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1. 发明申请

WO2006069204A3 PROCESS FOR TRANSITIONING BETWEEN ZIEGLER-NATTA-BASED AND CHROMIUM-BASED CATALYSTS 审中-公开
标题翻译：基于沸石和基于铬的催化剂之间的转移过程
公开(公告)号：WO2006069204A3
公开(公告)日：2006-09-14
申请号：PCT/US2005046498
申请日：2005-12-21
申请人： UNIVATION TECH LLC , GOODE MARK G , CANN KEVIN J , HUSSEIN DAVID F , SANTANA ROBERT L , SCHUTZ DAVID C , AGAPIOU AGAPIOS K
发明人： GOODE MARK G , CANN KEVIN J , HUSSEIN DAVID F , SANTANA ROBERT L , SCHUTZ DAVID C , AGAPIOU AGAPIOS K
IPC分类号： C08F2/42 , C08F2/34 , C08F10/00
CPC分类号： C08F10/02 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F2/34 , C08F2/42 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F210/08
摘要： Embodiments of our invention relate to processes for transitioning among polymerization catalyst systems including processes for transitioning among olefin polymerization reactions using Ziegler-Natta catalysts systems and chromium-based catalyst systems. Among embodiments contemplated are a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor, comprising: adding to the reactor a deactivating agent (DA) selected from one of carbon monoxide, carbon dioxide, or combinations thereof; adding to the reactor a cocatalyst adsorbing agent (CAA), comprising an inorganic oxide selected from one of silica, alumina or combinations thereof; wherein the first catalyst comprises at least one conventional Ziegler-Natta catalyst, and a cocatalyst, wherein the second catalyst comprises at least one chromium-based catalyst, wherein the reactor is a gas-phase, fluidized bed reactor, and wherein the CAA is substantially free of transition metals. In another embodiment a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor is contemplated, comprising: adding a transition aid agent (TAA) wherein the TAA is selected from one of alkoxylated amines, alkoxylated amides, or combinations thereof, wherein the first catalyst comprises at least one Ziegler-Natta catalyst comprising the catalyst, a cocatalyst and optionally a support, and the second catalyst comprises at least one chromiumbased catalyst.
摘要翻译：本发明的实施方案涉及在聚合催化剂体系中过渡的方法，包括使用齐格勒 - 纳塔催化剂体系和铬基催化剂体系在烯烃聚合反应中过渡的方法。考虑的实施方案是在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：向反应器中加入选自一氧化碳，二氧化碳或其组合中的一种失活剂（DA）; 向所述反应器中加入选自二氧化硅，氧化铝或其组合的无机氧化物的助催化剂吸附剂（CAA）; 其中所述第一催化剂包含至少一种常规齐格勒 - 纳塔催化剂和助催化剂，其中所述第二催化剂包含至少一种铬基催化剂，其中所述反应器是气相流化床反应器，并且其中所述CAA基本上没有过渡金属。在另一个实施方案中考虑了在烯烃聚合反应器中从第一催化剂转变为第二催化剂的方法，包括：加入转移助剂（TAA），其中TAA选自烷氧基化胺，烷氧基化酰胺或其组合之一其中所述第一催化剂包含至少一种齐格勒 - 纳塔催化剂，其包含所述催化剂，助催化剂和任选的载体，所述第二催化剂包含至少一种基于铬的催化剂。

2. 发明申请

WO2005044863A1 POLYMERIZATION PROCESS AND CONTROL OF POLYMER COMPOSITION PROPERTIES 审中-公开
标题翻译：聚合过程和聚合物组合物性质的控制
公开(公告)号：WO2005044863A1
公开(公告)日：2005-05-19
申请号：PCT/US2004/009411
申请日：2004-03-25
申请人： UNIVATION TECHNOLOGIES, LLC , EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P. , SANTANA, Robert, L. , SHANNON, Porter, C.
发明人： EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P. , SANTANA, Robert, L. , SHANNON, Porter, C.
IPC分类号： C08F2/34
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F4/65904 , C08F2/40 , C08F2/34 , C08F2/005 , C08F2/38 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/07 , C08F210/08 , C08F2500/05 , C08F2500/01 , C08F2500/02
摘要： Methods of controlling rheological properties of polymer compositions comprising at least one high molecular weight polymer and one low molecular weight polymer are disclosed. The polymer compositions are produced by polymerizing monomers in a single reactor using a bimetallic catalyst composition. A control agent such as, for example, an alcohol, ether, oxygen or amine is added to the reactor to control the rheological properties of the reactor. The polymerization takes place in the presence of rheological-altering compounds such as alkanes and aluminum alkyls. The control agents are added in an amount sufficient to counter the influences of the rheological-altering compounds.
摘要翻译：公开了控制包含至少一种高分子量聚合物和一种低分子量聚合物的聚合物组合物的流变性质的方法。聚合物组合物通过使用双金属催化剂组合物在单个反应器中聚合单体来制备。将控制剂例如醇，醚，氧或胺加入到反应器中以控制反应器的流变性能。聚合反应发生在流变学变化化合物如烷烃和烷基铝的存在下。加入的控制剂的量足以抵抗流变改变化合物的影响。

3. 发明申请

WO2003047752A1 METHOD OF MAKING MIXED ZIEGLER-NATTA/METALLOCENE CATALYSTS 审中-公开
标题翻译：制备混合的ZIEGLER-NATTA / METALLOCENE催化剂的方法
公开(公告)号：WO2003047752A1
公开(公告)日：2003-06-12
申请号：PCT/US2002/031777
申请日：2002-10-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
发明人： MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
IPC分类号： B01J31/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F4/6541 , C08F4/651 , C08F4/6546 , C08F4/65904 , C08F210/14 , C08F2500/12 , C08F4/025
摘要： Methods of making mixed Ziegler-Natta/metallocene catalysts are disclosed. The methods include slurrying a dehydrated support in a hydrocarbon solvent, adding a dialkylmagnesium compound, then adding a non-metallocene group 4 or 5 metal compound, followed by adding a metallocene, an alumoxane, and optionally an aklyl aluminum compound and an electron donor compound, followed by drying the product. The alumoxane is added in an aromatic solvent.
摘要翻译：公开了制造混合的齐格勒 - 纳塔/茂金属催化剂的方法。所述方法包括将脱水载体在烃溶剂中制浆，加入二烷基镁化合物，然后加入非茂金属基团4或5金属化合物，然后加入茂金属，铝氧烷和任选的烷基铝化合物和电子给体化合物，然后干燥产品。将铝氧烷加入芳族溶剂中。

4. 发明申请

WO2006069204A2 PROCESS FOR TRANSITIONING BETWEEN ZIEGLER-NATTA-BASED AND CHROMIUM-BASED CATALYSTS 审中-公开
标题翻译：基于齐格勒 - 纳塔克星和铬基催化剂之间的过渡过程
公开(公告)号：WO2006069204A2
公开(公告)日：2006-06-29
申请号：PCT/US2005/046498
申请日：2005-12-21
申请人： UNIVATION TECHNOLOGIES, LLC , GOODE, Mark, G. , CANN, Kevin, J. , HUSSEIN, David, F. , SANTANA, Robert, L. , SCHUTZ, David, C. , AGAPIOU, Agapios, K.
发明人： GOODE, Mark, G. , CANN, Kevin, J. , HUSSEIN, David, F. , SANTANA, Robert, L. , SCHUTZ, David, C. , AGAPIOU, Agapios, K.
IPC分类号： C08F2/42 , C08F10/00 , C08F2/34
CPC分类号： C08F10/02 , C08F210/16 , C08F2410/05 , Y10S526/901 , C08F2/34 , C08F2/42 , C08F210/14 , C08F2500/12 , C08F2500/07 , C08F2500/18 , C08F210/08
摘要： Embodiments of our invention relate to processes for transitioning among polymerization catalyst systems including processes for transitioning among olefin polymerization reactions using Ziegler-Natta catalysts systems and chromium-based catalyst systems. Among embodiments contemplated are a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor, comprising: adding to the reactor a deactivating agent (DA) selected from one of carbon monoxide, carbon dioxide, or combinations thereof; adding to the reactor a cocatalyst adsorbing agent (CAA), comprising an inorganic oxide selected from one of silica, alumina or combinations thereof; wherein the first catalyst comprises at least one conventional Ziegler-Natta catalyst, and a cocatalyst, wherein the second catalyst comprises at least one chromium-based catalyst, wherein the reactor is a gas-phase, fluidized bed reactor, and wherein the CAA is substantially free of transition metals. In another embodiment a method of transitioning from a first catalyst to a second catalyst in an olefin polymerization reactor is contemplated, comprising: adding a transition aid agent (TAA) wherein the TAA is selected from one of alkoxylated amines, alkoxylated amides, or combinations thereof, wherein the first catalyst comprises at least one Ziegler-Natta catalyst comprising the catalyst, a cocatalyst and optionally a support, and the second catalyst comprises at least one chromiumbased catalyst.
摘要翻译：本发明的实施方案涉及聚合催化剂体系之间的转换方法，包括使用齐格勒 - 纳塔催化剂体系和铬基催化剂体系在烯烃聚合反应之间转换的方法。所考虑的实施方式中有一种在烯烃聚合反应器中从第一催化剂转化为第二催化剂的方法，包括：向反应器中加入选自一氧化碳，二氧化碳或其组合中的一种的去活化剂（DA）向反应器中加入助催化剂吸附剂（CAA），其包含选自二氧化硅，氧化铝或其组合中的一种的无机氧化物; 其中所述第一催化剂包含至少一种常规齐格勒 - 纳塔催化剂和助催化剂，其中所述第二催化剂包含至少一种铬基催化剂，其中所述反应器为气相流化床反应器，并且其中所述CAA基本上不含过渡金属。在另一个实施方案中，考虑了在烯烃聚合反应器中从第一催化剂转化为第二催化剂的方法，包括：添加转变助剂（TAA），其中TAA选自烷氧基化胺，烷氧基化酰胺或其组合中的一种其中所述第一催化剂包含至少一种齐格勒 - 纳塔催化剂，所述齐格勒 - 纳塔催化剂包含所述催化剂，助催化剂和任选的载体，并且所述第二催化剂包含至少一种基于铬和钐的催化剂。

5. 发明申请

WO2003047751A1 BIMETALLIC CATALYSTS WITH HIGHER ACTIVITY 审中-公开
标题翻译：具有较高活性的双金属催化剂
公开(公告)号：WO2003047751A1
公开(公告)日：2003-06-12
申请号：PCT/US2002/031491
申请日：2002-10-03
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
发明人： MINK, Robert, I. , NOWLIN, Thomas, E. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , SHIRODKAR, Pradeep, P.
IPC分类号： B01J31/00
CPC分类号： C08F10/02 , C08F4/65904 , C08F4/65912 , C08F4/65925 , C08F4/6546 , C08F4/65916 , C08F4/025
摘要： Methods of preparing bimetallic catalysts are disclosed. The methods include the steps of providing a supported non-metallocene catalyst, contacting a slurry of the supported non-metallocene catalyst in a non-polar hydrocarbon with a solution of a metallocene compound and an alumoxane, and drying the contact product to obtain a supported bimetallic catalyst. The supported non-metallocene catalyst is prepared by dehydrating a particulate support material at a temperature of greater than 600 °C, preparing a slurry of the dehydrated support in a non-polar hydrocarbon, contacting the slurry with an organomagnesium compound and an alcohol, contacting the resulting slurry with a non-metallocene compound of a Group 4 or Group 5 transition metal, and drying the contact product to obtain a supported non-metallocene catalyst as a free-flowing powder. The bimetallic catalysts show increased activity relative to catalysts prepared using support materials dehydrated at lower temperatures.
摘要翻译：公开了制备双金属催化剂的方法。所述方法包括提供负载的非金属茂催化剂的步骤，使非极性烃中负载的非金属茂催化剂的浆液与茂金属化合物和铝氧烷的溶液接触，并干燥该接触产物以获得负载的双金属催化剂。负载的非茂金属催化剂是通过在大于600℃的温度下脱水颗粒状载体材料制备的，将脱水载体的浆料制备在非极性烃中，使该浆料与有机镁化合物和醇接触，得到的浆料与第4族或第5族过渡金属的非茂金属化合物，并干燥该接触产物，得到负载型非茂金属催化剂作为自由流动的粉末。相对于使用在较低温度下脱水的载体材料制备的催化剂，双金属催化剂显示出增加的活性。

6. 发明申请

WO2003044061A1 POLYMERIZATION MONITORING AND CONTROL USING LEADING INDICATORS 审中-公开
标题翻译：使用引导指标的聚合监测和控制
公开(公告)号：WO2003044061A1
公开(公告)日：2003-05-30
申请号：PCT/US2002/032765
申请日：2002-10-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P.
发明人： SCHURZKY, Kenneth, G. , SANTANA, Robert, L. , EHRMAN, Fred, D. , SHIRODKAR, Pradeep, P.
IPC分类号： C08F2/34
CPC分类号： C08F10/02 , C08F4/65904 , C08F4/65916 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/34 , C08F210/14 , C08F2500/12
摘要： Methods of monitoring and controlling polymerization reactions are disclosed. The ratio of concentrations of two reactor components are determined in a gas stream of a reactor to obtain a leading indicator function L. The value of L or a function of L, such as rescaled value or a reciprocal, is compared to a target value, and at least one reactor parameter is adjusted in response to a deviation between L or the function of L and the target value. Monitoring of the leading indicator permits rapid diagnosis of reactor problems, and rapid adjustments of reactor parameters, compared to laboratory analysis of samples of polymer properties.
摘要翻译：公开了监测和控制聚合反应的方法。在反应器的气流中确定两个反应器组分的浓度比，以获得前导指示函数L.将L或L的函数（例如重新缩放值或倒数）的值与目标值进行比较，并且响应于L或L的函数与目标值之间的偏差来调整至少一个电抗器参数。与聚合物性质样品的实验室分析相比，主要指标的监测可以快速诊断反应堆问题，并快速调整反应器参数。

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