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    • 2. 发明授权
    • Process for preparing high internal phase ratio emulsions and latexes
derived thereof
    • 制备高内相比乳液和衍生自其的胶乳的方法
    • US5539021A
    • 1996-07-23
    • US463151
    • 1995-06-05
    • James E. PateJames PetersNanette E. LutenskeRonald R. Pelletier
    • James E. PateJames PetersNanette E. LutenskeRonald R. Pelletier
    • B01F3/08B01F15/04B01J13/00C08J3/03C08J3/09C08J3/02
    • B01J13/0086B01J13/00C08J3/03C08J3/09Y10S516/929
    • The present invention is a method of preparing a high internal phase ratio emulsion without phase inversion comprising the steps of:a) continuously merging into a disperser and in the presence of an emulsifying and a stabilizing amount of a surfactant, a continuous phase liquid stream having a flow rate R.sub.1, and a disperse phase liquid stream having a flow rate R.sub.2 ; andb) mixing the merged streams with a sufficient amount of shear, and with R.sub.2 :R.sub.1 sufficiently constant, to form the high internal phase ratio emulsion without phase inversion or stepwise distribution of an internal phase into an external phase;wherein R.sub.2 :R.sub.1 encompasses a range, the lower limit of which range being defined by a point where the volume average particle size of the high internal phase ratio emulsion begins to show an inverse dependence on R.sub.2 :R.sub.1, and wherein the upper limit of which range is just less than an R.sub.2 :R.sub.1 where a phase inversion of the high internal phase ratio emulsion takes place.Monodisperse submicron particles can be prepared using the process of the present invention. Useful latexes can be prepared from these high internal phase ratio emulsions.
    • 本发明是一种制备不含相转化的高内相比乳液的方法,包括以下步骤:a)连续合并到分散器中,并在乳化剂和稳定剂量的表面活性剂存在下,连续相液体流具有 流量R1和具有流量R2的分散相液体流; 和b)将合并的流与足够量的剪切混合,并使R2:R1充分恒定,以形成高内相比乳液,而不会内相逐步分配到外相中; 其中R2:R1包含一个范围,其下限限定在高内相比乳液的体积平均粒径开始显示与R2:R1的反相关性的点,其中其上限 范围小于R2:R1,其中发生高内相比乳液的相转化。 可以使用本发明的方法制备单分散亚微米颗粒。 可以从这些高内相比乳液制备有用的胶乳。
    • 4. 发明授权
    • Bituminous compositions and method of making
    • 沥青组合物和制造方法
    • US5100939A
    • 1992-03-31
    • US647954
    • 1991-01-30
    • John F. VitkuskeLu H. TungRonald R. PelletierRonald E. SnyderWilliam A. Gros
    • John F. VitkuskeLu H. TungRonald R. PelletierRonald E. SnyderWilliam A. Gros
    • C08L95/00
    • C08L95/00
    • Disclosed are bituminous blends having improved toughness and elasticity. The blends contain a bituminous binder and a tapered block copolymer formed from a monovinyl aromatic compound and a conjugated diene. Suitable tapered block copolymers include a tapered A-B-A type block copolymer of the A-t-B-t-A configuration, particularly those having an isolated monovinyl aromatic compound content of about 20 to about 90 weight percent, and tapered A-B-A type block copolymers of the A-B-t-A configuration having an isolated monovinyl aromatic compound content of about 20 to about 90 weight percent of the total monovinyl aromatic compound in the tapered block copolymer. Further disclosed is a method of making the blends. Further disclosed is a tapered A-B-A type block copolymer having an isolated monovinyl aromatic compound content of about 29 to about 75 weight percent.
    • 公开了具有改进的韧性和弹性的沥青混合物。 共混物含有沥青粘合剂和由单乙烯基芳族化合物和共轭二烯形成的渐缩嵌段共聚物。 合适的锥形嵌段共聚物包括AtBtA构型的锥形ABA型嵌段共聚物,特别是具有约20至约90重量%的单一乙烯基芳族化合物含量的渐缩ABA型嵌段共聚物和具有分离的单乙烯基芳族化合物的ABtA构型的锥形ABA型嵌段共聚物 含量为锥形嵌段共聚物中总单乙烯基芳族化合物的约20至约90重量%。 进一步公开了制备共混物的方法。 进一步公开了具有约29-约75重量%的分离的单乙烯基芳族化合物含量的锥形A-B-A型嵌段共聚物。
    • 5. 发明授权
    • Tapered block copolymers
    • 锥形嵌段共聚物
    • US5234999A
    • 1993-08-10
    • US800342
    • 1991-11-26
    • Lu H. TungRonald R. PelletierRonald E. SnyderWilliam A. Gros
    • Lu H. TungRonald R. PelletierRonald E. SnyderWilliam A. Gros
    • C08L95/00
    • C08L95/00
    • Disclosed are bituminous blends having improved toughness and elasticity. The blends contain a bituminous binder and a tapered block copolymer formed from a monovinyl aromatic compound and a conjugated diene. Suitable tapered block copolymers include a tapered A-B-A type block copolymer of the A-t-B-t-A configuration, particularly those having an isolated monovinyl aromatic compound content of about 20 to about 90 weight percent, and tapered A-B-A type block copolymers of the A-B-t-A configuration having an isolated monovinyl aromatic compound content of about 20 to about 90 weight percent of the total monovinyl aromatic compound in the tapered block copolymer. Further disclosed is a method of making the blends. Further disclosed is a tapered A-B-A type block copolymer having an isolated monovinyl aromatic compound content of about 29 to about 75 weight percent.
    • 公开了具有改进的韧性和弹性的沥青混合物。 共混物含有沥青粘合剂和由单乙烯基芳族化合物和共轭二烯形成的渐缩嵌段共聚物。 合适的锥形嵌段共聚物包括AtBtA构型的锥形ABA型嵌段共聚物,特别是具有约20至约90重量%的单一乙烯基芳族化合物含量的渐缩ABA型嵌段共聚物和具有分离的单乙烯基芳族化合物的ABtA构型的锥形ABA型嵌段共聚物 含量为锥形嵌段共聚物中总单乙烯基芳族化合物的约20至约90重量%。 进一步公开了制备共混物的方法。 进一步公开了具有约29-约75重量%的分离的单乙烯基芳族化合物含量的锥形A-B-A型嵌段共聚物。
    • 6. 发明授权
    • High-strength films of block copolymer latices
    • 高强度嵌段共聚物胶片
    • US5563204A
    • 1996-10-08
    • US469182
    • 1995-06-06
    • David R. SpethRonald R. PelletierBrian W. Walther
    • David R. SpethRonald R. PelletierBrian W. Walther
    • B29C41/00B29C71/02B29D7/01C08J3/03C08J5/18C08L53/02C08K5/01C08L53/00
    • C08J3/03B29C41/003B29D7/01C08J5/18C08L53/02C08L53/025B29C71/02B29K2009/06B29K2096/04B29K2105/0064C08J2353/02
    • An aqueous dispersion is claimed which is capable of forming a free-standing, coherent, elastomeric, solid film which, after drying and annealing at 80.degree. C. for 30 minutes, demonstrates a tensile strength of about 11.0 MPa or greater wherein the dispersion comprises: I. an organic phase comprising: (a) one or more block copolymer(s) corresponding to the formula A-B-X.sub.m -(B-A).sub.n, wherein each A polymer block consists essentially of a monovinylidene aromatic monomer, having a weight average molecular weight from about 8,000 to about 15,000 Daltons, each B polymer block consists essentially of a conjugated diene and, optionally, a monovinylidene aromatic monomer having a weight average molecular weight from about 30,000 to about 200,000 Daltons, X is the remnant of a multifunctional coupling agent, m is 0 or 1, and n is an integer from 1 to 5, and (b) optionally, an extender for the block copolymer which is compatible with the B block; II. a surfactant; and III. water, wherein the A block effective phase volume in the organic phase is from about 5 to about 20 percent.
    • 要求保护的水分散体,其能够形成独立的,粘连的,弹性体的固体膜,其在80℃下干燥和退火30分钟后,表现出约11.0MPa或更大的拉伸强度,其中分散体包含 :I.有机相,其包含:(a)对应于式AB-Xm-(BA)n的一种或多种嵌段共聚物,其中每个A聚合物嵌段基本上由单亚乙烯基芳族单体组成,其具有重均分子量 每个B聚合物嵌段基本上由共轭二烯和任选的重均分子量为约30,000至约200,000道尔顿的单亚乙烯基芳族单体组成,X是多官能偶联剂的残余物 ,m为0或1,n为1至5的整数,(b)任选地,与B嵌段相容的嵌段共聚物的增量剂; 二, 表面活性剂; 和III。 水,其中有机相中A嵌段有效相体积为约5至约20%。