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1. 发明授权

US6037383A Microcellular polyurethane elastomer containing urea groups 失效
标题翻译：含有尿素基团的微孔聚氨酯弹性体
公开(公告)号：US6037383A
公开(公告)日：2000-03-14
申请号：US91638
申请日：1998-10-07
申请人： Ruediger Krech , Udo Rotermund , Heinz Bollmann , Renate Hempel , Wolfgang Scholz , Manfred Genz
发明人： Ruediger Krech , Udo Rotermund , Heinz Bollmann , Renate Hempel , Wolfgang Scholz , Manfred Genz
IPC分类号： C08J9/36 , C08G18/08 , C08G18/76 , C08G18/04
CPC分类号： C08G18/7664 , C08G18/089 , C08G2101/0066 , C08G2101/0083 , C08G2350/00
摘要： A microcellular PU elastomer having improved dynamic mechanical properties and based on an isocyanate component consisting essentially of 4,4'-MDI and further customary constituents has a physicochemical structure which, in the gel permeation chromatograph (GPC) of a solution of the microcellular polyurethane elastomer prepared at 90.degree. C. in N,N-dimethylformamide containing 1 percent of di-n-butylamine measured against polymethyl methacrylate (PMMA) as standard, displays a signal occurring in addition to low molecular weight main signal and comprising one or more peaks at an (apparent) molar mass of greater than 250,000 g/mol which becomes smaller or disappears on addition of lithium chloride to this solution, and a urea content of from 14 to 18% by weight.A process is also provided for preparing such a microcellular PU elastomer having improved dynamic mechanical properties. The microcellular PU elastomers can be used for producing damping elements.
摘要翻译： PCT No.PCT / EP96 / 05640 Sec。 371日期：1998年10月7日 102（e）日期1998年10月7日PCT 1996年12月16日PCT公布。出版物WO97 / 23535 日期1997年7月3日具有改善的动态力学性能并基于由4,4'-MDI和其他常规组分组成的异氰酸酯组分的微孔PU弹性体具有物理化学结构，其在溶液的凝胶渗透色谱（GPC）在90℃下在含有1％二正丁胺的N，N-二甲基甲酰胺中制备的聚氨基甲酸甲酯（PMMA）作为标准的微孔聚氨酯弹性体显示除了低分子量主信号之外还发生的信号，并且包含摩尔质量大于250,000g / mol的一个或多个峰变得更小或在向该溶液中加入氯化锂时消失，尿素含量为14至18重量％。还提供了一种制备这种具有改进的动态力学性能的微孔PU弹性体的方法。微孔PU弹性体可用于制造阻尼元件。

2. 发明授权

US08507633B2 Thermoplastic polyurethanes 有权
标题翻译：热塑性聚氨酯
公开(公告)号：US08507633B2
公开(公告)日：2013-08-13
申请号：US12293103
申请日：2007-04-11
申请人： Oliver Steffen Henze , Ruediger Krech , Frank Prissok , Karin Scheffer , Frank Schaefer , Heinrich Niermann
发明人： Oliver Steffen Henze , Ruediger Krech , Frank Prissok , Karin Scheffer , Frank Schaefer , Heinrich Niermann
IPC分类号： C08G18/00
CPC分类号： A43B1/14 , A43B5/04 , C08G18/4854 , C08G18/6674 , C08G2120/00
摘要： A process for the preparation of thermoplastic polyurethane by reacting (a) isocyanates with (b) compounds reactive toward isocyanates and having a molecular weight (Mw) of from 500 to 10 000 g/mol and (c) chain extenders having a molecular weight of from 50 to 499 g/mol, if appropriate in the presence of (d) catalysts and/or (e) conventional additives, wherein the chain extender mixture consisting of a main chain extender (c1) and one or more co-chain extenders (c2) is used and the thermoplastic polyurethane prepared has a rigid phase fraction of greater than 0.40, the rigid phase fraction being defined by the following formula: rigid ⁢ ⁢ phase ⁢ ⁢ fraction = { ∑ x = 1 k ⁢ [ ( m KVx / M KVx ) * M Iso + m KVx ] } / m ges with the following meanings: MKVx: molar mass of the chain extender x in g/mol mKVx: mass of the chain extender x in g MIso: molar mass of the isocyanate used in g/mol mges: total mass of all starting materials in g k: number of chain extenders.
摘要翻译：一种通过使（a）异氰酸酯与（b）对异氰酸酯具有反应性并且分子量（Mw）为500至10000g / mol的化合物和（c）分子量为在（d）催化剂和/或（e）常规添加剂的存在下，如果合适，其为50至499g / mol，其中由主链延长剂（c1）和一种或多种共扩链剂（ c2），所制备的热塑性聚氨酯具有大于0.40的刚性相分数，刚性相分数由下式定义：刚性相凝固分数= {Σx = 1 k [（m KVx / M KVx）* M Iso + m KVx]} / m ges，具有以下含义：MKVx：扩链剂的摩尔质量x（g / mol）mKVx：扩链剂的质量（以g计）MIso：所用异氰酸酯的摩尔质量以g / mol mges为单位：所有原料的总质量（gk）：增链剂数量。

3. 发明申请

US20100221474A1 THERMOPLASTIC POLYURETHANE WITH ANTISTATIC PROPERTIES 有权
标题翻译：具有抗静电性能的热塑性聚氨酯
公开(公告)号：US20100221474A1
公开(公告)日：2010-09-02
申请号：US12668698
申请日：2008-07-15
申请人： Frank Prissok , Frank Schaefer , Gitta Egbers , Ruediger Krech , Carsten Guenther
发明人： Frank Prissok , Frank Schaefer , Gitta Egbers , Ruediger Krech , Carsten Guenther
IPC分类号： B32B1/08 , C08K5/3445
CPC分类号： C08G18/0895 , C08G18/4238 , C08K3/017 , C08K5/3445 , C08K5/41 , C08K2201/017 , Y10T428/1352 , Y10T428/139 , C08L75/04
摘要： The present invention relates to antistatic, thermoplastic polyurethane comprising ethylmethylimidazole ethyl sulfate, to a process for production of antistatic, thermoplastic polyurethane comprising ethylmethylimidazole ethyl sulfate, and to the use of ethylmethylimidazole ethyl sulfate for the production of antistatic, thermoplastic polyurethane.
摘要翻译：本发明涉及一种包含乙基甲基咪唑乙基硫酸酯的抗静电的热塑性聚氨酯，涉及用于制备包含乙基甲基咪唑乙基硫酸酯的抗静电的热塑性聚氨酯的方法，以及使用乙基甲基咪唑乙基硫酸酯制备抗静电的热塑性聚氨酯。

4. 发明申请

US20110003961A1 THERMOPLASTIC POLYURETHANE WITH REDUCED FORMATION OF DEPOSIT 有权
标题翻译：具有减少形成沉积物的热塑性聚氨酯
公开(公告)号：US20110003961A1
公开(公告)日：2011-01-06
申请号：US12918910
申请日：2009-02-19
申请人： Oliver Steffen Henze , Stephan Friederichs , Ruediger Krech , Katja Hackmann , Marc Hansen
发明人： Oliver Steffen Henze , Stephan Friederichs , Ruediger Krech , Katja Hackmann , Marc Hansen
IPC分类号： C08G18/32 , C09K3/00 , B29C45/00 , C08G18/34
CPC分类号： C08G18/664 , C08G18/3206 , C08G18/73
摘要： A thermoplastic polyurethane is obtainable via reaction of the following components A, B, C, and, if appropriate, D and E (e) at least one aliphatic, organic diisocyanate, as component A, (f) at least one compound which is reactive toward component A and which has a weight-average molar mass of from 500 to 10 000 g/mol, as component B, (g) a mixture composed of alkanediols as chain extenders, comprising from 60 to 85 mol % of 1,6-hexanediol as main chain extender C1 and from 15 to 40 mol % of 1,3-propanediol as co-chain extender C2, as component C, (h) at least one catalyst, as component D, (i) conventional additives as component E.
摘要翻译：热塑性聚氨酯可以通过以下组分A，B，C和（如果合适的话）D和E（e）至少一种作为组分A的脂族有机二异氰酸酯反应获得，（f）至少一种反应性的化合物对于组分A，其重均分子量为500至10000g / mol，作为组分B，（g）由作为扩链剂的链烷二醇组成的混合物，包含60至85mol％的1,6-己二醇，作为组分C的（C），（h）至少一种催化剂作为组分D，（i）作为组分E的常规添加剂。

5. 发明授权

US08715799B2 Thermoplastic polyurethane with antistatic properties 有权
标题翻译：具有抗静电性能的热塑性聚氨酯
公开(公告)号：US08715799B2
公开(公告)日：2014-05-06
申请号：US12668698
申请日：2008-07-15
申请人： Frank Prissok , Frank Schaefer , Gitta Egbers , Ruediger Krech , Carsten Guenther
发明人： Frank Prissok , Frank Schaefer , Gitta Egbers , Ruediger Krech , Carsten Guenther
IPC分类号： B32B1/08 , C08K5/34 , C08K5/41
CPC分类号： C08G18/0895 , C08G18/4238 , C08K3/017 , C08K5/3445 , C08K5/41 , C08K2201/017 , Y10T428/1352 , Y10T428/139 , C08L75/04
摘要： The present invention relates to antistatic, thermoplastic polyurethane comprising ethylmethylimidazole ethyl sulfate, to a process for production of antistatic, thermoplastic polyurethane comprising ethylmethylimidazole ethyl sulfate, and to the use of ethylmethylimidazole ethyl sulfate for the production of antistatic, thermoplastic polyurethane.
摘要翻译：本发明涉及一种包含乙基甲基咪唑乙基硫酸酯的抗静电的热塑性聚氨酯，涉及用于制备包含乙基甲基咪唑乙基硫酸酯的抗静电的热塑性聚氨酯的方法，以及使用乙基甲基咪唑乙基硫酸酯制备抗静电的热塑性聚氨酯。

6. 发明授权

US08287788B2 Method for the continuous production of thermoplastically-processable polyurethane elastomers 有权
标题翻译：连续生产热塑性聚氨酯弹性体的方法
公开(公告)号：US08287788B2
公开(公告)日：2012-10-16
申请号：US11815221
申请日：2006-01-31
申请人： Guenter Scholz , Marian Mours , Sven Lawrenz , Horst Papenfuss , Christoph Bahr , Ruediger Krech
发明人： Guenter Scholz , Marian Mours , Sven Lawrenz , Horst Papenfuss , Christoph Bahr , Ruediger Krech
IPC分类号： B29C47/78 , C08G18/00
CPC分类号： C08G18/222 , B29C35/02 , B29C47/0004 , B29C47/0021 , B29C47/34 , B29C47/40 , B29C47/50 , B29C47/786 , B29C47/827 , B29C47/862 , B29K2021/00 , B29K2075/00 , B29K2105/0014 , C08G18/0895 , C08G18/664 , C08G18/6674
摘要： The present invention relates to a process for the continuous production of thermoplastically processable polyurethane elastomers, by metering a polyisocyanate (A), a proportion of 1-80 equivalent%, based on the isocyanate group content of the polyisocyanate (A), of a compound (B) having an average of at 1.8-3.0 hydrogen atoms having Zerewitinoff activity, with an average molar mass of 450-5000 g/mol, and a proportion of 12-99 equivalent%, based on the isocyanate group content of the polyisocyanate (A), of a chain extender (C), into a self-cleaning twin-screw extruder whose diameter is 32-62 mm, which is operated at shear rates above 6000 s−1 and residence times of 1-20 seconds, and then bringing the mixture from the self-cleaning twin-screw extruder into a second apparatus in order to complete the reaction.
摘要翻译：本发明涉及一种通过计量多异氰酸酯（A），以聚异氰酸酯（A）的异氰酸酯基含量为基准的1-80当量％的化合物的连续制备热塑性加工性聚氨酯弹性体的方法，（B）平均摩尔质量为450-5000g / mol，平均摩尔质量为12-99当量％，基于多异氰酸酯的异氰酸酯基含量（B），其具有平均摩尔质量为1.8〜3.0的Zerewitinoff活性， A）为扩链剂（C），直径为32-62mm的自清洁双螺杆挤出机，其剪切速率高于6000s -1，停留时间为1-20秒，然后将来自自清洁双螺杆挤出机的混合物引入第二装置以完成反应。

7. 发明申请

US20100048834A1 CABLE SHEATHING 审中-公开
标题翻译：电缆穿线
公开(公告)号：US20100048834A1
公开(公告)日：2010-02-25
申请号：US12519771
申请日：2007-12-12
申请人： Oliver Steffen Henze , Rolf Steinberger , Ruediger Krech , Nicole Duevel
发明人： Oliver Steffen Henze , Rolf Steinberger , Ruediger Krech , Nicole Duevel
IPC分类号： C08L75/04 , C08G18/00
CPC分类号： C08G18/3206 , C08G18/3212 , C08G18/675 , H01B3/302
摘要： Cable sheathing on the basis of thermoplastic polyurethane based on the reaction of (a) isocyanates with (b) diols, wherein the diol (b) is based on straight-chain or branched diols (i) having from 16 to 45 carbon atoms in an uninterrupted carbon skeleton.
摘要翻译：基于（a）异氰酸酯与（b）二醇的反应的基于热塑性聚氨酯的电缆护套，其中二醇（b）基于具有16至45个碳原子的直链或支链二醇（i）不间断的碳骨架。

8. 发明授权

US06538075B1 Thermoplastic polyurethane 失效
标题翻译：热塑性聚氨酯
公开(公告)号：US06538075B1
公开(公告)日：2003-03-25
申请号：US10048275
申请日：2002-01-28
申请人： Ruediger Krech , Juergen Mueller , Norbert Pohlmann , Paul Sellig , Rolf Steinberger
发明人： Ruediger Krech , Juergen Mueller , Norbert Pohlmann , Paul Sellig , Rolf Steinberger
IPC分类号： C08G1882
CPC分类号： C08G18/0895 , C08G18/664 , C08G18/83 , H01B3/302
摘要： The invention relates to thermoplastic polyurethane with a Shore hardness of 45A to 80A, a tensile strength, according to DIN 53504, higher than 5 Mpa, a tear strength, according to DIN 53515 higher than 30 N/mm and an abrasion according to DIN 53516 of less than 250 mm3.
摘要翻译：本发明涉及肖氏硬度为45A至80A的热塑性聚氨酯，根据DIN 53504的拉伸强度高于5Mpa，根据DIN 53515的撕裂强度高于30N / mm，根据DIN 53516的耐磨性小于250mm3。

9. 发明授权

US5621024A Preparation of thermoplastic polyurethanes 失效
标题翻译：热塑性聚氨酯的制备
公开(公告)号：US5621024A
公开(公告)日：1997-04-15
申请号：US542274
申请日：1995-10-12
申请人： Peter Eberhardt , Ruediger Krech , Udo Rotermund , Klaus Techritz
发明人： Peter Eberhardt , Ruediger Krech , Udo Rotermund , Klaus Techritz
IPC分类号： C08J3/20 , B29B7/88 , B29B11/10 , B29K75/00 , C08G18/00 , C08G18/08
CPC分类号： C08G18/0895 , B29C47/6087
摘要： The present invention relates to a process for the preparation of thermoplastic polyurethane by reacting a) organic and/or modified organic polyisocyanates with b) at least one oligomeric polyhydroxy and/or polyamino compound having an average molecular weight of from 400 to 10,000 g/mol, in the presence or absence of c) chain extenders having at least two Zerewitinoff-active hydrogen atoms and an average molecular weight of less than 400 g/mol, d) catalysts, e) compounds which are less than difunctional with respect to isocyanates and/or isocyanates which are less than difunctional and, f) assistants and/or additives, in a twin-screw extruder in which both screws rotate in the same direction and which has a length of/diameter ratio of from 20 to 6 and discharging the resulting thermoplastic polyurethane from the extruder with shaping.
摘要翻译：本发明涉及通过使a）有机和/或改性的有机多异氰酸酯与b）至少一种平均分子量为400至10,000g / mol的低聚多羟基和/或聚氨基化合物反应来制备热塑性聚氨酯的方法存在或不存在c）具有至少两个Zerewitinoff-活性氢原子和平均分子量小于400g / mol的扩链剂，d）催化剂，e）相对于异氰酸酯而言小于二官能度的化合物和 /或小于二官能度的异氰酸酯，和f）辅助剂和/或添加剂，其中两个螺杆沿相同方向旋转，并且其长度/直径比为20至6，并将从挤出机得到的热塑性聚氨酯与成型。

10. 发明授权

US08822624B2 Thermoplastic polyurethane with reduced formation of deposit 有权
标题翻译：热塑性聚氨酯减少沉积物的形成
公开(公告)号：US08822624B2
公开(公告)日：2014-09-02
申请号：US12918910
申请日：2009-02-19
申请人： Oliver Steffen Henze , Stephan Friederichs , Ruediger Krech , Katja Hackmann , Marc Hansen
发明人： Oliver Steffen Henze , Stephan Friederichs , Ruediger Krech , Katja Hackmann , Marc Hansen
IPC分类号： C08G18/32 , C09K3/00 , B29C45/00 , C08G18/34 , C08G18/73 , C08G18/66
CPC分类号： C08G18/664 , C08G18/3206 , C08G18/73
摘要： A thermoplastic polyurethane is obtainable via reaction of the following components A, B, C, and, if appropriate, D and E (e) at least one aliphatic, organic diisocyanate, as component A, (f) at least one compound which is reactive toward component A and which has a weight-average molar mass of from 500 to 10 000 g/mol, as component B, (g) a mixture composed of alkanediols as chain extenders, comprising from 60 to 85 mol % of 1,6-hexanediol as main chain extender C1 and from 15 to 40 mol % of 1,3-propanediol as co-chain extender C2, as component C, (h) at least one catalyst, as component D, (i) conventional additives as component E.
摘要翻译：热塑性聚氨酯可以通过以下组分A，B，C和（如果合适的话）D和E（e）至少一种作为组分A的脂族有机二异氰酸酯反应获得，（f）至少一种反应性的化合物对于组分A，其重均分子量为500至10000g / mol，作为组分B，（g）由作为扩链剂的链烷二醇组成的混合物，包含60至85mol％的1,6-己二醇，作为组分C的（C），（h）至少一种催化剂作为组分D，（i）作为组分E的常规添加剂。

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