OF PRODUCTION OF LOWER OLEFINS AND AROMATICAS 审中-公开
标题翻译：一种生产低油脂和芳香油的方法
公开(公告)号：WO2005085391A8
公开(公告)日：2008-01-24
申请号：PCT/CN2005000281
申请日：2005-03-08
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING , LONG JUN , DA ZHIJIAN , LI DADONG , WANG XIEQING , SHU XINGTIAN , ZHANG JIUSHUN , NIE HONG , XIE CHAOGANG , ZHANG ZHIGANG , WANG WEI
发明人： LONG JUN , DA ZHIJIAN , LI DADONG , WANG XIEQING , SHU XINGTIAN , ZHANG JIUSHUN , NIE HONG , XIE CHAOGANG , ZHANG ZHIGANG , WANG WEI
IPC分类号： C07C4/06 , C10G11/18
CPC分类号： C10G69/04 , C07C4/06 , C07C5/05 , C07C5/11 , C10G11/18 , C10G69/02 , C10G69/06 , C10G69/14 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/4018 , C10G2300/4093 , C10G2300/44 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： A process of production of lower olefins and aromatics involves contacting the feeds with a catalytic pyrolyzing catalyst. There are at least two reaction zones, the temperature of at least one reaction zone in the downstream of the first reaction zone is higher than that of the first one, but the weight space velocity is lower. The oil gas after reaction is separated from the catalyst, and the catalyst is recycled to the reactor after regeneration. The oil gas is separated and the required products of lower olefins and aromatics are obtained. This process can acquire maximum lower olefins such as propylene, ethylene from the heavy feeds, and the yield of the propylene exceeds 20wt. %, at the same time, aromatics such as toluene, xylene is obtained.
摘要翻译：低级烯烃和芳族化合物的生产方法包括使进料与催化热解催化剂接触。存在至少两个反应区，第一反应区下游的至少一个反应区的温度高于第一反应区的温度，但重量空间速度较低。反应后的油气与催化剂分离，再生后将催化剂再循环至反应器。分离油气，得到所需的低级烯烃和芳族化合物。该方法可从重质进料中获得最大的低级烯烃，如丙烯，乙烯，丙烯的产率超过20wt。％，同时得到芳族化合物如甲苯，二甲苯。

3. 发明申请

WO2005094992A8 A CATALYST CONTAINING ZEOLITE FOR HYDROCARBON CONVERTING AND PREPARATION THEREOF, AND A HYDROCARBON OIL CONVERTING METHOD USING SAID CATALYST 审中-公开
标题翻译：用于碳氢化合物转化和制备的含有沸石的催化剂和使用催化剂的烃油转化方法
公开(公告)号：WO2005094992A8
公开(公告)日：2006-09-28
申请号：PCT/CN2005000427
申请日：2005-03-31
申请人： CHINA PETROLEUM & CHEMICAL , RES INST PETROLEUM PROCESSING , LONG JUN , DA ZHIJIAN , TIAN HUIPING , CHEN ZHENYU , ZHANG WEILIN , SHU XINGTIAN , ZHANG JIUSHUN , ZHU YUXIA , LIU YUJIAN
发明人： LONG JUN , DA ZHIJIAN , TIAN HUIPING , CHEN ZHENYU , ZHANG WEILIN , SHU XINGTIAN , ZHANG JIUSHUN , ZHU YUXIA , LIU YUJIAN
IPC分类号： B01J29/42 , B01J29/08 , B01J29/40 , B01J29/48 , B01J29/80 , C10G11/05
CPC分类号： B01J29/42 , B01J29/084 , B01J29/40 , B01J29/405 , B01J29/48 , B01J29/80 , B01J2229/42 , C10G11/05 , C10G2300/807 , C10G2400/20
摘要： A catalyst for hydrocarbon converting comprises 1-60wt. % zeolite, 0.1-10wt. % co-catalyst (on the basis of the oxide), 5-98wt. % refractory inorganic oxide, 0-70wt. % clay based on the total weight of the catalyst, wherein the zeolite is MFI structure zeolite comprising phosphor and transition metals or the mixture of MFI structure and a large-pore zeolite, which contains 75-100 wt % MFI structure zeolite and 0-25 wt % large-pore zeolite relative to the total weight of the zeolite. On the basis of the weight of oxide, the MFI structure zeolite comprising phosphor and transition metals has anhydrous chemical formula as follows: (0-0.3)Na 2 0?(0.3-5.5)A1 2 0 3 ?(1.0-10)P 2 0 5 ?(0.7-15)M?1 x O y ?(0.01-5)M2 m 0 n ?(0-10)RE 2 0 3 ?(70-97)SiO 2 I or (0-0.3)Na 2 0?(0.3-5)A1 2 0 3 ?(1.0-10)P 2 0 5 ?(0.7-15)M p O q ?(0-10)RE 2 0 3 ?(70-98)Si0 2 II wherein the co-catalyst selects from one or more of the group of alkaline earth, IVB, non-noble metals in VIII group and rare-earth metals. The catalyst has high petroleum hydrocarbon conversion ability, and the yields of propylene, ethylene and light aromatics are higher.
摘要翻译：用于烃转化的催化剂包括1-60wt。％沸石，0.1-10wt。％助催化剂（基于氧化物），5-98wt。％耐火无机氧化物，0-70wt。基于催化剂的总重量，其中沸石是包含磷光体和过渡金属的MFI结构沸石或MFI结构和大孔沸石的混合物，其含有75-100重量％的MFI结构沸石和0-25 wt％的大孔沸石相对于沸石的总重量。基于氧化物的重量，包含荧光体和过渡金属的MFI结构沸石具有如下无水化学式：（0-0.3）Na 2 O 3（0.3-5.5）A1 < 2 0 _{3 ？（1.0-10）P _{2 0 _{5 ？（0.7-15）M？1 _{X 0 _{ý？（0.01-5）M2 _{米 0 _{名词？（0-10）RE _{2 < （70-97）SiO 2 I或（0-0.3）Na 2 O 3（0.3-5） A1 _{2 0 _{3 ？（1.0-10）P _{2 0 _{5 ？（0.7-15）M < SUB> p 0 _{q ？（0-10）RE _{2 0 _{3 ？（70-98）的SiO _{其中助催化剂选自VIII族中的一种或多种碱土金属，IVB族，非贵金属族和稀土类金属。该催化剂具有较高的石油烃转化能力，丙烯，乙烯和轻质芳烃的产率较高。}}}}}}}}}}}}}}}}

4. 发明授权

US5358918A Hydrocarbon conversion catalyst for producing high quality gasoline and C.sub.3 and C.sub.4 olefins 失效
标题翻译：用于生产高品质汽油和C3和C4烯烃的烃转化催化剂
公开(公告)号：US5358918A
公开(公告)日：1994-10-25
申请号：US30579
申请日：1993-03-12
申请人： Lu Yukang , Huo Yongqing , Shu Xingtian , Wang Yousheng , Wang Zeyu , Zhang Shuqin , Liu Haibin , Cui Suxin
发明人： Lu Yukang , Huo Yongqing , Shu Xingtian , Wang Yousheng , Wang Zeyu , Zhang Shuqin , Liu Haibin , Cui Suxin
IPC分类号： B01J29/08 , B01J29/40 , B01J29/80 , C10G11/05 , B01J29/06
CPC分类号： C10G11/05 , B01J29/80 , B01J29/084 , B01J29/088 , B01J29/405
摘要： A hydrocarbon conversion catalyst for converting petroleum distillates of different boiling ranges, residue oils, and crude oils, especially the heavy hydrocarbons containing high nickel, into high quality gasoline and C.sub.3 and C.sub.4 olefins. The catalyst of the invention comprises three zeolitic active components consisting of a rare-earth-containing pentasil type high silica zeolite ZRP, a REY zeolite, and a high silica Y zeolite, in a total content of 10-40 wt % based on the total weight of the catalyst, and the remainder synthetic matrix or semi-synthetic matrix comprising 10-40 wt % silica and/or alumina binder. In the total amount of the active components, zeolite ZRP, REY, and the high silica Y are 3-50, 12-75, and 12-75 wt % respectively. The zeolite ZRP used in the catalyst is characterized in an anhydrous chemical composition of the formula 0.01-0.30 RE.sub.2 O.sub.3.0.4-1.0 Na.sub.2 O.Al.sub.2 O.sub.3.20-60 SiO.sub.2 , a specific X- ray diffraction pattern, a higher adsorption capacity ratio of normal hexane to cyclohexane, and a rare earth ingredient which originates from a rare earth containing faujasite used as seed in the synthesis of the zeolite.
摘要翻译：用于将不同沸程的石油馏分，残油和原油，特别是含有高镍的重质烃转化成高品质汽油和C3和C4烯烃的烃转化催化剂。本发明的催化剂包含由含稀土的pentasil型高硅沸石ZRP，REY沸石和高二氧化硅Y沸石组成的三种沸石活性组分，总含量为10-40重量％，基于总量催化剂的重量，以及包含10-40重量％二氧化硅和/或氧化铝粘合剂的其余合成基质或半合成基质。在活性组分的总量中，沸石ZRP，REY和高二氧化硅Y分别为3-50,12-75和12-75wt％。在催化剂中使用的沸石ZRP的特征在于0.01-0.30 RE2O3.0.4-1.0 Na2O.Al2O3.20-60SiO 2的无水化学组成，具体的X射线衍射图，正己烷的吸附容量比较高环己烷，以及来源于在沸石的合成中作为种子使用的含有八面沸石的稀土的稀土成分。

5. 发明授权

US5380690A Cracking catalyst for the production of light olefins 失效
标题翻译：用于生产轻质烯烃的裂化催化剂
公开(公告)号：US5380690A
公开(公告)日：1995-01-10
申请号：US72771
申请日：1993-06-07
申请人： Shi Zhicheng , Shi Wenyuan , Ye Yifang , Ge Xingpin , Cao Ping , Liu Shunhua , Xie Chaogang , Li Zaiting , Shu Xingtian , Yang Xiaoming , Fu Wei , Zhou Meng , He Mingyuan
发明人： Shi Zhicheng , Shi Wenyuan , Ye Yifang , Ge Xingpin , Cao Ping , Liu Shunhua , Xie Chaogang , Li Zaiting , Shu Xingtian , Yang Xiaoming , Fu Wei , Zhou Meng , He Mingyuan
IPC分类号： B01J29/08 , B01J29/40 , B01J29/80 , C10G11/05 , B01J29/28
CPC分类号： C10G11/05 , B01J29/40 , B01J29/80 , B01J2229/26 , B01J2229/42 , B01J29/084
摘要： A cracking catalyst for the production of light olefins comprises 0-70% (based on the weight of the catalyst) of clay, 5-99% of inorganic oxides, and 1-50% of zeolite. The zeolite in the catalyst is a mixture of 0-25 wt % of REY or high silica Y zeolite and 75-100 wt % of phosphorus and rare earth containing high silica zeolite having a structure of pentasil. The catalyst exhibits higher hydrothermal activity-stability, conversion level, and C.sub.2 -C.sub.4 olefin yields in cracking reaction, comparing with the catalyst using HZSM-5 zeolite as active component.
摘要翻译：用于生产轻质烯烃的裂化催化剂包括0-70％（基于催化剂重量）的粘土，5-99％的无机氧化物和1-50％的沸石。催化剂中的沸石是0-25重量％的REY或高二氧化硅Y沸石和75-100重量％的磷和具有pentasil结构的含有高二氧化硅沸石的稀土的混合物。与使用HZSM-5沸石作为活性组分的催化剂相比，催化剂表现出更高的水热活性 - 稳定性，转化率和裂解反应中的C2-C4烯烃产率。

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