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    • 1. 发明申请
    • COMPOSITIONS BASED ON SELF-EXTINGUISHING EXPANDABLE VINYL AROMATIC POLYMERS
    • 基于自发挥发性芳香族芳族聚合物的组合物
    • WO2013064444A1
    • 2013-05-10
    • PCT/EP2012/071330
    • 2012-10-29
    • VERSALIS S.P.APONTICIELLO, AntonioSIMONELLI, AlessandraSAIU, MaurizioFELISARI, RiccardoVALENTINO, Olga
    • PONTICIELLO, AntonioSIMONELLI, AlessandraSAIU, MaurizioFELISARI, RiccardoVALENTINO, Olga
    • C08K5/00C08K5/02C08K5/58C08J9/00C08J9/18
    • C08K5/0066C08J9/0019C08J9/0052C08J9/0066C08J9/16C08J9/224C08J9/232C08J2201/03C08J2325/04C08K5/02C08K5/58C08L25/04
    • The present invention relates to a composition based on self-extinguishing expandable vinyl aromatic polymers, which comprises: a) a polymer obtained by the polymerization of one or more vinyl aromatic monomers present in an amount ranging from 50% to 100% by weight, and a monomer copolymerizable with the vinyl aromatic monomers, homogeneously englobed in the polymer in an amount ranging from 0% to 50% by weight; b) at least one expandable system in an amount ranging from 3% to 10% by weight, calculated with respect to the polymer (a); c) at least one flame-retardant additive in an amount ranging from 0.005% to 5% by weight, calculated with respect to the polymer (a), and containing at least 30% by weight of bromine, said amount being calculated with respect to the flame-retardant additive; d) at least one synergetic additive containing a C-C or C-O-O-C thermolabile bond in an amount ranging from 0.001% to 2% by weight, calculated with respect to the polymer (a); and e) at least one athermanous additive selected from carbon-black, a graphite, a carbon coke in particle form and mixtures thereof; said composition is characterized in that it contains a stabilizing additive including at least one tin alkyl mercapto-ester having a purity higher than or equal to 95%.
    • 本发明涉及一种基于自熄性可膨胀乙烯基芳族聚合物的组合物,其包括:a)通过一种或多种乙烯基芳族单体的聚合获得的聚合物,其量为50重量%至100重量%,和 可与乙烯基芳族单体共聚的单体,均匀地嵌入聚合物中,其量为0重量%至50重量%; b)相对于聚合物(a)计算的至少一种可膨胀体系,其量为3重量%至10重量%; c)相对于聚合物(a)计算的至少一种量为0.005重量%至5重量%的阻燃添加剂,并且含有至少30重量%的溴,所述量相对于 阻燃添加剂; d)至少一种含有相对于聚合物(a)计算的0.001重量%至2重量%的C-C或C-O-O-C不耐热粘合剂的协同添加剂; 和e)至少一种选自碳黑,石墨,颗粒形式的碳焦炭及其混合物的惰性添加剂; 所述组合物的特征在于其含有稳定添加剂,其包含至少一种纯度高于或等于95%的烷基巯基酯。