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1. 发明授权

US06177375B1 High activity olefin polymerization catalysts 失效
标题翻译：高活性烯烃聚合催化剂
公开(公告)号：US06177375B1
公开(公告)日：2001-01-23
申请号：US09037138
申请日：1998-03-09
申请人： Thomas J. Pullukat , Ronald S. Shinomoto
发明人： Thomas J. Pullukat , Ronald S. Shinomoto
IPC分类号： B01J3100
CPC分类号： C08F10/00 , C08F4/6548 , C08F4/6565
摘要： A method for preparing a silica supported, &agr;-olefin polymerization catalyst includes the steps of treating a silica support with an organosilane compound, contacting the silylated silica support with a transition metal compound to form an intermediate, then contacting the resulting intermediate with an alkylmagnesium alkoxide to form the catalyst. The transition metal compound is either a metal chloride or a metal chloroalkoxide, and the transition metal is selected from titanium, vanadium, and zirconium. The alkylmagnesium alkoxide may be selected from butylethylmagnesium butoxide, butylethylmagnesium 2-ethylhexoxide, butyloctylmagnesium ethoxide, or butylmagnesium propoxide. The process steps may be carried out in the presence of an aliphatic organic solvent, such as heptane, with a slurry of solids in the solvent being formed during the process steps. Catalysts produced by this process, during which the alkylmagnesium alkoxide contacts the reacting components after the transition metal compound is applied, have higher activities when compared with catalysts prepared by known processes under similar conditions.
摘要翻译：制备二氧化硅负载的α-烯烃聚合催化剂的方法包括以下步骤：用有机硅烷化合物处理二氧化硅载体，使甲硅烷基化二氧化硅载体与过渡金属化合物接触以形成中间体，然后使所得中间体与烷基醇镁以形成催化剂。过渡金属化合物是金属氯化物或金属氯代醇盐，过渡金属选自钛，钒和锆。烷基镁醇盐可以选自丁基丁基丁基铵，丁基乙基-2-乙基氧化乙基镁，丁基辛基镁乙醇盐，或丁基丙基镁。方法步骤可以在脂族有机溶剂如庚烷的存在下进行，在工艺步骤期间在溶剂中形成固体浆料。通过该方法生产的催化剂在烷基镁化合物与过渡金属化合物之间的反应组分接触时，与在类似条件下通过已知方法制备的催化剂相比，具有较高的活性。

2. 发明授权

US5473028A Process and a catalyst for preventing reactor fouling 失效
标题翻译：工艺和防止反应堆结垢的催化剂
公开(公告)号：US5473028A
公开(公告)日：1995-12-05
申请号：US229516
申请日：1994-04-19
申请人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
发明人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
IPC分类号： C08F2/34 , C08F4/02 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/14 , C08F210/16 , C08J5/18 , C08L23/08 , C08L23/16
CPC分类号： C08J5/18 , C08F210/16 , C08L23/0815 , C08F4/61912 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F4/65925 , C08J2323/08 , C08L2314/06 , Y10S526/901 , Y10S526/943
摘要： A support containing methylalumoxane and derivatives thereof is described which is formed by an incipient impregnation technique. The most preferred support is silica. Incipient impregnation in accordance with the invention provides a supported alumoxane, methylalumoxane, which substantially eliminates the problem of fluid bed reactor fouling when methylalumoxane is introduced into the reactor during its operation. The process comprises providing methylaluminoxane in particulate form for use as a catalytic component in the fluidized bed gas phase polymerization process.In accordance with the invention, the process comprises providing methylalumoxane activated metallocene compound in particulate form as catalysts in fluid bed gas phase.
摘要翻译：描述了通过初始浸渍技术形成的包含甲基铝氧烷及其衍生物的载体。最优选的载体是二氧化硅。根据本发明的初始浸渍提供了负载的铝氧烷，甲基铝氧烷，其基本上消除了当甲基铝氧烷在其操作期间引入反应器时流化床反应器结垢的问题。该方法包括提供颗粒形式的甲基铝氧烷，用作流化床气相聚合方法中的催化组分。根据本发明，该方法包括以颗粒形式提供甲基铝氧烷活化的茂金属化合物作为流化床气相中的催化剂。

3. 发明授权

US5723402A Silicas with specific contents of cations as supports for olefin polymerization catalysts 失效
标题翻译：具有阳离子的具体含量的硅油作为烯烃聚合催化剂的载体
公开(公告)号：US5723402A
公开(公告)日：1998-03-03
申请号：US655178
申请日：1996-05-30
申请人： Thomas J. Pullukat , Ronald S. Shinomoto , Carl A. Gillings
发明人： Thomas J. Pullukat , Ronald S. Shinomoto , Carl A. Gillings
IPC分类号： B01J21/02 , B01J21/08 , C08F4/659 , C08F4/6592 , C08F10/00 , B01J21/14
CPC分类号： C08F10/00 , B01J21/02 , B01J21/08 , C08F4/65916 , C08F4/65925
摘要： A process of producing supported olefin polymerization catalysts in which the support is a porous silica material containing specified amounts of alkali and alkaline metal cations, and olefin polymerization catalysts produced thereby.
摘要翻译：制备负载型烯烃聚合催化剂的方法，其中载体是含有特定量的碱金属和碱金属阳离子的多孔二氧化硅材料，以及由此生产的烯烃聚合催化剂。

4. 发明授权

US5461017A Olefin polymerization catalysts 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US5461017A
公开(公告)日：1995-10-24
申请号：US205430
申请日：1994-03-04
申请人： Allan B. Furtek , Ronald S. Shinomoto
发明人： Allan B. Furtek , Ronald S. Shinomoto
IPC分类号： B01J31/06 , B01J31/14 , B01J31/16 , B01J31/22 , C08F4/619 , C08F4/6192 , C08F10/00 , B01J31/12
CPC分类号： B01J31/165 , B01J31/06 , B01J31/143 , B01J31/2295 , C08F10/00 , B01J2531/48 , C08F4/61912 , C08F4/61916 , C08F4/6192 , C08F4/61922
摘要： An improved catalyst for the polymerization of olefins comprising at least one metallocene and at least one aluminoxane co-catalyst supported on a substrate comprising a cross-linked polymeric, porous, resin wherein at least one of the monomers in the resin has at least one pendant functional group which is not reactive under the conditions of the formation of the substrate, and therefore survives the copolymerization which forms the substrate. One specific cross-linked resin is a copolymer of styrene, divinyl benzene and acetoxy styrene.
摘要翻译：一种用于烯烃聚合的改进的催化剂，其包含至少一种茂金属和至少一种负载在包含交联聚合物，多孔树脂的基材上的铝氧烷助催化剂，其中树脂中的至少一种单体具有至少一个侧基在形成基材的条件下不具有反应性的官能团，因此在形成基材的共聚中存活。一种具体的交联树脂是苯乙烯，二乙烯基苯和乙酰氧基苯乙烯的共聚物。

5. 发明授权

US5362824A Olefin polymerization catalysts 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US5362824A
公开(公告)日：1994-11-08
申请号：US991486
申请日：1992-12-15
申请人： Allan B. Furtek , Ronald S. Shinomoto
发明人： Allan B. Furtek , Ronald S. Shinomoto
IPC分类号： C08F4/619 , C08F4/6192 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/61912 , C08F4/61916 , C08F4/61922 , Y10S526/943
摘要： An improved catalyst for the polymerization of olefins comprising at least one metallocene and at least one aluminoxane co-catalyst supported on a substrate comprising a cross-linked polymeric, porous, resin wherein at least one of the monomers in the resin has at least one pendant functional group which is not reactive under the conditions of the formation of the substrate, and therefore survives the copolymerization which forms the substrate. One specific cross-linked resin is a copolymer of styrene, divinyl benzene and acetoxy styrene.
摘要翻译：一种用于烯烃聚合的改进的催化剂，其包含至少一种茂金属和至少一种负载在包含交联聚合物，多孔树脂的基材上的铝氧烷助催化剂，其中树脂中的至少一种单体具有至少一个侧基在形成基材的条件下不具有反应性的官能团，因此在形成基材的共聚中存活。一种具体的交联树脂是苯乙烯，二乙烯基苯和乙酰氧基苯乙烯的共聚物。

6. 发明授权

US5602067A Process and a catalyst for preventing reactor fouling 失效
标题翻译：工艺和防止反应堆结垢的催化剂
公开(公告)号：US5602067A
公开(公告)日：1997-02-11
申请号：US333685
申请日：1994-11-03
申请人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
发明人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
IPC分类号： C08F4/02 , B01J31/14 , B01J31/16 , B01J31/22 , B01J31/38 , C08F4/619 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/16 , C08J5/18 , C08L23/08 , C08L23/16 , B01J31/00
CPC分类号： B01J31/38 , B01J31/143 , B01J31/1616 , B01J31/2295 , C08F10/00 , C08F210/16 , C08J5/18 , C08L23/0815 , B01J2531/48 , B01J2531/49 , C08F4/61912 , C08F4/61916 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65922 , C08F4/65925 , C08J2323/08 , C08L2314/06 , Y02P20/588
摘要： A support containing methylalumoxane and derivatives thereof is described which is formed by an incipient impregnation technique. The most preferred support is silica. Incipient impregnation in accordance with the invention provides a supported alumoxane, methylalumoxane, which substantially eliminates the problem of fluidized bed reactor fouling when methylalumoxane is introduced into the reactor during its operation. In accordance with the invention, the process comprises providing methylalumoxane activated metallocene compound in particulate form as catalysts in fluidized bed gas phase operation.
摘要翻译：描述了通过初始浸渍技术形成的包含甲基铝氧烷及其衍生物的载体。最优选的载体是二氧化硅。根据本发明的初始浸渍提供了负载的铝氧烷，甲基铝氧烷，其基本上消除了当甲基铝氧烷在其操作期间引入反应器时流化床反应器结垢的问题。根据本发明，该方法包括在流化床气相操作中提供颗粒形式的甲基铝氧烷活化的茂金属化合物作为催化剂。

7. 发明授权

US6001764A Olefin polymerization catalysts with specific silica supports 失效
标题翻译：具有特定二氧化硅载体的烯烃聚合催化剂
公开(公告)号：US6001764A
公开(公告)日：1999-12-14
申请号：US75279
申请日：1998-05-08
申请人： Thomas J. Pullukat , Ronald S. Shinomoto , Reinhard H. Witt
发明人： Thomas J. Pullukat , Ronald S. Shinomoto , Reinhard H. Witt
IPC分类号： B01J31/00 , C08F4/02 , C08F10/00
CPC分类号： C08F10/00 , C08F110/02
摘要： A catalyst having a high pore volume, high surface area porous silica support and a non-metallocene, Ziegler-Natta catalytic component incorporated on the silica support is provided for the production of polyolefins from .alpha.-olefins. The porous silica support is made up of silica gel particles having an average surface area of about 600 to about 800 m.sup.2 /g of silica and an average pore volume of about 2.5 to about 4.0 ml/g of silica. Preferably, the silica particles have an average surface area of about 650 to about 750 m.sup.2 /g of silica and an average pore volume of about 2.75 to about 3.25 ml/g of silica. Even more preferably, the silica particles have an average surface area of about 700 m.sup.2 /g of silica and an average pore volume of about 3.0 ml/g of silica. The catalytic component comprises a complex product of a transition metal halide and a metal alkyl which excludes cyclopentadienyl rings.
摘要翻译：提供了一种具有高孔体积，高表面积多孔二氧化硅载体和非金属茂的催化剂，并入二氧化硅载体上的齐格勒 - 纳塔催化组分用于从α-烯烃生产聚烯烃。多孔二氧化硅载体由具有约600至约800m 2 / g二氧化硅的平均表面积和约2.5至约4.0ml / g二氧化硅的平均孔体积的硅胶颗粒组成。优选地，二氧化硅颗粒的平均表面积为约650至约750m 2 / g二氧化硅，平均孔体积为约2.75至约3.25ml / g二氧化硅。甚至更优选地，二氧化硅颗粒的平均表面积为约700m 2 / g二氧化硅，平均孔体积为约3.0ml / g二氧化硅。催化组分包括过渡金属卤化物和不包括环戊二烯基环的金属烷基的复合产物。

8. 发明授权

US5332706A Process and a catalyst for preventing reactor fouling 失效
标题翻译：工艺和防止反应堆结垢的催化剂
公开(公告)号：US5332706A
公开(公告)日：1994-07-26
申请号：US997421
申请日：1992-12-28
申请人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
发明人： Thomas E. Nowlin , Frederick Y. Lo , Ronald S. Shinomoto , Pradeep P. Shirodkar
IPC分类号： C08F2/34 , C08F4/02 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/658 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/14 , C08F210/16 , C08J5/18 , C08L23/08 , C08L23/16
CPC分类号： C08J5/18 , C08F210/16 , C08L23/0815 , C08F4/61912 , C08F4/65912 , C08F4/65916 , C08F4/65922 , C08F4/65925 , C08J2323/08 , C08L2314/06 , Y10S526/901 , Y10S526/943
摘要： A support containing methylalumoxane and derivatives thereof is described which is formed by an incipient impregnation technique. The most preferred support is silica. Incipient impregnation in accordance with the invention provides a supported alumoxane, methylalumoxane, which substantially eliminates the problem of fluid bed reactor fouling when methylalumoxane is introduced into the reactor during its operation.In accordance with the invention, the process comprises providing methylalumoxane activated metallocene compound in particulate form as catalysts in fluid bed gas phase.
摘要翻译：描述了通过初始浸渍技术形成的包含甲基铝氧烷及其衍生物的载体。最优选的载体是二氧化硅。根据本发明的初始浸渍提供了负载的铝氧烷，甲基铝氧烷，其基本上消除了当甲基铝氧烷在其操作期间引入反应器时流化床反应器结垢的问题。根据本发明，该方法包括以颗粒形式提供甲基铝氧烷活化的茂金属化合物作为流化床气相中的催化剂。

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