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    • 6. 发明授权
    • Process for making hydrophobic silica with reduced surface area under
neutral conditions
    • 在中性条件下制备表面积减小的疏水性二氧化硅的方法
    • US5942590A
    • 1999-08-24
    • US22282
    • 1998-02-11
    • Gary Thomas BurnsQin DengJames Richard HahnClifford Carlton Reese
    • Gary Thomas BurnsQin DengJames Richard HahnClifford Carlton Reese
    • C01B33/159C01B33/16C09C1/30C08G77/00
    • B82Y30/00C01B33/16C09C1/3081C09C1/309C01P2004/51C01P2004/64C01P2006/12C01P2006/90
    • The present invention is hydrophobic silica gels having a reduced surface area and a method for their preparation under neutral conditions. The method comprises two steps, where in the first step the pH of a mixture comprising a silica hydrosol and colloidal silica is adjusted with a base to within a range of pH 3 to pH 6 to facilitate formation of a silica hydrogel having incorporated therein colloidal silica. In the second step the silica hydrogel is contacted with an organosilicon compound in the presence of a catalytic amount of a strong acid to effect hydrophobing of the silica hydrogel to form a hydrophobic silica gel having a surface area within a range of about 100 m.sup.2 /g to 450 m.sup.2 /g in the dry state. In a preferred process the hydrophobic silica gel is contacted with a sufficient quantity of a water-immiscible organic solvent to convert the hydrophobic silica hydrogel into a hydrophobic silica organogel. A water soluble compound of cerium or iron may be added during conduct of the second step to improve heat stability of the hydrophobic silica gel.
    • 本发明是具有减小的表面积的疏水性硅胶和其在中性条件下制备的方法。 该方法包括两个步骤,其中在第一步骤中,将包含二氧化硅水溶胶和胶体二氧化硅的混合物的pH调节至碱在pH 3至pH 6的范围内,以促进形成掺入胶体二氧化硅的二氧化硅水凝胶 。 在第二步骤中,二氧化硅水凝胶在催化量的强酸存在下与有机硅化合物接触,以实现二氧化硅水凝胶的疏水化,从而形成表面积在约100m 2 / g范围内的疏水性硅胶 在干燥状态下为450m2 / g。 在优选的方法中,将疏水性硅胶与足够量的与水不混溶的有机溶剂接触以将疏水性二氧化硅水凝胶转化成疏水性二氧化硅有机凝胶。 在第二步进行时可以加入铈或铁的水溶性化合物,以提高疏水硅胶的热稳定性。
    • 9. 发明授权
    • RTV silicone compositions with rapid development of green strength
    • RTV硅胶组合物具有绿色强度的快速发展
    • US06235832B1
    • 2001-05-22
    • US09456423
    • 1999-12-08
    • Qin DengRobert Harold KrahnkeLoren Dale LowerTimothy B. LuederRichard Alan PalmerNick Evan Shephard
    • Qin DengRobert Harold KrahnkeLoren Dale LowerTimothy B. LuederRichard Alan PalmerNick Evan Shephard
    • C08G7718
    • C08L83/04C08G77/12C08G77/16C08G77/18C08L83/14C08L83/00
    • A room temperature vulcanizing (RTV) silicone composition curable in the presence of moisture with rapid development of green strength. The RTV silicone composition comprises (A) 0 to about 85 weight percent polydiorganosiloxanes comprising on average at least 1.2 chain terminations per molecule selected from the group consisting of hydroxysilyl groups and alkoxysilyl groups; (B) about 10 to 95 weight percent polydiorganosiloxanes comprising on average at least 1.2 chain terminations per molecule selected from the group consisting of hydroxysilyl groups, alkoxysilyl groups, and multi-alkoxysilyl groups, provided that at least one chain termination per molecule comprises a multi-alkoxysilyl group; (C) an effective amount of a condensation catalyst; (D) 0 to about 40 weight percent of an alkoxysilane; and (E) 0 to about 60 weight percent of a filler; provided that the sum of the weight percents of Components (A) and (B) comprises about 20 to 95 weight percent based on the total weight of the RTV silicone composition.
    • 室温硫化(RTV)硅氧烷组合物在水分存在下固化,具有绿色强度的快速发展。 RTV硅氧烷组合物包含(A)0至约85重量%的聚二有机硅氧烷,其每分子平均含有至少1.2个链端,其选自羟基甲硅烷基和烷氧基甲硅烷基; (B)约10至95重量%的聚二有机硅氧烷,其每分子平均含有至少1.2个分子链,其选自羟基甲硅烷基,烷氧基甲硅烷基和多烷氧基甲硅烷基,条件是每分子至少一个链终止包括多 - 烷氧基甲硅烷基 (C)有效量的缩合催化剂; (D)0〜约40重量%的烷氧基硅烷; 和(E)0至约60重量%的填料; 只要组分(A)和(B)的重量百分比的总和相对于RTV硅氧烷组合物的总重量为约20至95重量%。
    • 10. 发明授权
    • Neutral-aged hydrophobic organosilicate-modified silica gels
    • 中性疏水性有机硅酸酯改性硅胶
    • US5807501A
    • 1998-09-15
    • US801410
    • 1997-02-20
    • Gary Thomas BurnsQin DengJames Richard HahnClifford Carlton Reese
    • Gary Thomas BurnsQin DengJames Richard HahnClifford Carlton Reese
    • C01B33/159C01B33/16C09C1/30B01J13/00C04B14/04
    • C01B33/16C09C1/3081C01P2004/61C01P2006/12C01P2006/14C01P2006/16C01P2006/22C01P2006/60C01P2006/90Y10T428/2995
    • The present invention is neutral-aged hydrophobic organosilicate-modified silica gels and a method for their preparation. The method comprises three steps, where in the first step an organosilicate-modified silica hydrosol is contacted with a strong mineral acid at a pH less than about 1 to form an organosilicate-modified silica hydrogel. In the second step the organosilicate-modified silica hydrogel is aged at a pH within a range of about pH 3.5 to pH 8. In the third step the neutral-aged organosilicate-modified silica hydrogel is contacted with an organosilicon compound in the presence of a catalytic amount of a strong acid to effect hydrophobing of the organosilicate-modified silica hydrogel to form a hydrophobic organosilicate-modified silica hydrogel having a surface area within a range of about 100 m.sup.2 /g to 750 m.sup.2 /g in the dry state. In a preferred process the hydrophobic organosilicate-modified silica hydrogel is contacted with a sufficient quantity of a water-immiscible organic solvent to convert the hydrophobic organosilicate-modified silica hydrogel into a hydrophobic organosilicate-modified silica organogel.
    • 本发明是中性老化的疏水性有机硅酸酯改性硅胶及其制备方法。 该方法包括三个步骤,其中在第一步中,将有机硅酸酯改性的二氧化硅水溶胶与pH值小于约1的强无机酸接触以形成有机硅酸酯改性的二氧化硅水凝胶。 在第二步中,将有机硅酸酯改性的二氧化硅水凝胶在pH值约为3.5至pH8的范围内老化。在第三步中,将中性有机硅酸酯改性的二氧化硅水凝胶与有机硅化合物在 催化量的强酸以实现有机硅酸酯改性二氧化硅水凝胶的疏水化,从而形成疏水性有机硅酸酯改性二氧化硅水凝胶,其在干燥状态下的表面积为约100m 2 / g至750m 2 / g。 在优选的方法中,将疏水性有机硅酸酯改性的二氧化硅水凝胶与足够量的与水不混溶的有机溶剂接触以将疏水性有机硅酸酯改性的二氧化硅水凝胶转化成疏水性有机硅酸酯改性的二氧化硅有机凝胶。