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    • 1. 发明授权
    • Nodularizing treatment employing unitized modifying agent
    • US4037643A
    • 1977-07-26
    • US606909
    • 1975-08-22
    • Prem P. MohlaAdolf HetkeRobert J. Warrick
    • Prem P. MohlaAdolf HetkeRobert J. Warrick
    • B22D2/00C21C1/08C21C1/10B22D27/20
    • B22D2/00C21C1/08C21C1/10
    • A method and apparatus is disclosed for conditioning a charge of molten cast iron, which would normally solidify with a flake graphite structure, to produce partial or total spheroidal graphite cast iron. In addition, the method and apparatus can be used to further condition a partially conditioned cast iron to yield a partial or fully spheroidal graphite cast iron. A recess is provided in the metal flow system (within or without the mold system) leading to the casting cavity or cavities. The recess has a shape and cross-section (taken in directions normal to the direction of flow of the molten charge) such that the spheroidizing agent dissolves uniformly when the molten iron flows over it to achieve unprecedented homogeneity. A dense solid unitary block of spheroidizing or nodularizing agent, substantially devoid of MgO interiorly thereof, is typically snugly fitted in said recess and mates with the side walls and bottom of said recess. The block typically presents a substantially constant and uniform interface with the molten charge during all stages of conditioning and pouring; however, a deviation in the interface area may be designed into the block to compensate for molten iron temperature variations or molten iron flow rate variations when the casting technique experiences unusually high variations in the ferrostatic pressure head. A relationship is disclosed between charge weight, charge flow rate, magnesium concentration in the spheroidizing alloy, and interface area so as to determine a desired degree of nodularity in the final casting and/or to design a solution rate compatible with a specific casting technique. The residual magnesium can be reliably maintained at a level sufficient to consistently obtain full spheroidal graphite shape. A preferred magnesium level is 0.020% to 0.040% of the weight of the casting but higher or lower levels can be reliably obtained if required by base metal chemistry. This is significant since the prior art has been unable to reliably obtain full nodularity with 0.02-0.025% residual magnesium under commercial conditions.
    • 5. 发明授权
    • Nodularizing catalyst for cast iron and method of making same
    • 铸铁球结催化剂及其制备方法
    • US4040821A
    • 1977-08-09
    • US711680
    • 1976-08-04
    • Adolf HetkePrem P. MohlaRobert J. Warrick
    • Adolf HetkePrem P. MohlaRobert J. Warrick
    • B22C9/06B22D1/00C21C1/10C22C33/08C22C28/00
    • B22D1/007B22C9/06C21C1/10Y10T428/12181Y10T428/12208Y10T428/12222
    • An improved catalyst is disclosed for making spheroidal graphite cast iron, the catalyst being in the form of a solid impervious and brittle block but severed from a sheet stock having a predetermined grid pattern of perforations or notches along at least one surface of said sheet stock. The block is substantially devoid of segregation and oxide interiorally thereof; the thickness of said block is increased over that capable of being produced by the prior art in the as-cast condition and yet devoid of segregation. The method of making such block comprises casting the molten catalyst into shallow closed pans, the cover for said pans carrying a pattern of ribs or projections, the cover and pan cooperating to define a selected configuration for an as-cast sheet stock. The resulting cast product can be manually or automatically broken along any desired module, defined by said grid pattern, to suit a variety of in plant casting applications particularly utilizing in-the-mold nodularizing treatment. The latter method places a nodularizing catalyst in a recess or reaction chamber defined within the gating system of a mold, whether constructed of bonded sand or pre-cast refractory.
    • 公开了用于制备球墨铸铁的改进的催化剂,该催化剂为固体不透性和脆性块的形式,但是沿着所述片状原料的至少一个表面具有预定的穿孔或缺口网格图案的片材切断。 该块基本上没有内部的偏析和氧化物; 所述块的厚度比在铸态条件下由现有技术产生的厚度增加,但是没有分离。 制造这种块的方法包括将熔融催化剂浇铸到浅闭合盘中,用于所述盘的盖具有肋或突起的图案,盖和盘协作以形成用于铸造片材的选定构型。 所得到的铸造产品可以沿着由所述网格图案限定的任何所需模块手动或自动断裂,以适应于各种植物浇铸应用,特别是利用模内结节化处理。 后一种方法将结节状催化剂置于限定在模具的浇注系统内的凹槽或反应室中,无论是由粘结砂或预制耐火材料构成。
    • 6. 发明授权
    • Method of making ductile iron treating agents
    • 制造球墨铸铁处理剂的方法
    • US4003424A
    • 1977-01-18
    • US630569
    • 1975-11-10
    • Adolf HetkePrem P. MohlaRobert J. Warrick
    • Adolf HetkePrem P. MohlaRobert J. Warrick
    • C21C1/10B22C7/02B22C9/04B22C9/20B22D1/00B22D27/20B22D21/00B22D25/02
    • B22C9/046B22C9/20B22D1/00B22D27/20
    • A method of making a more economical and reliable treating agent for use in late metal treatment when pouring metal castings. The treating agent is defined as an essentially homogeneous solid cast block preferably containing alloying ingredients to nodulize or inoculant ferrous metal. Each block is designed to present a generally uniform reaction surface to molten metal to be treated. This is obtained by casting the block to a shape which snugly fits a prepared basin in the mold gating system over which the molten metal to be treated must flow, or to cast the block in an annular configuration through which the molten metal must flow. The latter block has contoured inner surfaces which maintain a generally constant reactive surface as the block is consumed. These blocks are preferably prepared by simultaneously casting a large number in closely nested relation. Each mold for said blocks receives molten material, out of which the agent is formed, from a common sprue; runners interconnect the mold cavities and sprue, for example, in a simulated "Christmas tree" arrangement. The gating system and mold cavity pattern, for casting the treating agent to a special shape are all comprised of a material that will vaporize upon contact by the molten treating agent, such as polystyrene. The unitary tree structure of foam patterns and gating system is placed in a flask and surrounded by unbonded heat absorbing particles, such as sand or steel shot. Rapid solidification is assured by the selection of heat absorbing particles and by the use of the vaporizable patterns to avoid noticeable segregation in the alloy blocks. The blocks formed for the treating agent are characterized by increased homogeneity, absence of undesirable segregation, absence of internal oxidation, and absence of organic or refractory impurities; the blocks are less costly to make both as to capital requirements and operating expenses.
    • 一种在浇注金属铸件时制备更经济可靠的后处理金属处理剂的方法。 该处理剂被定义为基本上均匀的固体铸块,优选含有合成成分以使其结节化或接种黑色金属。 每个块被设计成对待处理的熔融金属呈现大致均匀的反应表面。 这是通过将块浇铸成适合于待浇铸的熔融金属必须流动的模具浇注系统中的准备好的盆地的形状,或者将块浇铸成熔融金属必须流过的环形构型。 后一块具有轮廓的内表面,当块被消耗时,其保持大体上恒定的反应性表面。 这些块优选通过以嵌套密切的关系同时浇铸大量来制备。 用于所述块的每个模具从公共浇道接收熔融材料,其中形成所述试剂; 赛跑者将模腔和浇道相互连接,例如模拟的“圣诞树”排列。 用于将处理剂浇铸成特殊形状的浇注系统和模腔图案都由当熔融处理剂如聚苯乙烯接触时将气化的材料构成。 将泡沫图案和浇注系统的单一树结构放置在烧瓶中,并由未粘合的吸热颗粒(例如砂或钢丸)包围。 通过选择吸热颗粒并通过使用可汽化图案来确保快速凝固,以避免合金块中明显的偏析。 形成用于处理剂的嵌段的特征在于均匀性增加,不存在不希望的分离,不存在内部氧化,以及不存在有机或难熔杂质; 对于资本要求和运营费用,这些块的成本较低。