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1. 发明申请

US20060147699A1 Protective ceramic coating 审中-公开
标题翻译：保护陶瓷涂层
公开(公告)号：US20060147699A1
公开(公告)日：2006-07-06
申请号：US10528752
申请日：2003-10-03
申请人： Partho Sarkar , Lorne Johanson , Florin Esanu
发明人： Partho Sarkar , Lorne Johanson , Florin Esanu
IPC分类号： B32B5/16
CPC分类号： C03C17/42 , C03C3/064 , C03C14/004 , C03C17/007 , C03C2214/04 , C03C2214/08 , C03C2214/32 , C03C2217/452 , C03C2217/475 , C03C2218/111 , C03C2218/112 , C03C2218/113 , C03C2218/116 , C04B35/119 , C04B35/6263 , C04B35/6264 , C04B35/634 , C04B2235/3244 , C04B2235/3418 , C04B2235/36 , C04B2235/3821 , C04B2235/402 , C04B2235/441 , C04B2235/5436 , C23C18/02 , C23C18/04 , C23C18/1208 , C23C18/1254 , C23C18/1295 , Y10T428/25
摘要： This invention relates to a composite coating for protection of metal, glass and ceramic substrates and a method of producing same. The coating process consists of: depositing a ceramic porous coating made of a ceramic filler and a binding phase consisting of a finely divided glass and a ceramic sol; sintering the coating by a heat treatment up to 700° C.; and, optionally sealing the porous ceramic coating with an inorganic sealant or an organic sealant, or a combination thereof.
摘要翻译：本发明涉及一种用于保护金属，玻璃和陶瓷基片的复合涂层及其制造方法。涂覆方法包括：沉积由陶瓷填料制成的陶瓷多孔涂层和由细碎玻璃和陶瓷溶胶组成的结合相; 通过高达700℃的热处理烧结涂层; 并且可选地用无机密封剂或有机密封剂或其组合密封多孔陶瓷涂层。

2. 发明授权

US06936367B2 Solid oxide fuel cell system 有权
标题翻译：固体氧化物燃料电池系统
公开(公告)号：US06936367B2
公开(公告)日：2005-08-30
申请号：US10156755
申请日：2002-05-23
申请人： Partho Sarkar , Lorne Johanson , Hongsang Rho
发明人： Partho Sarkar , Lorne Johanson , Hongsang Rho
IPC分类号： H01M4/86 , C04B38/06 , C25D1/14 , C25D13/02 , C25D13/14 , H01M20060101 , H01M2/02 , H01M4/02 , H01M4/88 , H01M8/00 , H01M8/02 , H01M8/04 , H01M8/06 , H01M8/10 , H01M8/12 , H01M8/24
CPC分类号： H01M8/02 , C04B38/06 , C25D1/14 , C25D13/02 , C25D13/14 , H01M8/004 , H01M8/0232 , H01M8/0236 , H01M8/0252 , H01M8/06 , H01M8/0612 , H01M8/12 , H01M8/1213 , H01M8/1226 , H01M8/1286 , H01M8/243 , H01M8/2475 , H01M8/2485
摘要： This invention relates to a fuel cell system comprising a fuel cell stack, external circuit electrical leads coupled to the fuel cell electrodes, and a thermal enclosure assembly enclosing the stack. The stack includes a plurality of inner tubular solid oxide fuel cells, the inside of the inner fuel cells being fluidly couplable to a first reactant source, and a porous support matrix embedding the inner fuel cells and being fluidly couplable to a second reactant source such that a second reactant is flowable through the matrix and to the outer surface of the embedded fuel cells. The stack may also include an outer tubular solid oxide fuel cell surrounding the matrix and the inner fuel cells such that the second reactant is flowable through the matrix and to an inside surface of the outer fuel cell and wherein the outer surface of the outer fuel cell is fluidly couplable to a first reactant source.
摘要翻译：本发明涉及一种燃料电池系统，其包括燃料电池堆，耦合到燃料电池电极的外部电路电线以及围绕该堆叠的热封闭组件。所述堆叠包括多个内部管状固体氧化物燃料电池，所述内部燃料电池的内部可流体耦合到第一反应物源，以及多孔载体矩阵，其嵌入所述内部燃料电池并且可流体耦合到第二反应物源，使得第二反应物可流过基质并且流过嵌入式燃料电池的外表面。堆叠还可以包括围绕基体和内部燃料电池的外部管状固体氧化物燃料电池，使得第二反应物可以通过基体流动并流到外部燃料电池的内表面，并且其中外部燃料电池的外表面与第一反应物源流体耦合。

3. 发明授权

US07736772B2 Tubular solid oxide fuel cell stack 有权
标题翻译：管状固体氧化物燃料电池堆
公开(公告)号：US07736772B2
公开(公告)日：2010-06-15
申请号：US10504624
申请日：2003-02-14
申请人： Partho Sarkar , Hongsang Rho
发明人： Partho Sarkar , Hongsang Rho
IPC分类号： H01M8/00 , H01M8/10 , H01M2/00 , H01M2/14 , H01M4/00 , B28B1/00 , B01D53/22
CPC分类号： B01D53/228 , C01B3/505 , C01B2203/041 , C02F1/32 , C02F1/725 , C02F2305/10 , H01M4/8621 , H01M8/0228 , H01M8/1213 , H01M8/124 , H01M8/2404 , H01M8/243 , H01M8/249 , Y02P70/56
摘要： This invention relates to a stack comprising a continuous solid-phase matrix and tubular fuel cells embedded in the matrix. Each fuel cell comprises an inner electrode layer, an outer electrode layer, and an electrolyte layer sandwiched between the inner and outer electrode layers. The matrix is sufficiently porous to allow a first reactant to flow through the matrix and to the outer electrode of each fuel cell, and have sufficient mechanical strength to support the fuel cells in the stack. The fuel cells are embedded such that a second reactant may be flowed through the inside of each tubular fuel cell and to the inner electrode thereof. Alternatively, a stack of tubular separation membranes or a stack of tubular membrane reactors may be embedded in the matrix. The matrix material may comprise solid state foam, metal filament, or metal, cermet, or ceramic wool.
摘要翻译：本发明涉及一种包括连续固相基体和嵌入基质中的管状燃料电池的叠层体。每个燃料电池包括内电极层，外电极层和夹在内电极层和外电极层之间的电解质层。该基质足够多孔以允许第一反应物流过每个燃料电池的基体和外电极，并且具有足够的机械强度来支撑堆叠中的燃料电池。燃料电池被嵌入，使得第二反应物可以流过每个管状燃料电池的内部并流过其内部电极。或者，可以将一叠管状分离膜或一组管状膜反应器嵌入基质中。基质材料可以包括固态泡沫，金属丝或金属，金属陶瓷或陶瓷棉。

4. 发明申请

US20060127725A9 Solid oxide fuel cell system 有权
标题翻译：固体氧化物燃料电池系统
公开(公告)号：US20060127725A9
公开(公告)日：2006-06-15
申请号：US10997787
申请日：2004-11-23
申请人： Partho Sarkar , Hongsang Rho , Lorne Johanson
发明人： Partho Sarkar , Hongsang Rho , Lorne Johanson
IPC分类号： H01M8/12 , H01M8/02 , H01M8/06
CPC分类号： H01M8/02 , C04B38/06 , C25D1/14 , C25D13/02 , C25D13/14 , H01M8/004 , H01M8/0232 , H01M8/0236 , H01M8/0252 , H01M8/06 , H01M8/0612 , H01M8/12 , H01M8/1213 , H01M8/1226 , H01M8/1286 , H01M8/243 , H01M8/2475 , H01M8/2485
摘要： This invention relates to a fuel cell system comprising an outer tubular solid oxide fuel cell, a solid phase porous matrix located inside the outer fuel cell and attached to its inner electrode layer, and at least one inner tubular solid oxide fuel cell embedded in the matrix. The outer fuel cell has an inner electrode layer configured to receive a first reactant fluid, an outer electrode layer configured to receive a second reactant fluid, and an electrolyte layer sandwiched between the electrode layers. The inner fuel cell has an outer electrode layer configured to receive the first reactant fluid, an inner electrode layer configured to receive the second reactant fluid, and an electrolyte layer sandwiched between the inner and outer electrode layers. The matrix has sufficient mechanical strength to support the inner fuel cell and sufficient porosity to enable the first reactant fluid to flow through the matrix to the inner and outer fuel cell respectively.
摘要翻译：本发明涉及一种燃料电池系统，其包括外部管状固体氧化物燃料电池，位于外部燃料电池内部并附接到其内部电极层的固相多孔基体，以及嵌入基体中的至少一个内部管状固体氧化物燃料电池。外部燃料电池具有构造成接收第一反应物流体的内部电极层，被配置为接收第二反应物流体的外部电极层和夹在电极层之间的电解质层。内部燃料电池具有构造成容纳第一反应物流体的外部电极层，被配置为容纳第二反应物流体的内部电极层和夹在内部和外部电极层之间的电解质层。该基体具有足够的机械强度来支撑内部燃料电池和足够的孔隙率以使第一反应物流体能够分别通过基体流到内燃料电池和外燃料电池。

5. 发明申请

US20050214613A1 Tubular solid oxide fuel cell stack 有权
标题翻译：管状固体氧化物燃料电池堆
公开(公告)号：US20050214613A1
公开(公告)日：2005-09-29
申请号：US10504624
申请日：2003-02-14
申请人： Partho Sarkar , Hongsang Rho
发明人： Partho Sarkar , Hongsang Rho
IPC分类号： B01D53/22 , B05D5/12 , C01B3/50 , C02F1/30 , C02F1/32 , C02F1/72 , H01M4/86 , H01M8/02 , H01M8/10 , H01M8/12 , H01M8/24
CPC分类号： B01D53/228 , C01B3/505 , C01B2203/041 , C02F1/32 , C02F1/725 , C02F2305/10 , H01M4/8621 , H01M8/0228 , H01M8/1213 , H01M8/124 , H01M8/2404 , H01M8/243 , H01M8/249 , Y02P70/56
摘要： This invention relates to a stack comprising a continuous solid-phase matrix and tubular fuel cells embedded in the matrix. Each fuel cell comprises an inner electrode layer, an outer electrode layer, and an electrolyte layer sandwiched between the inner and outer electrode layers. The matrix is sufficiently porous to allow a first reactant to flow through the matrix and to the outer electrode of each fuel cell, and have sufficient mechanical strength to support the fuel cells in the stack. The fuel cells are embedded such that a second reactant may be flowed through the inside of each tubular fuel cell and to the inner electrode thereof. Alternatively, a stack of tubular separation membranes or a stack of tubular membrane reactors may be embedded in the matrix. The matrix material may comprise solid state foam, metal filament, or metal, cermet, or ceramic wool.
摘要翻译：本发明涉及一种包括连续固相基体和嵌入基质中的管状燃料电池的叠层体。每个燃料电池包括内电极层，外电极层和夹在内电极层和外电极层之间的电解质层。该基质足够多孔以允许第一反应物流过每个燃料电池的基体和外电极，并且具有足够的机械强度来支撑堆叠中的燃料电池。燃料电池被嵌入，使得第二反应物可以流过每个管状燃料电池的内部并流过其内部电极。或者，可以将一叠管状分离膜或一组管状膜反应器嵌入基质中。基质材料可以包括固态泡沫，金属丝或金属，金属陶瓷或陶瓷棉。

6. 发明授权

US08241771B2 Compact solid oxide fuel cell stack 失效
标题翻译：紧凑型固体氧化物燃料电池堆
公开(公告)号：US08241771B2
公开(公告)日：2012-08-14
申请号：US10539831
申请日：2003-12-17
申请人： Partho Sarkar , Lorne Johanson , Hongsang Rho
发明人： Partho Sarkar , Lorne Johanson , Hongsang Rho
IPC分类号： H01M8/12
CPC分类号： H01M8/04007 , H01M4/8885 , H01M8/0232 , H01M8/0254 , H01M8/1231 , H01M8/2404 , H01M8/2428 , H01M8/243
摘要： This invention relates to a solid oxide fuel cell stack comprising a plurality of tubular solid oxide fuel cells each comprising concentric inner and outer electrode layers sandwiching a concentric electrolyte layer. The fuel cells extend in the same direction and are arranged in a cluster with at least one fuel cell having an electrolyte layer with a different composition and different maximum operating temperature than another fuel cell in the cluster. The fuel cell having the electrolyte layer with a higher maximum operating temperature is located closer to the core of the cluster than the fuel cell having the electrolyte layer with a lower maximum operating temperature.
摘要翻译：本发明涉及一种固体氧化物燃料电池堆，其包括多个管状固体氧化物燃料电池，每个管状固体氧化物燃料电池均包含夹持同心电解质层的同心内部和外部电极层。燃料电池在相同的方向上延伸并且布置成具有至少一个燃料电池的集群中，所述燃料电池具有与组中的另一个燃料电池不同的组成和不同的最大工作温度的电解质层。具有较高最高工作温度的电解质层的燃料电池比具有较低最高工作温度的电解质层的燃料电池更靠近集束芯。

7. 发明授权

US07732076B2 Heating solid oxide for fuel cell stack 有权
标题翻译：加热燃料电池堆的固体氧化物
公开(公告)号：US07732076B2
公开(公告)日：2010-06-08
申请号：US10597939
申请日：2005-02-11
申请人： Rong Zheng , Gary Kovacik , Hongsang Rho , Partho Sarkar , Luis Yamarte , Mark L. Richardson
发明人： Rong Zheng , Gary Kovacik , Hongsang Rho , Partho Sarkar , Luis Yamarte , Mark L. Richardson
IPC分类号： H01M8/10 , H01M8/04
CPC分类号： H01M8/04022 , H01M8/1231 , H01M8/243 , H01M8/2457
摘要： This invention relates to a solid oxide fuel cell system comprising at least one longitudinally extending tubular solid oxide fuel cell and a longitudinally extending heater mounted in thermal proximity to the fuel cell to provide heat to the fuel cell during start up and during operation as needed. The heater and fuel cell can be encased within a tubular thermal casing; the inside of the casing defines a first reactant chamber for containing a first reactant, such as oxidant. The fuel cell comprises a ceramic solid state electrolyte layer and inner and outer electrode layers concentrically arranged around and sandwiching the electrolyte layer. The outer electrode layer is fluidly communicable with the first reactant, and the inner electrode layer is fluidly isolated from the first reactant and fluidly communicable with a second reactant, such as fuel.
摘要翻译：本发明涉及一种固体氧化物燃料电池系统，其包括至少一个纵向延伸的管状固体氧化物燃料电池和纵向延伸的加热器，其安装在燃料电池附近，以在启动期间和在运行期间根据需要向燃料电池提供热量。加热器和燃料电池可以封装在管状热套管内; 壳体的内部限定了用于容纳第一反应物（例如氧化剂）的第一反应物室。燃料电池包括陶瓷固态电解质层和同心地布置在电解质层周围并夹着电解质层的内外电极层。外部电极层可与第一反应物流体连通，并且内部电极层与第一反应物流体隔离并且可与第二反应物（例如燃料）流体连通。

8. 发明申请

US20070243444A1 Heating Solid Oxide for Fuel Cell Stack 有权
标题翻译：燃料电池堆的加热固体氧化物
公开(公告)号：US20070243444A1
公开(公告)日：2007-10-18
申请号：US10597939
申请日：2005-02-11
申请人： Rong Zheng , Gary Kovacik , Hongsang Rho , Partho Sarkar , Luis Yamarte , Mark Richardson
发明人： Rong Zheng , Gary Kovacik , Hongsang Rho , Partho Sarkar , Luis Yamarte , Mark Richardson
IPC分类号： H01M8/10
CPC分类号： H01M8/04022 , H01M8/1231 , H01M8/243 , H01M8/2457
摘要： This invention relates to a solid oxide fuel cell system comprising at least one longitudinally extending tubular solid oxide fuel cell and a longitudinally extending heater mounted in thermal proximity to the fuel cell to provide heat to the fuel cell during start up and during operation as needed. The heater and fuel cell can be encased within a tubular thermal casing; the inside of the casing defines a first reactant chamber for containing a first reactant, such as oxidant. The fuel cell comprises a ceramic solid state electrolyte layer and inner and outer electrode layers concentrically arranged around and sandwiching the electrolyte layer. The outer electrode layer is fluidly communicable with the first reactant, and the inner electrode layer is fluidly isolated from the first reactant and fluidly communicable with a second reactant, such as fuel.
摘要翻译：本发明涉及一种固体氧化物燃料电池系统，其包括至少一个纵向延伸的管状固体氧化物燃料电池和纵向延伸的加热器，其安装在燃料电池附近，以在启动期间和在运行期间根据需要向燃料电池提供热量。加热器和燃料电池可以封装在管状热套管内; 壳体的内部限定了用于容纳第一反应物（例如氧化剂）的第一反应物室。燃料电池包括陶瓷固态电解质层和同心地布置在电解质层周围并夹着电解质层的内外电极层。外部电极层可与第一反应物流体连通，并且内部电极层与第一反应物流体隔离并且可与第二反应物（例如燃料）流体连通。

9. 发明授权

US07235321B2 Solid oxide fuel cell system 有权
标题翻译：固体氧化物燃料电池系统
公开(公告)号：US07235321B2
公开(公告)日：2007-06-26
申请号：US10997787
申请日：2004-11-23
申请人： Partho Sarkar , Hongsang Rho , Lorne Johanson
发明人： Partho Sarkar , Hongsang Rho , Lorne Johanson
IPC分类号： H01M8/12 , H01M8/06 , H01M8/24
CPC分类号： H01M8/02 , C04B38/06 , C25D1/14 , C25D13/02 , C25D13/14 , H01M8/004 , H01M8/0232 , H01M8/0236 , H01M8/0252 , H01M8/06 , H01M8/0612 , H01M8/12 , H01M8/1213 , H01M8/1226 , H01M8/1286 , H01M8/243 , H01M8/2475 , H01M8/2485
摘要： This invention relates to a fuel cell system comprising an outer tubular solid oxide fuel cell, a solid phase porous matrix located inside the outer fuel cell and attached to its inner electrode layer, and at least one inner tubular solid oxide fuel cell embedded in the matrix. The outer fuel cell has an inner electrode layer configured to receive a first reactant fluid, an outer electrode layer configured to receive a second reactant fluid, and an electrolyte layer sandwiched between the electrode layers. The inner fuel cell has an outer electrode layer configured to receive the first reactant fluid, an inner electrode layer configured to receive the second reactant fluid, and an electrolyte layer sandwiched between the inner and outer electrode layers. The matrix has sufficient mechanical strength to support the inner fuel cell and sufficient porosity to enable the first reactant fluid to flow through the matrix to the inner and outer fuel cell respectively.
摘要翻译：本发明涉及一种燃料电池系统，其包括外部管状固体氧化物燃料电池，位于外部燃料电池内部并附接到其内部电极层的固相多孔基体，以及嵌入基体中的至少一个内部管状固体氧化物燃料电池。外部燃料电池具有构造成接收第一反应物流体的内部电极层，被配置为接收第二反应物流体的外部电极层和夹在电极层之间的电解质层。内部燃料电池具有构造成容纳第一反应物流体的外部电极层，被配置为容纳第二反应物流体的内部电极层和夹在内部和外部电极层之间的电解质层。该基体具有足够的机械强度来支撑内部燃料电池和足够的孔隙率以使第一反应物流体能够分别通过基体流到内燃料电池和外燃料电池。

10. 发明授权

US07452622B2 Metal-supported tubular fuel cell 有权
标题翻译：金属支撑的管状燃料电池
公开(公告)号：US07452622B2
公开(公告)日：2008-11-18
申请号：US10522235
申请日：2003-07-24
申请人： Partho Sarkar , Hongsang Rho , Lorne Johanson , Luis Yamarte
发明人： Partho Sarkar , Hongsang Rho , Lorne Johanson , Luis Yamarte
IPC分类号： H01M8/12 , B05D5/12
CPC分类号： H01M8/1213 , C04B38/06 , C25D1/14 , C25D13/02 , C25D13/14 , H01M4/8621 , H01M4/8885 , H01M4/9066 , H01M8/0252 , H01M8/0289 , H01M8/0612 , H01M8/1226 , H01M8/1253 , H01M8/126 , H01M8/243 , H01M8/2475 , H01M8/2485 , H01M2008/1293 , Y02E60/525 , Y02P70/56
摘要： This invention relates to a method of manufacturing a metal-supported tubular micro-solid oxide fuel cell, and a fuel cell made from such method. The method comprises the steps of coating a wooden substrate member with a conductive substrate layer, coating the substrate layer with an inner electrode layer, coating the inner electrode layer with an electrolyte layer, drying and sintering the coated substrate member such that the substrate member combusts, coating the electrolyte layer with an outer electrode layer, and then drying and sintering the layers. The invention further relates to a method of manufacturing a tubular solid oxide fuel cell assembly comprising: a) coating a tubular substantially metallic support layer with a ceramic or cermet inner electrode layer, b) coating the inner electrode layer with a ceramic electrolyte layer; c) coating the electrolyte layer with a ceramic or cermet outer electrode layer, then d) sintering the layers to produce a hollow tubular metal-supported fuel cell; the electrode and electrolyte layers having a collective wall thickness of 80 μm or less, the support layer having sufficient mechanical strength to support the electrode and electrolyte layers and sufficient porosity to flow a reactant therethrough.
摘要翻译：本发明涉及一种制造金属支撑的管状微固体氧化物燃料电池的方法和由这种方法制成的燃料电池。该方法包括以下步骤：用导电基底层涂覆木制基底部件，用内部电极层涂覆基底层，用电解质层涂覆内部电极层，干燥并烧结涂覆的基底部件，使得基底部件燃烧，用外电极层涂覆电解质层，然后干燥和烧结层。本发明还涉及一种制造管状固体氧化物燃料电池组件的方法，包括：a）用陶瓷或金属陶瓷内部电极层涂覆管状的基本上金属的支撑层，b）用陶瓷电解质层涂覆内部电极层; c）用陶瓷或金属陶瓷外电极层涂覆电解质层，然后d）烧结层以产生中空的管状金属载体燃料电池; 电极和电解质层具有80μm或更小的集体壁厚，支撑层具有足够的机械强度以支撑电极和电解质层，并且足够的孔隙率使反应物流过其中。

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