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1. 发明申请

US20070225470A1 Thermoplastic composition, method of making, and articles formed therefrom 有权
标题翻译：热塑性组合物，制造方法和由其形成的制品
公开(公告)号：US20070225470A1
公开(公告)日：2007-09-27
申请号：US11385171
申请日：2006-03-21
申请人： Jianbo Di , Brian Mullen , Paul Sybert
发明人： Jianbo Di , Brian Mullen , Paul Sybert
IPC分类号： C08G64/00
CPC分类号： C08G64/18 , C08F293/005 , C08L53/00 , C08L69/00 , Y10T428/31504 , Y10T428/31507 , C08L2666/14 , C08L2666/02 , C08L2666/18
摘要： A polyacrylate-polycarbonate copolymer comprises a polycarbonate block comprising aromatic carbonate units, and a polyacrylate block derived from a difinctional polyacrylate polymer having the formula Z1-(M)x-Z2 wherein M is an acrylate block unit comprising a reaction residue of a (meth)acrylate monomer, a non-(meth)acrylate monomer, or a combination comprising a (meth)acrylate and a non-(meth)acrylate monomer, at least one acrylate block unit is a (meth)acrylate monomer; x is greater than one; and Z1 and Z2 are each independently functionalized terminal groups of the formula -(A3)y-B, wherein B is a reactive group comprising a hydroxy or non-hydroxy group, A3 an aliphatic group, an aromatic group, or an aliphatic-aromatic group, y is 0 or 1, A3 is free of hydrogen atoms beta to B when B is a hydroxy group, and B and A3 are each free of sulfur atoms. A method of making, a thermoplastic composition, and articles are also disclosed.
摘要翻译：聚丙烯酸酯 - 聚碳酸酯共聚物包含包含芳族碳酸酯单元的聚碳酸酯嵌段和衍生自具有式<β的在线式描述=“在线公式”的分歧聚丙烯酸酯聚合物的聚丙烯酸酯嵌段末端=“铅”→> Z β-in-line-formula description =“In-line Formulas”end =“tail” 其中M是包含（甲基）丙烯酸酯单体，非（甲基）丙烯酸酯单体或包含（甲基）丙烯酸酯和非（甲基）丙烯酸酯单体的组合的反应残基的丙烯酸酯嵌段单元，至少一个丙烯酸酯嵌段单元是（甲基）丙烯酸酯单体; x大于1; Z 1和Z 2各自各自独立地是式的线性化方程式描述=“In-line Formulas”end =“lead”的官能化端基。 > - （A ^{3 ） <？in-line-formula description =“In-line formula”end =“tail”？>其中B是包含羟基或非羟基的反应性基团，脂族基团，芳族基团或脂肪族 - 芳族基团，y为0或1，A 3，当B是羟基时，B与B之间没有氢原子，B和A 3都不含硫原子。还公开了制备方法，热塑性组合物和制品。}

2. 发明申请

US20070191549A1 COATING COMPOSITIONS, THEIR PREPARATION, AND COATED ARTICLES MADE THEREFROM 审中-公开
标题翻译：涂料组合物，其制备和涂覆制品
公开(公告)号：US20070191549A1
公开(公告)日：2007-08-16
申请号：US11695970
申请日：2007-04-03
申请人： Glen Merfeld , Rainer Koeniger , Ali Acar , Paul Sybert , Zhaohui Su
发明人： Glen Merfeld , Rainer Koeniger , Ali Acar , Paul Sybert , Zhaohui Su
IPC分类号： C08F297/02
CPC分类号： C08G63/78 , C08K5/09 , C08K5/10 , C08K5/1515 , C08K5/17 , C08K5/29 , C08L61/24 , C08L61/28 , C08L101/00 , C09D167/03 , Y10T428/31507 , Y10T428/31786 , Y10T428/31942 , C08L2666/16
摘要： A coating composition comprising components A, B and optionally C, wherein component A comprises at least one hydroxy-terminated polyarylate. Component B is an organic species which can react with the hydroxy terminal groups of component A, and component C is a catalyst or mixture of catalysts. The hydroxy-terminated polyarylates are prepared by a solution polymerization method.
摘要翻译：包含组分A，B和任选C的涂料组合物，其中组分A包含至少一种羟基封端的多芳基化合物。组分B是可以与组分A的羟基端基反应的有机物，组分C是催化剂或催化剂的混合物。羟基封端的聚芳酯通过溶液聚合法制备。

3. 发明申请

US20060160961A1 Method for preparing copolyestercarbonates 审中-公开
标题翻译：共聚酯碳酸酯的制备方法
公开(公告)号：US20060160961A1
公开(公告)日：2006-07-20
申请号：US11276026
申请日：2006-02-10
申请人： Gregory O'Neil , Ali Acar , Paul Sybert , Pratima Rangarajan , Hongyi Zhou , Joseph Suriano
发明人： Gregory O'Neil , Ali Acar , Paul Sybert , Pratima Rangarajan , Hongyi Zhou , Joseph Suriano
IPC分类号： C08F20/00 , C08G63/00
CPC分类号： C08G63/64
摘要： A method of preparing block copolyestercarbonates wherein al one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic diacid chloride are reacted under interfacial conditions to give a hydroxy-terminated polyester intermediate. The dihydroxy-substituted aromatic compound is used in about 10 mole to about 125 mole percent excess relative to the diacid chloride. Enhanced control of hydroxy-terminated polyester intermediate molecular weight is achieved by limiting the amount of water present to provide a final salt level of greater than 30 percent. The final salt level is a theoretical value but is readily calculable. The hydroxy-terminated polyester intermediate is then converted to a block copolyestercarbonate by reaction with a carbonate precursor such as phosgene.
摘要翻译：制备嵌段共聚酯碳酸酯的方法，其中将Al 1羟基取代的芳族烃部分和至少一种芳族二酰氯在界面条件下反应得到羟基封端的聚酯中间体。二羟基取代的芳族化合物以相对于二酰氯为约10摩尔至约125摩尔％的过量使用。羟基封端的聚酯中间体分子量的增强控制是通过限制存在的水量提供大于30％的最终盐水平来实现的。最终的盐水平是理论值，但容易计算。然后通过与诸如光气的碳酸酯前体反应将羟基封端的聚酯中间体转化成嵌段共聚酯碳酸酯。

4. 发明申请

US20050288406A1 Miscible polyimide blends 有权
标题翻译：可混合的聚酰亚胺共混物
公开(公告)号：US20050288406A1
公开(公告)日：2005-12-29
申请号：US10878954
申请日：2004-06-28
申请人： Robert Gallucci , Mark Sanner , Paul Sybert
发明人： Robert Gallucci , Mark Sanner , Paul Sybert
IPC分类号： C08K5/00 , C08K5/5313 , C08K5/5333 , C08L67/02 , C08L67/03 , C08L69/00 , C08L79/08 , C08K5/49
CPC分类号： C08L69/005 , C08K5/0066 , C08K5/5313 , C08K5/5333 , C08L67/02 , C08L67/03 , C08L79/08 , C08L2666/20 , C08L2666/18
摘要： Compositions made from a polyarylate or polyester carbonate containing greater than about 50 mole % resorcinol based ester linkages give miscible blends with polyimide resins. The blends of polyimides and resorcinol based polyesters or resorcinol based polyester carbonates also give miscible blends when combined with other aryl alky polyester resins.
摘要翻译：由含有大于约50摩尔％间苯二酚基酯键的多芳基化合物或聚酯碳酸酯制成的组合物可与聚酰亚胺树脂混合。当与其他芳基烷基聚酯树脂结合时，聚酰亚胺和间苯二酚基聚酯或间苯二酚基聚酯碳酸酯的共混物也提供可混溶的共混物。

5. 发明申请

US20070122627A1 WEATHERABLE, THERMOSTABLE POLYMERS HAVING IMPROVED FLOW COMPOSITION 有权
标题翻译：具有改进流动性组合物的耐热可聚合聚合物
公开(公告)号：US20070122627A1
公开(公告)日：2007-05-31
申请号：US11627828
申请日：2007-01-26
申请人： Gary Davis , Brian Mullen , Paul Sybert
发明人： Gary Davis , Brian Mullen , Paul Sybert
IPC分类号： B32B27/36 , C08F20/00
CPC分类号： B32B27/365 , B32B27/06 , B32B27/08 , B32B27/20 , B32B27/283 , B32B27/36 , B32B2307/584 , B32B2307/71 , B32B2307/712 , B32B2419/00 , B32B2605/00 , C08F293/00 , C08G63/19 , C08G63/64 , C08G63/676 , C08G63/6956 , C08G63/79 , C08J7/047 , C08J2467/00 , C08J2469/00 , C08L53/00 , C08L2666/02 , C09D153/00 , C09D167/03 , C09J153/00 , F02B61/045 , Y10T428/31504 , Y10T428/31507
摘要： A copolymer composition comprises an arylate polyester unit, an aromatic carbonate unit, and a soft-block moiety, wherein individual occurrences of the soft block moiety are linked by a spacer unit comprising one or more of the arylate polyester units, one or more of the aromatic carbonate units, or a combination comprising each of these. In one embodiment, a soft block moiety comprises a polysiloxane unit. A film of the composition has a percent transmittance of greater than or equal to 60% as determined according to ASTM D1003-00. A method of forming a copolymer composition is disclosed, comprising substantially forming the bis-haloformates of a dihydroxy compound comprising an arylate polyester unit, and a dihydroxy compound comprising a soft-block moiety, and reacting the bis haloformates with a dihydroxy aromatic compound. In an embodiment, a multilayer article comprises the thermostable, weatherable polymer.
摘要翻译：共聚物组合物包含芳基化聚酯单元，芳族碳酸酯单元和软嵌段部分，其中软嵌段部分的单独出现由包含一个或多个芳基化聚酯单元的间隔单元连接，一个或多个芳族碳酸酯单元，或包含这些中的每一个的组合。在一个实施方案中，软嵌段部分包含聚硅氧烷单元。根据ASTM D1003-00测定，该组合物的透光率百分比大于或等于60％。公开了一种形成共聚物组合物的方法，其包括基本上形成包含芳基化聚酯单元的二羟基化合物的双卤代甲酸酯和包含软嵌段部分的二羟基化合物，并使双卤代甲酸酯与二羟基芳族化合物反应。在一个实施方案中，多层制品包含耐热耐候性聚合物。

6. 发明申请

US20070027271A1 WEATHERABLE, THERMOSTABLE POLYMERS HAVING IMPROVED FLOW COMPOSITION 有权
标题翻译：具有改进流动性组合物的耐热可聚合聚合物
公开(公告)号：US20070027271A1
公开(公告)日：2007-02-01
申请号：US11426680
申请日：2006-06-27
申请人： Gary Davis , Brian Mullen , Paul Sybert
发明人： Gary Davis , Brian Mullen , Paul Sybert
IPC分类号： C08L83/10 , C08L83/14
CPC分类号： C08G64/186 , C08G63/64 , C08G63/6956 , C08G77/448 , C08L69/00 , C08L83/10 , C08L2666/02
摘要： A copolymer composition comprises a polysiloxane block of Formula XIX or XXII, having 4 to 50 siloxane units, and a polyarylate-polycarbonate block consisting essentially of 50 to 99 mol % arylate polyester units and 1 to 50 mol % aromatic carbonate units, wherein 1 to 30 mole percent of the aromatic carbonate units are resorcinol carbonates, and 0 to 35 mol % of the aromatic carbonate units are bisphenol carbonates; wherein the sum of mole percentages of arylate polyester units, and aromatic carbonate units is 100 mol %; the polysiloxane blocks connect to an arylate ester unit, and/or an aromatic carbonate unit; the siloxane units of the polysiloxane block are present at 0.2 to 10 wt % based on weight of the copolymer composition; and a molded article of 3.2±0.12 millimeters thickness and consisting of the copolymer composition has a percent transmittance greater than or equal to 70%, according to ASTM D1003-00.
摘要翻译：共聚物组合物包含具有4至50个硅氧烷单元的式XIX或XXII的聚硅氧烷嵌段和基本上由50至99mol％芳基化聚酯单元和1至50mol％芳族碳酸酯单元组成的聚芳酯 - 聚碳酸酯嵌段，其中1至 30摩尔％的芳族碳酸酯单元是间苯二酚碳酸酯，0-35摩尔％的芳族碳酸酯单元是双酚碳酸酯; 其中芳基化聚酯单元和芳族碳酸酯单元的摩尔百分比之和为100摩尔％。聚硅氧烷嵌段连接到芳基酯单元和/或芳族碳酸酯单元; 聚硅氧烷嵌段的硅氧烷单元以基于共聚物组合物的重量计为0.2-10重量％存在; 并且根据ASTM D1003-00，由共聚物组合物组成的3.2±0.12毫米厚的模制品具有百分比透射率大于或等于70％。

7. 发明申请

US20060264582A1 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US20060264582A1
公开(公告)日：2006-11-23
申请号：US11267743
申请日：2005-11-04
申请人： Brian Mullen , Paul Sybert
发明人： Brian Mullen , Paul Sybert
IPC分类号： C08F20/00
CPC分类号： C08G63/64 , C08L69/005 , C08L2666/18 , C08L69/00
摘要： A reaction product comprises a polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, and a transesterification catalyst. The reaction product has a haze of less than 5.0%, specifically less than 3.5% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
摘要翻译：反应产物包括包含聚酯单元和聚碳酸酯单元的聚酯 - 聚碳酸酯和酯交换催化剂。根据ASTM D1003-00，反射产物的雾度小于5.0％，特别是小于3.5％，其厚度为3.2mm。公开了一种包含反应产物和由其形成的制品的热塑性组合物。还公开了形成反应产物的方法。

8. 发明授权

US08057903B2 Multilayer articles comprising resorcinol arylate polyester and method for making thereof 有权
标题翻译：包括间苯二酚芳基化聚酯的多层制品及其制备方法
公开(公告)号：US08057903B2
公开(公告)日：2011-11-15
申请号：US10210746
申请日：2002-07-31
申请人： Himanshu Asthana , Safwat Tadros , Paul Sybert , Christopher L. Hein , Edward Kung , David Rosendale , Xiangyang Li , Luca Saggese , Erich O. Teutsch , Glen Tryson , Hua Wang , Hongyi Zhou , Chris Hartshorn , Axel Grimm , Theodorus J. M. Timmerman , Jeroen Vervoort , Hendrik Cornelus Jacobus De Nooijer , Gert Boven , Beth Brister , Enamul Haque
发明人： Himanshu Asthana , Safwat Tadros , Paul Sybert , Christopher L. Hein , Edward Kung , David Rosendale , Xiangyang Li , Luca Saggese , Erich O. Teutsch , Glen Tryson , Hua Wang , Hongyi Zhou , Chris Hartshorn , Axel Grimm , Theodorus J. M. Timmerman , Jeroen Vervoort , Hendrik Cornelus Jacobus De Nooijer , Gert Boven , Beth Brister , Enamul Haque
IPC分类号： B32B27/00
CPC分类号： B32B27/36 , B29C45/14811 , B29C47/0021 , B29C47/0054 , B29C47/065 , B29C47/145 , B29C47/56 , B29C51/002 , B29C51/02 , B29C51/082 , B29C2791/001 , B29K2033/04 , B29K2633/08 , B29K2705/00 , B29K2713/00 , B29K2995/0055 , B29K2995/0058 , B29L2031/30 , B29L2031/3008 , B32B27/06 , B32B37/153 , B32B38/0008 , B32B38/12 , B32B2038/0016 , B32B2310/0445 , B32B2310/14 , B32B2605/08 , Y10T428/24942 , Y10T428/31507 , Y10T428/31565 , Y10T428/3158 , Y10T428/31587 , Y10T428/31681 , Y10T428/31786
摘要： Multilayer articles comprising a coating layer comprising resorcinol arylate chain members bound to a support substrate via an optional intermediate tie layer. Adhesion between the layers of the multilayer article is enhanced by modifying at least a part of a surface of at least one of the layers in the multilayer article by a technique selected from at least one of: surface adhesive treatment, surface corona treatment, flame treatment, plasma surface treatment, vacuum deposition treatment, ionization radiation, chemical surface treatment, surface abrasion treatment, and surface texturing treating.
摘要翻译：包含包含间苯二酚芳基化物链成员的涂层的多层制品通过任选的中间粘结层结合到支撑基底上。通过选自以下技术中的一种技术来修饰多层制品中的至少一层的至少一部分表面的至少一部分来增强多层制品的层之间的粘附：表面粘合剂处理，表面电晕处理，火焰处理，等离子体表面处理，真空沉积处理，电离辐射，化学表面处理，表面磨损处理和表面纹理处理。

9. 发明申请

US20070027268A1 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US20070027268A1
公开(公告)日：2007-02-01
申请号：US11263516
申请日：2005-10-31
申请人： Jianbo Di , Brian Mullen , Paul Sybert
发明人： Jianbo Di , Brian Mullen , Paul Sybert
IPC分类号： C08F20/00
CPC分类号： C08G64/42 , C08G63/64 , C08L69/005 , C08L2666/18 , C08L69/00
摘要： A reaction product comprises a first polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a second polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, and a transesterification catalyst. The reaction product has a haze of less than 1.7%, specifically less than 1.0% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
摘要翻译：反应产物包括包含聚酯单元和聚碳酸酯单元的第一聚酯 - 聚碳酸酯，包含聚酯单元和聚碳酸酯单元的第二聚酯 - 聚碳酸酯和酯交换催化剂。根据ASTM D1003-00，反射产物的雾度小于1.7％，特别是小于1.0％，其厚度为3.2mm。公开了一种包含反应产物和由其形成的制品的热塑性组合物。还公开了形成反应产物的方法。

10. 发明申请

US20060264581A1 Transparent compositions, methods for the preparation thereof, and articles derived therefrom 有权
标题翻译：透明组合物，其制备方法和由其衍生的制品
公开(公告)号：US20060264581A1
公开(公告)日：2006-11-23
申请号：US11263515
申请日：2005-10-31
申请人： Gordon Berkstresser , Brian Mullen , Paul Sybert
发明人： Gordon Berkstresser , Brian Mullen , Paul Sybert
IPC分类号： C08F20/00
CPC分类号： C08L69/005 , C08G63/19 , C08G63/64 , C08G63/82 , C08L69/00 , C08L2666/18
摘要： A reaction product comprises a polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a polycarbonate polymer, and a transesterification catalyst, wherein the polyester-polycarbonate comprises greater than or equal to 75 mole % aromatic ester units, and less than 25 mole % carbonate units. The reaction product has a haze of less than 1.7%, specifically less than 1.0% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
摘要翻译：反应产物包括聚酯 - 聚碳酸酯，其包含聚酯单元和聚碳酸酯单元，聚碳酸酯聚合物和酯交换催化剂，其中聚酯 - 聚碳酸酯包含大于或等于75摩尔％的芳族酯单元和小于25摩尔％碳酸盐单位。根据ASTM D1003-00，反射产物的雾度小于1.7％，特别是小于1.0％，其厚度为3.2mm。公开了一种包含反应产物和由其形成的制品的热塑性组合物。还公开了形成反应产物的方法。

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