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    • 10. 发明授权
    • Staged catalytic ammonia decomposition in integrated gasification
combined cycle systems
    • 综合气化联合循环系统分阶段催化氨分解
    • US5912198A
    • 1999-06-15
    • US691084
    • 1996-08-01
    • Alan S. FeitelbergRaul Eduardo AyalaStephen Lan-Sun HungDavid Joseph Najewicz
    • Alan S. FeitelbergRaul Eduardo AyalaStephen Lan-Sun HungDavid Joseph Najewicz
    • B01D53/58B01D53/86C01B3/58C10J3/00C10J1/20
    • C01B3/583B01D53/58B01D53/8634C10J3/00C10K1/004C10K1/101C10K1/16C10K3/02C10K3/04C01B2203/044C01B2203/047C10J2300/165C10J2300/1662C10J2300/1687C10J2300/1861Y02E20/16Y02E20/18
    • The ammonia content of fuel gas in an IGCC power generation system is reduced through ammonia decomposition, thereby reducing the NO.sub.x emissions from the plant. The power generation system includes a gasifier, a gas turbine and at least one catalytic reactor arranged between the gasifier and the gas turbine. The catalytic reactor may be either a three stage or two stage device. The three stage reactor includes a first catalyst which promotes water-gas-shift, a second catalyst which promotes CO methanation, and a third catalyst which promotes ammonia decomposition. The two stage reactor includes a first catalyst which promotes water-gas-shift and CO methanation and a second catalyst which promotes ammonia decomposition. The plural catalytic stages may be disposed in a single vessel or successively disposed in individual vessels, and the catalysts may be in a pelletized form or coated on honeycomb structures. Alternatively, fluidized bed reactors may be used. The reactions are carried out either adiabatically or non-adiabatically. Heat from the water-gas-shift and CO methanation reactions may be used to generate steam, which can be injected downstream or sent to a steam turbine. Preferably, a second catalytic reactor is provided in parallel with the first reactor so that the two reactors can alternately receive fuel gas from the gasifier.
    • IGCC发电系统中燃气的氨含量通过氨分解而降低,从而减少了工厂的NOx排放。 发电系统包括气化器,燃气轮机和布置在气化器和燃气轮机之间的至少一个催化反应器。 催化反应器可以是三级或二级装置。 三级反应器包括促进水煤气转移的第一催化剂,促进CO甲烷化的第二催化剂和促进氨分解的第三催化剂。 两级反应器包括促进水煤气变换和CO甲烷化的第一催化剂和促进氨分解的第二催化剂。 多个催化级可以设置在单个容器中或相继设置在各个容器中,并且催化剂可以是颗粒形式或涂覆在蜂窝结构上。 或者,可以使用流化床反应器。 反应是绝热的或非绝热的。 来自水煤气变换和CO甲烷化反应的热量可用于产生蒸汽,其可以向下游喷射或送到蒸汽轮机。 优选地,与第一反应器平行地设置第二催化反应器,使得两个反应器可以交替地从气化器接收燃料气体。