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    • 3. 发明授权
    • Dielectric compositions stabilized against water treeing with organo
silane compounds containing the azomethine group and partial
condensation products
    • 用含有偶氮甲碱基和部分缩合产物的有机硅烷化合物稳定防水结构的介电组合物
    • US4263158A
    • 1981-04-21
    • US76627
    • 1979-09-18
    • Arnold C. AshcraftRobert J. Turbett
    • Arnold C. AshcraftRobert J. Turbett
    • C08K5/5465H01B3/30H01B3/44H01B3/46H01B7/28
    • H01B7/28C08K5/5465H01B3/308H01B3/441H01B3/46
    • A dielectric composition comprising ethylene polymer and effective amounts, as a water treeing inhibitor, of at least one organo silane of the following formula: ##STR1## wherein R and R.sub.1 are independently selected from hydrogen, a hydrocarbyl group or substituted hydrocarbyl groups wherein the substituents are hydroxy, halogen, nitro, C.sub.1 to C.sub.8 alkyl, C.sub.1 to C.sub.8 alkoxy; or R and R.sub.1 together with the adjacent carbon atom form a ring of 3 to 7 carbon atoms; R.sub.2 is C.sub.1 to C.sub.8 alkyl, C.sub.1 to C.sub.18 alkoxy, C.sub.6 to C.sub.18 aryl, C.sub.1 to C.sub.8 acyloxy, C.sub.6 to C.sub.18 substituted or unsubstituted aryloxy; R.sub.3 and R.sub.4 are independently selected from C.sub.1 to C.sub.18 alkoxy, C.sub.6 to C.sub.18 substituted or unsubstituted aryloxy or C.sub.1 to C.sub.8 acyloxy; Y is C.sub.1 to C.sub.8 alkylene, C.sub.6 to C.sub.18 substituted or unsubstituted arylene or --CH.sub.2 CH.sub.2 NH(CH.sub.2).sub.3 --.Partial condensation products of the silanes also have been found to inhibit water treeing in ethylene polymers.
    • 一种包含乙烯聚合物和有效量的作为水树木抑制剂的至少一种下式有机硅烷的电介质组合物:其中R和R 1独立地选自氢,烃基或取代的烃基,其中取代基 是羟基,卤素,硝基,C 1至C 8烷基,C 1至C 8烷氧基; 或R和R 1与相邻的碳原子一起形成3至7个碳原子的环; R2是C1至C8烷基,C1至C18烷氧基,C6至C18芳基,C1至C8酰氧基,C6至C18取代或未取代的芳氧基; R 3和R 4独立地选自C 1至C 18烷氧基,C 6至C 18取代或未取代的芳氧基或C 1至C 8酰氧基; Y为C1至C8亚烷基,C6至C18取代或未取代的亚芳基或-CH2CH2NH(CH2)3-。 已经发现硅烷的部分缩合产物抑制乙烯聚合物中的水树。