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1. 发明专利

CA2012948C AQUEOUS COATING COMPOSITIONS 未知
公开(公告)号：CA2012948C
公开(公告)日：2001-05-15
申请号：CA2012948
申请日：1990-03-23
申请人： SMAK YVONNE WILHELMINA , HEUTS MARTINUS PETRUS JOSEPH , CAREY JOHN GERARD , OVERBEEK GERARDUS CORNELIS
发明人： SMAK YVONNE WILHELMINA , HEUTS MARTINUS PETRUS JOSEPH , CAREY JOHN GERARD , OVERBEEK GERARDUS CORNELIS
IPC分类号： C08G18/08 , C08G18/12 , C08G18/83 , C09D5/00 , C09D5/02 , C09D123/02 , C09D133/02 , C09D175/00 , C09D175/04 , C09D201/02 , C09D157/00
摘要： An aqueous selfcrosslinkable coating composition which comprises an aqueous dispersion of at least one polymer having chain-pendant amine groups and certain selected non-polymeric ketone-containing compounds, particularly acetoacetates and acetoacetamides, whereby selfcrosslinking is effected, often at ambient or low temperatures, during and/or after film formation.

2. 发明专利

CA1341075C AQUEOUS DISPERSIONS 未知
公开(公告)号：CA1341075C
公开(公告)日：2000-08-08
申请号：CA577413
申请日：1988-09-14
申请人： GOOS HENDRICUS CORNELIS , OVERBEEK GERARDUS CORNELIS
发明人： GOOS HENDRICUS CORNELIS , OVERBEEK GERARDUS CORNELIS
IPC分类号： C08G18/63 , C08F2/16 , C08F2/44 , C08F283/00 , C08G18/00 , C08G18/08 , C08L75/00 , C08L75/04 , C09D175/00 , C09D175/04 , C09J175/00 , C09J175/04 , B32B7/12
摘要： A surfactant-free aqueous polymer dispersion containing an anionic water-dispersible polyurethane and a vinyl polymer in a weight ratio of from 10:90 to 90:10, said dispersion having been obtained by: (A) forming a solution of an anionic water-dispersible isocyanale-terminated polyurethane in at least one vinyl monomer; (B) dispersing the solution in an aqueous medium; (C) chain extending the polyurethane, and either (D) adding further vinyl monomer, and (E) initiating polymerisation of the vinyl monomer, or (F) initiating polymerisation of the vinyl monomer, and (G) adding further vinyl monomer during polymerisation.

3. 发明申请

WO2012084974A1 BIO-RENEWABLE SEQUENTIAL VINYL POLYMER 审中-公开
标题翻译：生物可再生顺序的乙烯基聚合物
公开(公告)号：WO2012084974A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073440
申请日：2011-12-20
申请人： DSM IP Assets B.V. , OVERBEEK, Gerardus Cornelis , NABUURS, Tijs
发明人： OVERBEEK, Gerardus Cornelis , NABUURS, Tijs
IPC分类号： C08L33/12 , C09D133/12 , C08F265/06
CPC分类号： C09D133/06 , C08F265/06 , C08L33/12 , C08L51/06 , C08L2201/06 , C09D5/02 , C09D11/106 , C09D133/12 , C09D151/06 , C09J151/06 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , C08L2666/04 , C08F2/08
摘要： An aqueous polymer dispersion comprising a vinyl polymer with at least two phases comprising: A) 40 to 90 wt% of a vinyl polymer A having a glass transition temperature in the range of from -50 to 30 °C; and B) 10 to 60 wt% of a vinyl polymer B having a glass transition temperature the range of from 50 to 130 °C; wherein vinyl polymer A comprises 0.1 to 10 wt% of at least one acid-functional olefinically unsaturated monomer, wherein at least 20 wt% of the monomer composition used to form vinyl polymer A and vinyl polymer B is derived from at least one bio-renewable olefinically unsaturated monomer.
摘要翻译：包含具有至少两相的乙烯基聚合物的含水聚合物分散体，其包含：A）40至90重量％的玻璃化转变温度为-50至30℃的乙烯基聚合物A; 和B）10〜60重量％的玻璃化转变温度为50〜130℃的乙烯基聚合物B; 其中乙烯基聚合物A包含0.1至10重量％的至少一种酸官能的烯属不饱和单体，其中用于形成乙烯基聚合物A和乙烯基聚合物B的单体组合物的至少20重量％衍生自至少一种生物可再生的烯属不饱和单体。

4. 发明申请

WO2008155324A1 PROCESS FOR OBTAINING LOW FREE MONOMER LEVELS IN A BLOCK COPOLYMER EMULSION PREPARED WITH (REVERSE) IODINE TRANSFER POLYMERISATION 审中-公开
标题翻译：制备（反向）碘转移聚合的嵌段共聚物乳液中低自由基单体含量的方法
公开(公告)号：WO2008155324A1
公开(公告)日：2008-12-24
申请号：PCT/EP2008/057605
申请日：2008-06-17
申请人： DSM IP Assets B.V. , NABUURS, Tijs , OVERBEEK, Gerardus Cornelis , SCHELLEKENS, Michael Arnoldus Jacobus , VISSER, Danny , VAES, Frank
发明人： NABUURS, Tijs , OVERBEEK, Gerardus Cornelis , SCHELLEKENS, Michael Arnoldus Jacobus , VISSER, Danny , VAES, Frank
IPC分类号： C08F293/00 , C08F2/00 , C08F2/22 , C08L53/00 , C09D153/00 , C09J153/00 , C08F8/00
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005 , C08F2438/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： A process for obtaining an aqueous emulsion comprising a block copolymer by the solution polymerisation of vinyl monomers to obtain block [B] in the presence of a) a radical precursor; and b) an iodine atom containing block [A]; where block [A] and [B] together comprise 0 to 2 wt% of methacrylic acid; where block [A] and block [B] together comprise ≥ 2.5 wt% of vinyl monomers bearing ionic or potentially ionic water-dispersing groups not including methacrylic acid; and performing a post polymerisation reaction on the block copolymer emulsion obtained in step II; and wherein said aqueous emulsion has a free vinyl monomer level
摘要翻译：一种通过乙烯基单体的溶液聚合获得嵌段共聚物以在a）自由基前体存在下获得嵌段[B]的方法; 和b）含有碘原子的嵌段[A]; 其中嵌段[A]和[B]一起包含0至2重量％的甲基丙烯酸; 其中嵌段[A]和嵌段[B]一起包含= 2.5重量％的带有不含甲基丙烯酸的离子或潜在离子水分散基团的乙烯基单体; 并对在步骤II中获得的嵌段共聚物乳液进行后聚合反应; 并且其中当固体含量= 20重量％时，所述水性乳液的游离乙烯基单体含量<1000ppm。

5. 发明申请

WO2008122576A1 AQUEOUS OLIGOMER / POLYMER EMULSION WITH CATIONIC FUNCTIONALITY 审中-公开
标题翻译：具有阳离子功能的水性低聚物/聚合物乳液
公开(公告)号：WO2008122576A1
公开(公告)日：2008-10-16
申请号：PCT/EP2008/054042
申请日：2008-04-03
申请人： DSM IP ASSETS B.V. , SCHELLEKENS, Michael, Arnoldus, Jacobus , GEURTS, John , NABUURS, Tijs , OVERBEEK, Gerardus, Cornelis
发明人： SCHELLEKENS, Michael, Arnoldus, Jacobus , GEURTS, John , NABUURS, Tijs , OVERBEEK, Gerardus, Cornelis
IPC分类号： C08F293/00 , C08F2/38 , C08F2/22 , C08F8/00 , C08L53/00 , C09D153/00
CPC分类号： C09D151/003 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D5/14 , C09D153/00 , C09D153/005 , Y10T428/31855 , Y10T428/31938 , C08L2666/02
摘要： An aqueous emulsion comprising at least a covalently bound vinyl oligomer and vinyl polymer, wherein said vinyl oligomer comprises 5 to 85 mol% of vinyl monomers bearing quaternary ammonium ion functional groups or quaternisable amine functional groups and is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer mechanism in solution in the presence of a control agent and a source of free radicals; wherein said vinyl polymer is obtained by emulsion polymerisation of vinyl monomers in the presence of the vinyl oligomer; wherein the weight % ratio of vinyl oligomer to vinyl polymer is in the range of from 0.5 : 99.5 to 65 : 35.
摘要翻译：包含至少共价结合的乙烯基低聚物和乙烯基聚合物的水性乳液，其中所述乙烯基低聚物包含5-85摩尔％的带有季铵离子官能团或可季铵化胺官能团的乙烯基单体，并且通过至少一种受控自由基聚合获得一种乙烯基单体通过在控制剂和自由基来源的溶液中的可逆加成 - 断裂链转移机理; 其中所述乙烯基聚合物通过乙烯基单体在乙烯基低聚物存在下的乳液聚合获得; 其中乙烯基低聚物与乙烯基聚合物的重量％比在0.5:99.5至65:35的范围内。

6. 发明申请

WO2007102734A1 CONDUCTIVE INK 审中-公开
标题翻译：导电油墨
公开(公告)号：WO2007102734A1
公开(公告)日：2007-09-13
申请号：PCT/NL2007/050091
申请日：2007-03-06
申请人： DSM IP ASSETS B.V. , OVERBEEK, Gerardus Cornelis , SCHELLEKENS, Michael Arnoldus Jacobus , BÜCKMANN, Alfred Jean Paul
发明人： OVERBEEK, Gerardus Cornelis , SCHELLEKENS, Michael Arnoldus Jacobus , BÜCKMANN, Alfred Jean Paul
IPC分类号： C09D11/00 , H01B1/20
CPC分类号： C09D11/101 , C09D11/52 , H01B1/22 , H05K1/095 , Y10T428/249948 , Y10T428/25 , Y10T428/265
摘要： A conductive ink comprising 10 to 75 wt% of at least one solvent comprising
摘要翻译：一种导电油墨，其包含10至75重量％的至少一种包含<20重量％水的溶剂; 0〜50重量％的至少一种Mn在50〜10,000g / mol范围内的可辐射固化材料; 5至70重量％的至少一种Mw为4,000至70,000g / mol的聚氨基甲酸酯，0至5wt％的具有离子或潜在离子性水分散基团的异氰酸酯反应性组分，异氰酸酯基含量<0.5重量％和20〜85重量％的导电材料。

7. 发明申请

WO2003082999A1 AQUEOUS COATING COMPOSITION COMPRISING NON-CROSSLINKABLE OLIGOMERS(S) AND DISPERSED POLYMERS(S) 审中-公开
标题翻译：包含不可交联的低聚物（S）和分散聚合物（S）的水性涂料组合物
公开(公告)号：WO2003082999A1
公开(公告)日：2003-10-09
申请号：PCT/GB2003/001215
申请日：2003-03-21
申请人： AVECIA BV , AVECIA LIMITED , MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
发明人： MARTIN, Emilio , SCHEERDER, Jurgen , OVERBEEK, Gerardus, Cornelis , TENNEBROEK, Ronald , NABUURS, Tijs , STEENWINKEL, Pablo
IPC分类号： C09D201/00
CPC分类号： C09D167/00 , C09D175/04 , C08L2666/04
摘要： An aqueous coating composition comprising a non-crosslinkable water-dispersible oligomer(s); a dispersed polymer(s); water and optionally co-solvent wherein the composition has an open time of at least 20 min; a wet edge time of at least 10 min; a tack free time of ≤ 24 hours and an equilibrium viscosity of 5,000 Pa.s.
摘要翻译：一种包含不可交联的水分散性低聚物的水性涂料组合物; 分散的聚合物; 水和任选的共溶剂，其中组合物的开放时间为至少20分钟; 湿边缘时间至少为10分钟; 无粘性时间<= 24小时，平衡粘度为5000帕。

8. 发明申请

WO1996019536A1 AQUEOUS POLYMER EMULSIONS 审中-公开
标题翻译：水性聚合物乳液
公开(公告)号：WO1996019536A1
公开(公告)日：1996-06-27
申请号：PCT/EP1995005022
申请日：1995-12-19
申请人： ZENECA RESINS B.V. , PETERS, Antonius, Carolus, Ida, Adrianus , OVERBEEK, Gerardus, Cornelis
发明人： ZENECA RESINS B.V.
IPC分类号： C08L57/00
CPC分类号： C08F290/141 , C08F291/00 , C08F2/16
摘要： Aqueous emulsion of an organic polymeric material (preferably olefinic), said polymeric material comprising: 1) a hydrophobic polymer part which has a polymodal particle size distribution, and 2) an oligomer part bearing acid groups which imparts or is capable of imparting reversibility to the polymeric material of the emulsion, this being realized, if necessary, by sufficient of the acid groups being in ionised form. Ionisation is usually achieved by raising pH to >/= 7 (neutralizing). The polymer emulsion is particularly useful for inks and overprint lacquer formulations, and for paint formulations.
摘要翻译：所述聚合物材料包括：1）具有多晶型粒度分布的疏水性聚合物部分，和2）具有酸性基团的低聚物部分，其赋予或能赋予其可逆性的有机聚合物材料乳液的聚合物材料，如果需要，通过足够的酸基团是电离的形式实现的。电离通常通过将pH升高至> 7 =（中和）来实现。聚合物乳液特别适用于油墨和套印漆配方以及油漆配方。

9. 发明申请

WO1995029944A1 PRODUCTION OF AQUEOUS POLYMER COMPOSITIONS 审中-公开
标题翻译：生产水性聚合物组合物
公开(公告)号：WO1995029944A1
公开(公告)日：1995-11-09
申请号：PCT/GB1995000948
申请日：1995-04-27
申请人： ZENECA RESINS BV , ZENECA LIMITED , OVERBEEK, Gerardus, Cornelis , SMAK, Yvonne, Wilhelmina , BUCKMANN, Alfred, Jean, Paul , PADGET, John, Christopher
发明人： ZENECA RESINS BV , ZENECA LIMITED
IPC分类号： C08F265/04
CPC分类号： C09D151/00 , C08F265/04 , C08F265/06 , C08F2/22
摘要： Process for making organic solvent-free aqueous crosslinkable polymer composition comprising: a) preparing an aqueous solution of an acid-functional oligomer with Tg below 50 DEG C and having crosslinker functional groups; b) conducting an aqueous emulsion polymerisation to make an aqueous emulsion of an olefinic hydrophobic polymer in the presence of the aqueous oligomer solution, the hydrophobic polymer having Tg at least 25 DEG C higher than that of the oligomer and optionally crosslinker functional groups, and c) combining with a crosslinking agent reactable with the crosslinker groups of the oligomer and polymer, said composition having Koening hardness of >/= 40 sec. and minimum film forming temperature (MFFT)
摘要翻译：制备无机溶剂的含水可交联聚合物组合物的方法，包括：a）制备Tg低于50℃并具有交联剂官能团的酸官能低聚物的水溶液; b）进行水性乳液聚合以在低聚物溶液的存在下制备烯属疏水性聚合物的水性乳液，所述疏水性聚合物的Tg比低聚物和任选的交联剂官能团的Tg高至少25℃，c ）与可与低聚物和聚合物的交联剂基团反应的交联剂组合，所述组合物具有≥40秒的科宁硬度。和最低成膜温度（MFFT）<55℃。此外，如此形成的水性组合物及其在各种应用中的用途。水性组合物具有优异的性能，特别是MFFT和Koening硬度的有利平衡。

10. 发明申请

WO1995004767A1 PRODUCTION OF POLYMER EMULSIONS 审中-公开
标题翻译：生产聚合物乳液
公开(公告)号：WO1995004767A1
公开(公告)日：1995-02-16
申请号：PCT/GB1994001692
申请日：1994-08-02
申请人： ZENECA LIMITED , ZENECA RESINS B.V. , HADDLETON, David, Mark , PADGET, John, Christopher , OVERBEEK, Gerardus, Cornelis
发明人： ZENECA LIMITED , ZENECA RESINS B.V.
IPC分类号： C08F265/02
CPC分类号： C08F265/02
摘要： Process for the production of an aqueous polymer emulsion which process comprises: a) preparing a low molecular weight polymer containing acid-functional groups using a free-radical polymerisation process which employs a free-radical initiator and, for the purpose of controlling molecular weight, a transition metal chelate complex, wherein said low molecular weight polymer has a number average molecular weight within the range of from 500 to 50,000; b) conducting an aqueous emulsion polymerisation process to form an aqueous emulsion of a hydrophobic polymer from at least one olefinically unsaturated monomer, wherein the low molecular weight polymer of step a) is introduced to the aqueous medium of said emulsion polymerisation process before the start of and/or during said emulsion polymerisation process and becomes dissolved or dispersed in said aqueous medium.
摘要翻译：制备含水聚合物乳液的方法，该方法包括：a）使用自由基聚合方法制备含有酸官能团的低分子量聚合物，其使用自由基引发剂，并且为了控制分子量，过渡金属螯合络合物，其中所述低分子量聚合物的数均分子量在500至50,000的范围内; b）进行水性乳液聚合方法以形成来自至少一种烯属不饱和单体的疏水性聚合物的水性乳液，其中步骤a）的低分子量聚合物在开始之前被引入所述乳液聚合方法的水性介质中和/或在所述乳液聚合过程期间溶解或分散在所述水性介质中。

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