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    • 1. 发明申请
    • METHODS FOR CONSTRUCTING UNDERGROUND BOREHOLE CONFIGURATIONS AND RELATED SOLUTION MINING METHODS
    • 构造地下洞穴构造的方法和相关解决方案采矿方法
    • US20120027516A1
    • 2012-02-02
    • US13193995
    • 2011-07-29
    • Roger L. DayJames A. Herickhoff
    • Roger L. DayJames A. Herickhoff
    • E21B43/29E21B7/00E21C41/16
    • E21B7/00C01D7/00C01D7/126E21B17/00E21B33/12E21B33/13E21B43/281E21B43/30
    • Disclosed are methods for solution mining of evaporite minerals, such as trona, comprising drilling an access well and at least two lateral boreholes; injecting a fluid; circulating the fluid through the lateral boreholes with a controlled fluid flow; and collecting a pregnant solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity at a temperature sufficient to maintain at least a portion of the solution in the cavity in the Wegscheiderite solid phase region; removing aqueous solution from the cavity; and recovering alkaline values from the removed aqueous solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity; removing aqueous solution from the cavity, wherein the temperature of the removed aqueous solution is at about the TWA point temperature; and recovering alkaline values from the removed aqueous solution.
    • 公开了用于溶解开采蒸发岩矿物的方法,例如天然碱,包括钻井进入井和至少两个横向钻孔; 注射液体 以受控的流体流动流体穿过横向钻孔; 并收集怀孕的解决方案。 还公开了溶液开采的方法,其包括将水溶液注入到地下天然气腔中,该温度足以将溶液的至少一部分保持在Wegscheiderite固相区域的空腔中; 从空腔中除去水溶液; 并从去除的水溶液中回收碱值。 还公开了溶液开采的方法,包括将水溶液注入地下空心腔中; 从空腔中除去水溶液,其中去除的水溶液的温度在约TWA点温度; 并从去除的水溶液中回收碱值。
    • 4. 发明授权
    • Methods for constructing underground borehole configurations and related solution mining methods
    • 地下钻孔配置方法及相关解决方案挖掘方法
    • US08899691B2
    • 2014-12-02
    • US13193995
    • 2011-07-29
    • Roger L. DayJames A. Herickhoff
    • Roger L. DayJames A. Herickhoff
    • E21B43/00C01D7/00C01D7/12E21B43/28E21B43/30
    • E21B7/00C01D7/00C01D7/126E21B17/00E21B33/12E21B33/13E21B43/281E21B43/30
    • Disclosed are methods for solution mining of evaporite minerals, such as trona, comprising drilling an access well and at least two lateral boreholes; injecting a fluid; circulating the fluid through the lateral boreholes with a controlled fluid flow; and collecting a pregnant solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity at a temperature sufficient to maintain at least a portion of the solution in the cavity in the Wegscheiderite solid phase region; removing aqueous solution from the cavity; and recovering alkaline values from the removed aqueous solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity; removing aqueous solution from the cavity, wherein the temperature of the removed aqueous solution is at about the TWA point temperature; and recovering alkaline values from the removed aqueous solution.
    • 公开了用于溶解开采蒸发岩矿物的方法,例如天然碱,包括钻井进入井和至少两个横向钻孔; 注射液体 以受控的流体流动流体穿过横向钻孔; 并收集怀孕的解决方案。 还公开了溶液开采的方法,其包括将水溶液注入到地下天然气腔中,该温度足以将溶液的至少一部分保持在Wegscheiderite固相区域的空腔中; 从空腔中除去水溶液; 并从去除的水溶液中回收碱值。 还公开了溶液开采的方法,包括将水溶液注入地下空心腔中; 从空腔中除去水溶液,其中去除的水溶液的温度在约TWA点温度; 并从去除的水溶液中回收碱值。
    • 6. 发明申请
    • METHODS FOR CONSTRUCTING UNDERGROUND BOREHOLE CONFIGURATIONS AND RELATED SOLUTION MINING METHODS
    • 构造地下洞穴构造的方法和相关解决方案采矿方法
    • US20100066153A1
    • 2010-03-18
    • US12566446
    • 2009-09-24
    • Roger L. DayJames A. Herickhoff
    • Roger L. DayJames A. Herickhoff
    • E21C41/00
    • E21B7/00C01D7/00C01D7/126E21B17/00E21B33/12E21B33/13E21B43/281E21B43/30
    • Disclosed are methods for solution mining of evaporite minerals, such as trona, comprising drilling an access well and at least two lateral boreholes; injecting a fluid; circulating the fluid through the lateral boreholes with a controlled fluid flow; and collecting a pregnant solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity at a temperature sufficient to maintain at least a portion of the solution in the cavity in the Wegscheiderite solid phase region; removing aqueous solution from the cavity; and recovering alkaline values from the removed aqueous solution. Also disclosed are methods of solution mining that include injecting an aqueous solution into an underground trona cavity; removing aqueous solution from the cavity, wherein the temperature of the removed aqueous solution is at about the TWA point temperature; and recovering alkaline values from the removed aqueous solution.
    • 公开了用于溶解开采蒸发岩矿物的方法,例如天然碱,包括钻井进入井和至少两个横向钻孔; 注射液体 以受控的流体流动流体穿过横向钻孔; 并收集怀孕的解决方案。 还公开了溶液开采的方法,其包括将水溶液注入到地下天然气腔中,该温度足以将溶液的至少一部分保持在Wegscheiderite固相区域的空腔中; 从空腔中除去水溶液; 并从去除的水溶液中回收碱值。 还公开了溶液开采的方法,包括将水溶液注入地下空心腔中; 从空腔中除去水溶液,其中去除的水溶液的温度在约TWA点温度; 并从去除的水溶液中回收碱值。
    • 7. 发明授权
    • Process for control of crystallization of inorganics from aqueous solutions
    • 从水溶液中控制无机物结晶的方法
    • US06660049B1
    • 2003-12-09
    • US08741456
    • 1996-10-31
    • Roger L. Day
    • Roger L. Day
    • C01D700
    • C01D7/24
    • Process of crystallization of sodium bicarbonate from solution mined Nahcolite pregnant liquor comprising the use of from about 2 to 100 parts per million of lecithin, introduced full strength, made miscible in water with a soap or detergent, saponified with NaOH at a pH of 10-12, or preferably as a mixture of lecithin in pregnant or barren liquor containing HCO3−/CO3= ions at a pH in the range of from about 8 to 12, preferaby 8-10. The lecithin functions as a crystal growth modifier, producing improved crystal yields, product size classification, improved crystal shape including reduction in dendritic, branched and twinned forms, very significant scale reduction, reduction in wet cake moisture, increase in product bulk density, reduction in both oversize and undersize fractions (the classification phenomenon) and less breakage during drying and handling. The aqueous lecithin premix is preferably added to a pregnant liquor tank, and may also be added in one or more crystallizers in the circuit in batch (timed aliquots) or continuously metered in proportion to throughput. The process may also be applied to crystallization of carbonates, bicarbonates, phosphates, nitrates, sulfates, hydroxides and borates of Na, Li, K, Ca and Mg from aqueous solutions including brines. For commercial scale bicarbonate production the presently preferred range is 2-30 ppm, and for product −425 &mgr;m+45 &mgr;m the range is about 5-15 ppm. Coarse product (+425 &mgr;m) is preferably produced in the range of about 12-30 ppm.
    • 从溶液中开始的碳酸氢钠结晶过程包括使用约2-100百万份卵磷脂,引入全部强度的Nahcolite怀孕液,与肥皂或洗涤剂混合,用NaOH皂化,pH为10, 12,或优选作为在约8至12范围内的pH范围内含有HCO 3 - / CO 3β=离子的怀孕或贫瘠液体中的卵磷脂的混合物,优选8-10。 卵磷脂作为晶体生长调节剂起作用,产生改善的晶体产率,产品尺寸分级,改进的晶体形状,包括树枝状,支链和孪晶形式的减少,非常显着的水垢减少,湿饼水分的减少,产品堆积密度的增加, 过大和过小的部分(分类现象),干燥和处理期间的破损少。 水性卵磷脂预混物优选加入到怀孕液体罐中,并且还可以以批量(定时等分试样)在电路中的一个或多个结晶器中加入或与生产量成比例地连续计量。 该方法也可以应用于包括盐水的水溶液中的Na,Li,K,Ca和Mg的碳酸盐,碳酸氢盐,磷酸盐,硝酸盐,硫酸盐,氢氧化物和硼酸盐的结晶。 对于商业规模的碳酸氢盐生产,目前优选的范围是2-30ppm,对于产品-425mum + 45mum,范围是约5-15ppm。 粗产物(+ 424mg)优选在约12-30ppm的范围内产生。