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1. 发明申请

WO2008080908A3 FILM FORMING COMPOSITION COMPRISING MODIFIED NANOPARTICLES AND MODIFIED NANOPARTICLES FOR USE IN FILM FORMING COMPOSITIONS 审中-公开
公开(公告)号：WO2008080908A3
公开(公告)日：2008-07-10
申请号：PCT/EP2007/064518
申请日：2007-12-21
申请人： NUPLEX RESINS B.V. , SCHUTYSER, Jan André Jozef , VIJVERBERG, Cornelis Adrianus Maria , BRINKHUIS, Richard Hendrikus Gerrit
发明人： SCHUTYSER, Jan André Jozef , VIJVERBERG, Cornelis Adrianus Maria , BRINKHUIS, Richard Hendrikus Gerrit
IPC分类号： C09C3/10 , C09D7/12
摘要： The present invention relates to afilm forming composition comprisinga resin andmodified nanoparticles comprising nanoparticles and adsorbed thereon a segmented copolymer, preferably a segmented blockcopolymer, comprising an adsorbing segment and a hydrophobic surface active segment, wherein the adsorbing segment has one or more functional groups that adsorb on the nanoparticles and wherein the hydrophobic segment is more hydrophobic than the resin providing surface migration of the nanoparticles. The invention also relates to novelmodified particles and the use of the specified segmented copolymer of specified modified particels in afilm forming composition for imparting thereto improvedsurface properties such as scratch resistance.

2. 发明申请

WO1995006075A1 ALLYL-EPOXY IPN 审中-公开
公开(公告)号：WO1995006075A1
公开(公告)日：1995-03-02
申请号：PCT/EP1994002664
申请日：1994-08-10
申请人： AKZO NOBEL N.V. , SCHUTYSER, Jan, André, Jozef , BUSER, Antonius, Johannes, Wilhelmus
发明人： AKZO NOBEL N.V.
IPC分类号： C08F283/10
CPC分类号： B32B15/08 , B32B27/38 , B32B2307/3065 , B32B2363/00 , B32B2457/08 , C08F283/10 , H05K1/0326 , C08F226/06
摘要： The invention pertains to an interpenetrating polymer network (IPN) composed of (1) epoxy network forming compounds comprising: (a) polyfunctional epoxy compounds (epoxy resin); (b) polyfunctional aromatic hydroxyl compounds; (2) allyl network forming compounds; in which the (1):(2) weight ratio is in the range of 95:5 to 40:60, and the epoxy network forming compounds (1a) and (1b) are in a non-stoichiometric ratio to each other, such that the percentage of stoichiometry is in the range of 10 to 80 %. The percentage of stoichiometry is defined as 100 % times the quotient of the number of hydroxyl equivalents and the number of epoxy equivalents, i.e., eq. OH/eq. epoxy x 100 %. Such IPNs are especially suitable for use in the electronics industry and exhibit a favourable, high Tg and a low TCE. This also applies in the case of comparatively high percentages of epoxy resin giving optimum peel strength. The epoxy resin preferably is based on the diglycidyl ether of Bisphenol-A, while the allyl compound is triallyl cyanurate (TAC) or triallyl isocyanurate (TAIC).
摘要翻译：本发明涉及由（1）环氧网络形成化合物组成的互穿聚合物网络（IPN），包括：（a）多官能环氧化合物（环氧树脂）; （b）多官能芳族羟基化合物; （2）烯丙基网络形成化合物; 其中（1）：（2）重量比在95:5至40:60的范围内，环氧网络形成化合物（1a）和（1b）彼此之间的非化学计量比，化学计量的百分比在10至80％的范围内。化学计量的百分数定义为羟基当量数和环氧当量数的商数的100％，即eq。 OH / EQ。环氧树脂×100％。这样的IPN尤其适用于电子工业，并具有良好的高Tg和低TCE。这也适用于相对较高百分比的赋予最佳剥离强度的环氧树脂的情况。环氧树脂优选基于双酚A的二缩水甘油醚，烯丙基化合物是三烯丙基氰尿酸酯（TAC）或三烯丙基异氰脲酸酯（TAIC）。

3. 发明申请

WO1996007683A1 ALLYL-CONTAINING EPOXY RESIN COMPOSITION COMPRISING A COPOLYMER OF AN ETHYLENICALLY UNSATURATED ANHYDRIDE AND A VINYL COMPOUND 审中-公开
标题翻译：含有乙烯基芳族化合物和乙烯基化合物的共聚物的含环氧树脂组合物
公开(公告)号：WO1996007683A1
公开(公告)日：1996-03-14
申请号：PCT/EP1995003523
申请日：1995-09-07
申请人： AKZO NOBEL N.V. , SCHUTYSER, Jan, André, Jozef , BUSER, Antonius, Johannes, Wilhelmus
发明人： AKZO NOBEL N.V.
IPC分类号： C08F283/10
CPC分类号： C08F283/10 , H05K1/0326
摘要： The invention relates to a resin composition comprising epoxy resin, a cross linking agent for the epoxy resin in the form of a carboxylic anhydride, and at least one allyl network forming compound. According to the invention, the anhydride-functional compound is a copolymer of an ethylenically unsaturated anhydride and a vinyl compound. Notably suitable are styrene-maleic anhydride copolymers known as SMA Type 1. Surprisingly, it was found that the presence of at least 2 wt.% of triallyl cyanurate (TAC) results in an increase in Tg, such that even with simple difunctional epoxy compounds resins can be obtained which have a glass transition temperature of 130 DEG C and higher. It was further found that the processing as prepreg of epoxy resins cross-linked using anhydride-vinyl copolymers will be greatly enhanced by the presence of at least 10 % of allyl.
摘要翻译：本发明涉及包含环氧树脂，羧酸酐形式的环氧树脂交联剂和至少一种烯丙基网形成化合物的树脂组合物。根据本发明，酸酐官能化合物是烯属不饱和酸酐和乙烯基化合物的共聚物。特别合适的是称为SMA型1的苯乙烯 - 马来酸酐共聚物。令人惊奇地发现，存在至少2重量％的氰尿酸三烯丙酯（TAC）导致Tg增加，使得即使使用简单的双官能环氧化合物可以获得玻璃化转变温度为130℃以上的树脂。进一步发现，使用酸酐 - 乙烯基共聚物交联的环氧树脂预浸料的加工将通过至少10％的烯丙基的存在而大大提高。

4. 发明申请

WO1993011465A1 PHOTOPOLYMERIZABLE COMPOSITION CONTAINING INTERLINKED ALLYLIC AND EPOXY POLYMER NETWORKS 审中-公开
标题翻译：含有交联聚乙烯和环氧聚合物网络的光聚合组合物
公开(公告)号：WO1993011465A1
公开(公告)日：1993-06-10
申请号：PCT/EP1992002332
申请日：1992-10-09
申请人： AKZO N.V. , BREEVELD, Ricardo, Henry , SCHUTYSER, Jan, André, Jozef
发明人： AKZO N.V.
IPC分类号： G03F07/027
CPC分类号： G03F7/027 , C08F283/10 , C23C18/208 , C23C18/2086 , C23C18/22 , H05K3/0023 , H05K3/184 , H05K3/287
摘要： The invention pertains to a photopolymerizable composition comprising a mixture of interpenetrating network-forming monomers and a photo-initiator, the interpenetrating network-forming monomers comprising ethylenically unsaturated compounds capable of forming a polymer network, and a mixture capable of forming an epoxy resin network. The polymer network is formed, at least partially, from allylic compounds. Essentially the polymer network and the epoxy resin network are interlinked by means of a compound having both an ethylenically unsaturated functional group and a functional group reactive towards at least one of the ingredients in the epoxy resin network. Preferably, said compound is an ethylenically unsaturated epoxy crosslinker, such as maleic anhydride. The photopolymerizable composition, which optionally further comprises photopolymerizable vinylic monomers, a film-forming binder, solvent, pigments, and other additives, proves particularly useful as an additive plating resist, or - if additive catalysts are added - as an electroless platable resist.
摘要翻译：本发明涉及包含互穿网络形成单体和光引发剂的混合物的可光聚合组合物，包含能够形成聚合物网络的烯键式不饱和化合物的互穿网络形成单体和能够形成环氧树脂网络的混合物。至少部分地由烯丙基化合物形成聚合物网络。基本上聚合物网络和环氧树脂网络通过具有烯键式不饱和官能团和对环氧树脂网络中的至少一种成分具有反应性的官能团的化合物相互连接。优选地，所述化合物是烯属不饱和环氧交联剂，例如马来酸酐。可任选地进一步包含可光聚合的乙烯基单体，成膜粘合剂，溶剂，颜料和其它添加剂的可光聚合组合物被证明特别可用作添加电镀抗蚀剂，或者 - 如果加入添加剂催化剂，则可以作为无电镀层抗蚀剂。

5. 发明申请

WO1993011176A1 PHOSPOROUS CONTAINING RESIN 审中-公开
标题翻译：含PHOSPOROUS的树脂
公开(公告)号：WO1993011176A1
公开(公告)日：1993-06-10
申请号：PCT/EP1992002705
申请日：1992-11-24
申请人： AKZO N.V. , SCHUTYSER, Jan, André, Jozef , BUSER, Antonius, Johannes, Wilhelmus , STEENBERGEN, André
发明人： AKZO N.V.
IPC分类号： C08F283/10
CPC分类号： C08G59/304 , C08F283/10 , H05K1/0373 , Y10S428/901 , Y10S525/903 , Y10T428/31518
摘要： Resin composed of an interpenetrating network (IPN) into which an organic phosphorous compound is incorporated. The IPN is composed of an allyl polymer network and an epoxy resin network. More particularly, a chemically incorporated phosphorus compound is present in at least one of the networks. Such an IPN can be produced by replacing at least one of the ingredients of an IPN-forming reaction mixture known in itself wholly or in part with an organic phosphorus compound which has at least one functional group reactive towards at least one of the other ingredients.
摘要翻译：由掺入有机磷化合物的互穿网络（IPN）构成的树脂。 IPN由烯丙聚合物网络和环氧树脂网络组成。更具体地，在至少一个网络中存在化学掺入的磷化合物。这样的IPN可以通过将本身完全或部分已知的具有至少一个官能团的有机磷化合物本身已知的至少一种本身已知的IPN形成反应混合物的成分替代至少一种其它成分来制备。

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