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    • 4. 发明专利
    • Starch nanocomposite material
    • STARCH纳米复合材料
    • JP2014028968A
    • 2014-02-13
    • JP2013207592
    • 2013-10-02
    • Plantic Technologies Ltdプランティック・テクノロジーズ・リミテッド
    • KISHAN C KHEMANIMOAD GRAEMELASCARIS EDMONDLI GUOXINGEORGE SIMONHABSUDA JANAROBERT SHANKSANTONIETTA GENOVESEWASANTHA GUNARATNENICHOLS LANCE
    • C08L3/02C08J3/22C08K3/34
    • C08L3/02C08K3/346C08K9/04C08L2666/06
    • PROBLEM TO BE SOLVED: To provide, as a nanocomposite material including a starch and a clay having a high flaking degree as main components, a nanocomposite material endowed, for example, with improved properties, led by an advanced transparency, improved mechanical and rheological characteristics, and/or mitigated water (humidity) sensitivity and suitable as packaging materials and for other applications.SOLUTION: The provided nanocomposite material is prepared, as a virtually exfoliated nanocomposite material including: a starch; a hydrophobically modified laminar silicate clay; and water accounting for 5 wt.% to 30 wt.% of the weight of the nanocomposite material; based on a melting method in which water is added at an eventual calculated concentration of 10-50 wt.% with respect to the weight of the nanocomposite material. This nanocomposite material is endowed with improved mechanical and rheological characteristics and mitigated water sensitivity in the sense of the water intake and/or loss rate thereof being low.
    • 要解决的问题:作为纳米复合材料,提供具有高剥离度的淀粉和粘土作为主要成分的纳米复合材料,具有提高性能的纳米复合材料,其具有先进的透明性,改进的机械和流变特性 ,和/或缓解的水(湿度)敏感性并且适合作为包装材料和其他应用。解决方案:提供的纳米复合材料作为实质上剥落的纳米复合材料制备,包括:淀粉; 疏水改性层状硅酸盐粘土; 和占纳米复合材料重量的5重量%至30重量%的水; 基于熔融方法,其中相对于纳米复合材料的重量,以最终计算的浓度为10-50重量%加入水。 该纳米复合材料具有改进的机械和流变特性,并且在水的摄入和/或损失率低的意义上减轻水敏感性。
    • 5. 发明申请
    • BARRIER FILM
    • 屏障胶片
    • WO2006042364A1
    • 2006-04-27
    • PCT/AU2005/001605
    • 2005-10-18
    • PLANTIC TECHNOLOGIES LTDHENDERSON-RUTGERS, RulandeFINK, MarkOAKLEY, Nicholas, Roy
    • HENDERSON-RUTGERS, RulandeFINK, MarkOAKLEY, Nicholas, Roy
    • C08L3/00
    • B32B9/02B32B1/02B32B9/045B32B27/08B32B27/18B32B27/22B32B27/24B32B27/306B32B27/36B32B2250/24B32B2270/00B32B2307/308B32B2307/71B32B2307/7166B32B2307/7242B32B2307/7244B32B2439/60B32B2439/70B32B2553/023C08J3/18C08J2303/00C08K5/053C08K5/09C08K2201/008C08L3/02C08L3/04C08L3/06C08L3/08C08L23/0853C08L23/0861C08L29/04C08L31/04C08L71/02C08L2205/02C08L2205/03Y10T428/31786Y10T428/31797Y10T428/31913Y10T428/31971C08L2666/04C08L2666/02
    • A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1 ,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) from 0.3 to 2.5 % by weight of a C12-22 fatty acid or salt; e) from 0.25% to 3% of an emulsifier system having a hydrophilic lipophilic balance value between 2 and 10. The barrier film may be co-injection moulded with polyethylene terephthalate (PET) or polylactic acid (PLA) for blow moulding into beverage bottles, with polyethylene (PE) or polypropylene (PP) or biodegradable polymers for high gas-barrier containers or closures, or may be co-extruded with polyethylene, polypropylene or polylactic acid for thin film packaging applications or for blow-moulded containers.
    • 一种阻隔组合物,其是可注射成型且能够制成透明膜或通过共挤出和/或层压结合到多层膜产品中的组合物,所述组合物以干基计:a)45至90重量% 的淀粉和/或选自通过与羟基烷基,乙酸酯或二羧酸酐或接​​枝聚合物反应改性的淀粉的改性淀粉; b)4至12重量%的选自聚乙烯醇,聚乙酸乙烯酯的水溶性聚合物和乙烯和乙烯醇的共聚物,其具有与淀粉组分的熔融状态相容的熔点c)5至45重量% 的山梨糖醇和至少一种选自甘油,麦芽糖醇,木糖醇,甘露糖醇,甘油三油酸甘油酯,环氧化亚麻籽油或大豆油的其它增塑剂的非结晶混合物,柠檬酸三丁酯,柠檬酸乙酰基三乙酯,柠檬酸甘油酯,2,2,4 - 三甲基-1,3-戊二醇二异丁酸酯; 聚环氧乙烷或聚乙二醇; d)0.3至2.5重量%的C 12-22脂肪酸或盐; e)0.25%至3%的亲水亲油平衡值在2至10之间的乳化剂体系。阻挡膜可以与聚对苯二甲酸乙二醇酯(PET)或聚乳酸(PLA)共注塑成型,用于吹塑成饮料瓶 ,聚乙烯(PE)或聚丙烯(PP)或可生物降解的聚合物,用于高阻隔性容器或封闭物,或可与聚乙烯,聚丙烯或聚乳酸共挤出用于薄膜包装应用或吹塑容器。
    • 7. 发明申请
    • EASY OPEN WATER SOLUBLE BLISTER PACKAGE
    • 轻松开启水溶性泡罩包装
    • WO2004113192A1
    • 2004-12-29
    • PCT/AU2004/000794
    • 2004-06-21
    • PLANTIC TECHNOLOGIES LTDMACINNES, DavidFINK, Mark
    • MACINNES, DavidFINK, Mark
    • B65D75/36
    • B65D75/366B65D65/46C08L3/02C08L3/04C08L3/06C08L3/08C08L23/08C08L29/04C08L31/04C08L67/00C08L2205/02C08L2205/03Y02W90/11Y02W90/13C08L2666/02C08L2666/04
    • A blister package consists of a backing sheet (16) of cardboard, paper or plastic adhered to a blister (17) in which at least one or both of the backing sheet and the blister is made from a transparent water soluble thermoformable polymer composition. A tooth brush, cleaning utensil or garden utensil enclosed in the water soluble packaging material can be opened by placing it under running water. The packaging material is a thermoformable transparent water soluble starch or modified starch based polymer composition that is easily disintegrated by direct contact with water, and that biodegrades in waste water. The preferred starch is a high amylose maize starch. The starch can also be derived from wheat, potato, rice, oats, arrowroot and pea sources. The backing sheet is adhered to the blister by wetting the flange (19) with water and applying the backing sheet with the use of a press plate (24).
    • 泡罩包装由粘附到泡罩(17)的纸板,纸或塑料的背板(16)组成,其中背衬片和泡罩中的至少一个或两个由透明的水溶性可热成形聚合物组合物制成。 水溶性包装材料中包含的牙刷,清洁用具或花园用具可以通过将其放置在流水下来打开。 包装材料是可热成形的透明水溶性淀粉或改性淀粉基聚合物组合物,其通过与水直接接触而容易分解,并且在废水中生物降解。 优选的淀粉是高直链淀粉玉米淀粉。 淀粉还可以来自小麦,马铃薯,大米,燕麦,arrow豆和豌豆来源。 通过用水润湿凸缘(19)并使用压板(24)施加背衬片,将背板粘附到泡罩上。
    • 8. 发明申请
    • STARCH NANOCOMPOSITE MATERIALS
    • STARCH纳米复合材料
    • WO2008144845A1
    • 2008-12-04
    • PCT/AU2008/000787
    • 2008-06-02
    • PLANTIC TECHNOLOGIES LTDKHEMANI, Kishan, C.MOAD, GraemeLASCARIS, EdmondLI, Guoxin
    • KHEMANI, Kishan, C.MOAD, GraemeLASCARIS, EdmondLI, Guoxin
    • C08K3/34B65D65/38B65D65/00C08L3/00
    • C08L3/02C08K3/346C08K9/04C08L2666/06
    • In one aspect, the invention provides a substantially exfoliated nanocomposite material including starch and hydrophobically modified layered silicate clay. In another aspect, the invention provides packaging made from material including the substantially exfoliated nanocomposite material described above. The nanocomposite material has improved mechanical and rheological properties and reduced sensitivity to moisture in that the rates of moisture update and/or loss are reduced. In another aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material described above, including a step of mixing the starch in the form of an aqueous gel with the hydrophobic clay in a melt mixing device. In a further aspect, the invention provides a process for preparing the substantially exfoliated nanocomposite material, including the steps of mixing the starch with the hydrophobic clay to form a masterbatch (hereinafter "the masterbatch process") and mixing the masterbatch with further starch.
    • 一方面,本发明提供了包括淀粉和疏水改性的层状硅酸盐粘土的基本上剥离的纳米复合材料。 另一方面,本发明提供由包括上述基本上剥离的纳米复合材料的材料制成的包装。 纳米复合材料具有改善的机械和流变性能并降低对水分的敏感性,因为减少了水分更新和/或损失的速率。 另一方面,本发明提供了一种制备上述基本上脱模的纳米复合材料的方法,包括在熔融混合装置中将水性凝胶形式的淀粉与疏水性粘土混合的步骤。 在另一方面,本发明提供了制备基本上脱落的纳米复合材料的方法,包括将淀粉与疏水性粘土混合以形成母料(以下称为“母料工艺”)并将母料与另外的淀粉混合的步骤。