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    • 1. 发明授权
    • High viscosity polyoxyalkylene glycol block copolymers and method of
making the same
    • 高粘度聚氧亚烷基二醇嵌段共聚物及其制备方法
    • US4481367A
    • 1984-11-06
    • US553880
    • 1983-11-22
    • Robert J. Knopf
    • Robert J. Knopf
    • C08G18/48C10M107/44C07C125/077C07C125/073
    • C08G18/4837C10M107/44C10M2217/042C10M2217/043C10N2240/06C10N2240/08
    • A high molecular weight, high viscosity liquid, water soluble polyoxyalkylene block copolymer suitable as a functional fluid is provided having the formula ##STR1## wherein Q is the organic residue from an organic diisocyanate; x is an integer in the range of about 1 to 10; R.sup.1 and R.sup.2 are hydrogen, methyl, ethyl, or mixtures thereof with the proviso that the overall content of species wherein R.sup.1 and R.sup.2 are hydrogen must be at least 50 percent by weight; R.sup.3 and R.sup.4 are organic residues resulting from the removal of terminal hydrogen atoms from difunctional polyols; y and z are integers representing the polyether blocks in said copolymer and the sum of which must be from about 1.05 to 2.0 times the value of x; and n, m, r, and s are integers wherein n=m and r=s and the sums n+m and r+s are each in the range of 8 to 250.
    • 提供了适合作为功能性流体的高分子量,高粘度的液体,水溶性聚氧化烯嵌段共聚物,其具有下式:其中Q是有机二异氰酸酯的有机残基; x为约1至10范围内的整数; R1和R2是氢,甲基,乙基或其混合物,条件是其中R 1和R 2是氢的物质的总含量必须为至少50重量%; R3和R4是从二官能多元醇除去末端氢原子得到的有机残基; y和z是表示所述共聚物中的聚醚嵌段的整数,其总和必须为x的约1.05至2.0倍; 并且n,m,r和s是n = m且r = s的整数,并且和n + m和r + s各自在8至250的范围内。