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    • 1. 发明授权
    • Process for the purification of mixtures of toluenediisocyanate
    • 纯化甲苯二异氰酸酯混合物的方法
    • US06803483B2
    • 2004-10-12
    • US10457105
    • 2003-06-09
    • Heinrich LokumOve NommensenHermann DallmeyerWilhelm Hagen
    • Heinrich LokumOve NommensenHermann DallmeyerWilhelm Hagen
    • C07C26300
    • C07C263/20C07C265/14
    • A process for the purification of toluenediisocyanate by fractionating a crude distillation feed containing toluenediisocyante, an organic solvent and less than 2% by weight of phosgene in a heat integrated system having an upstream distillation column, an interchanger and a downstream distillation column which are connected in series. The vapor which is recovered from the upstream distillation column is used to reboil the bottoms product of the downstream distillation column or the feed to the downstream distillation column in the interchanger. The crude distillation feed comprising less than 2% by weight of phosgene is fractionated into three product fractions P1-P3 and optionally a fourth fraction P4. P1 is a noncondensible gas stream enriched with phosgene and/or low-boilers. P2 is a solvent-enriched product. P3 is a high boiler enriched bottoms product comprising toluenediisocyanate, and P4 is a toluenediisocyanate enriched stream lean in highboilers and reaction residues.
    • 一种通过在含有甲苯二异氰酸酯,有机溶剂和小于2重量%的光气的粗蒸馏进料在具有上游蒸馏塔,交换器和下游蒸馏塔的热集成系统中分级来净化甲苯二异氰酸酯的方法,所述上游蒸馏塔, 系列。 从上游蒸馏塔回收的蒸气用于将下游蒸馏塔的塔底产物或交换器中的下游蒸馏塔的进料再沸腾。 包含小于2重量%的光气的原油蒸馏进料分馏成三个产物馏分P1-P3和任选的第四馏分P4。 P1是富含光气和/或低锅炉的不可冷凝气流。 P2是富溶剂的产品。 P3是含有甲苯二异氰酸酯的高锅炉富集底部产物,P4是富含甲苯二异氰酸酯的富含高沸物和反应残余物的料流。