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    • 4. 发明申请
    • STABILISED HYDROXYLAMINE SOLUTIONS
    • 稳定羟胺
    • WO1997022549A1
    • 1997-06-26
    • PCT/EP1996005771
    • 1996-12-20
    • BASF AKTIENGESELLSCHAFTSCHNEIDER, Hans-MichaelLEUTNER, Bernd
    • BASF AKTIENGESELLSCHAFT
    • C01B21/14
    • C01B21/149
    • The present invention relates to stabilised hydroxylamine solutions containing as stabilizer at least one compound of general formula (I) R R N -A-NR R or salts thereof. In said formula (I): A stands for alkylene, alkenylene, alkinylene, cycloalkylene, cycloalkenylene, arylene, o-, m- or p-xylylene, or a five- or six-member saturated or unsaturated heterocycle with a nitrogen atom, the groups in question can have 1, 2 or 3 substituents selected independently of one another from among alkyl, alkoxy or hydroxyl, or stands for the group -X-[-NR-B-]-n- wherein B and X stand for -CH2CH2- or -CH2CH2CH2-, n stands for a number between 10 and 50,000, R stands for H, alkyl, an ethylene or propylene group substituted with OH, NH2, NHCOR or COOH, CSSH, CH2CN or CH2PO3H2 or represents a bridge with a nitrogen atom of another polyethyleneimine or polypropyleneimine chain, said bridge being formed by -[-NR-B-]-o- or CH2 CHOH CH2-[-O CH2 CH2-]-p-CH2 CHOH CH2-, o and p independently of one another standing for 1-15, R stands for H, C1-C18 alkyl or CHR COR , R standing for a C12-C18 alkyl group, R , R , R , R independently of one another stand for H, CH2COOH, CH2PO3H2, alkyl, acyl, CH2CH2OH, CH2CH2NH2 or (a) in which R stands for OH, SH, NH2, CN, COOH, alkyl or alkoxy. Excepted from the disclosure are ethylenediamino-tetraacetic acid and N-hydroxyethylenediamino-triacetic acid and the salts thereof.
    • 本发明涉及含有作为稳定剂的通式(I)的至少一种化合物稳定化的羟胺溶液,R <1> [R <2> N-A-NR <3> [R <4>包括那些其中A是亚烷基,亚烯基,亚炔基 ,环亚烷基,环亚烯基,亚芳基,邻 - ,间 - 或对 - 亚二甲苯基,5-或6-元饱和或具有氮原子可能已所述残基1,2或3个取代基,其中独立选择的不饱和的杂环 是烷基,烷氧基或羟基,或-X - [ - NR-B - ] - ,n是其中B和X -CH2CH2-或-CH2CH2CH2-,正10-50000,R是H, 烷基,a表示被OH,NH 2,NHCOR <5>或COOH基取代的乙烯或丙烯基团,CSSH,CH 2 CN或CH2PO3H2或为桥到另一个聚乙烯亚胺或聚亚丙基链的氮原子,由桥 - [ - NR-B - ] - O或CH 2 CHOH CH 2 - [ - CH 2 CH 2 -O - ] - 形成在p-CH 2 CHOH CH 2,和邻 p独立地是1-15,R <5> <6> COR <6>为H,C1-C18烷基或CHR,其中R <6>表示C12-C18烷基,R <1?, R'2> [R <3>和R <4>独立地是H,CH 2 COOH,CH2PO3H2,烷基,酰基,CH2CH2OH,CH2CH2NH2或(a),其中R <7>表示OH,SH,NH 2,CN, COOH,烷基或烷氧基,或含有它们的盐,除乙二胺四乙酸和N- hydroxyethylenediaminotriacetic和它们的盐。