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    • 3. 发明申请
    • SEGMENTED POLYMERS AND METHOD FOR THE SYNTHESIS THEREOF
    • 分离聚合物及其合成方法
    • WO1987007529A1
    • 1987-12-17
    • PCT/GB1987000415
    • 1987-06-15
    • COURTAULDS PLCBROOK, Basil, WilliamDUNK, William, Albert, EdwardBAGULEY, Maurice, EdwardSAVILLE, Brian
    • COURTAULDS PLC
    • B01F17/00
    • B01F17/0057C08F293/00
    • A surface active agent contains at least one radical generator group in each of its lipophilic and hydrophilic moieties. A water-in-oil dispersion or oil-in-water dispersions contains a first polymerisable monomer dissolved in the oil phase and a second monomer dissolved in the oil phase and a second monomer dissolved in the aqueous phase. A surface active agent as defined above is dispersed across the interface of the oil phase and the aqueous phase with its lipophilic moiety well solvated by the oil phase and its hydrophilic moiety well solvated by the aqueous phase. A segmented polymer comprising such a surface active agent having at least one lipophilic polymer segment attached to its lipophilic moiety and at least one hydrophilic polymer segment attached to its hydrophilic moiety can be formed from the dispersion.
    • 表面活性剂在其亲脂性部分和亲水部分的每一个中含有至少一个自由基生成剂基团。 油包水分散体或水包油分散体含有溶解在油相中的第一可聚合单体和溶解在油相中的第二单体和溶解在水相中的第二单体。 如上定义的表面活性剂分散在油相和水相的界面上,其亲油部分被油相及其亲水部分很好地溶剂化,并被水相很好地溶剂化。 包含这样的表面活性剂的分段聚合物可以由分散体形成,所述表面活性剂具有连接到其亲脂性部分的至少一个亲脂性聚合物链段和连接到其亲水部分的至少一个亲水性聚合物链段。