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    • 2. 发明申请
    • ULTRA HIGH STRENGTH STEEL SHEET WITH AN EXCELLENT HEAT TREATMENT PROPERTY FOR HOT PRESS FORMING, QUENCHED MEMBER, AND MANUFACTURING METHOD FOR SAME
    • 具有优异热处理性能的超高强度钢板,用于热压成型,淬火构件及其制造方法
    • WO2009145563A3
    • 2010-03-04
    • PCT/KR2009002811
    • 2009-05-27
    • POSCOOH JIN-KEUNKANG DAE-YOUNGCHIN KWANG-GEUNSIN DONG-SEOUG
    • OH JIN-KEUNKANG DAE-YOUNGCHIN KWANG-GEUNSIN DONG-SEOUG
    • C22C38/04
    • C22C38/02C22C38/001C22C38/04C22C38/06C22C38/18
    • The present invention relates to an ultra high strength steel sheet with an excellent heat treatment property, wherein the steel sheet contains, by weight %, C: 0.2 to 0.5%, Si: 0.01 to 1.5%, Mn: 0.5 to 2.0%, P: 0.1% or less (but not 0%), S: 0.03% or less (but not 0%), soluble Al: 0.1% or less (but not 0%), N: 0.01 to 0.1%, and Cr: 0.1 to 2.0%, and a remainder consisting of Fe and other impurities, and has a tensile strength measured before hot press forming of 800 MPa or less. The invention also relates to a manufacturing method for same. Further, the present invention relates to a quenched member formed by hot press forming and quick freezing the steel sheet to a tensile strength of 1800 MPa or higher, and relates to a manufacturing method for same. The present invention provides a steel sheet the tensile strength of which when measured before hot press forming is 800MPa or less and the tensile strength of which when measured after hot press forming and quick freezing is 1800 MPa or higher. Moreover, the steel sheet of the present invention has a yield strength increased to 100 MPa or higher after coating.
    • 本发明涉及一种具有优异的热处理性能的超高强度钢板,其中钢板以重量%计含有C:0.2〜0.5%,Si:0.01〜1.5%,Mn:0.5〜2.0%,P :0.1%以下(但不为0%),S:0.03%以下(但不为0%),可溶性Al:0.1%以下(但不为0%),N:0.01〜0.1%,Cr:0.1 至2.0%,剩余部分由Fe等杂质构成,热压成型前的拉伸强度为800MPa以下。 本发明还涉及其制造方法。 此外,本发明涉及通过热压成型形成的淬火构件,并且将钢板快速冷冻至拉伸强度为1800MPa以上,并且涉及其制造方法。 本发明提供一种钢板,其在热压成形前测定的抗拉强度为800MPa以下,其热压成形和快速冷冻后的拉伸强度为1800MPa以上。 此外,本发明的钢板的涂布后的屈服强度提高到100MPa以上。
    • 3. 发明申请
    • HIGH STRENGTH THIN STEEL SHEET EXCELLING IN WELDABILITY AND PROCESS FOR PRODUCING THE SAME
    • 高强度钢板在焊接性能及其制造方法中的应用
    • WO2009084795A1
    • 2009-07-09
    • PCT/KR2008/004627
    • 2008-08-08
    • POSCOKANG, Hee JaeOH, Jin KeunCHIN, Kwang GeunKIM, Jong Sang
    • KANG, Hee JaeOH, Jin KeunCHIN, Kwang GeunKIM, Jong Sang
    • C22C38/00
    • C22C38/38C22C38/06C22C38/32C22C38/60
    • Provided are a high strength thin steel sheet having tensile strength of about 800 MPa or more, and a manufacturing method thereof. The thin steel sheet is mainly used for construction materials, home appliances, and automobiles. The thin steel sheet has excellent plating char¬ acteristic, welding characteristic, bending workability, and hole expansion ratio. The thin steel sheet includes, in weight %, C: 0.02-0.20%, Si: 1.5% or less, Mn: 1.5-3.0%, P: 0.001-0.10%, S: 0.010% or less, SoLAl: 0.01-0.40%, N: 0.020% or less, Cr: 0.3-1.5%, B: 0.0010-0.0060%, Sb: 0.001-0.10%, and including at least one material selected from the group consisting of Ti: 0.003-0.08%, Nb: 0.003-0.08%, and Mo: 0.003-0.08%, and includes Fe and other inevitable impurities as a remainder. Here, Si, Mn, B, Sb, P, and S meet conditions of 5
    • 本发明提供一种拉伸强度为约800MPa以上的高强度薄钢板及其制造方法。 薄钢板主要用于建筑材料,家用电器和汽车。 薄钢板具有优异的电镀特性,焊接特性,弯曲加工性和孔膨胀率。 该薄钢板以重量%计含有C:0.02-0.20%,Si:1.5%以下,Mn:1.5-3.0%,P:0.001-0.10%,S:0.010%以下,SoLAl:0.01-0.40 %,N:0.020%以下,Cr:0.3〜1.5%,B:0.0010〜0.0060%,Sb:0.001-0.10%,并且包括选自Ti:0.003-0.08%,Nb :0.003-0.08%,Mo:0.003-0.08%,其余为Fe等不可避免的杂质。 这里,Si,Mn,B,Sb,P和S满足5 <(Si / Mn + 150B)/ Sb <20和C + Mn / 20 + Si / 30 + 2P + 4S <0.27的条件。 此外,制造方法可以确保薄钢板的可加工性。
    • 4. 发明申请
    • ZINC-PLATED STEEL SHEET FOR HOT PRESSING HAVING OUTSTANDING SURFACE CHARACTERISTICS, HOT-PRESSED MOULDED PARTS OBTAINED USING THE SAME, AND A PRODUCTION METHOD FOR THE SAME
    • 用于具有优异表面特性的热压的镀锌钢板,使用其的热压成型件及其制造方法
    • WO2011081392A4
    • 2012-01-19
    • PCT/KR2010009392
    • 2010-12-28
    • POSCOSOHN IL-RYOUNGKIM JONG-SANGPARK JOONG-CHULCHO YEOL-RAEOH JIN-KEUNCHO HAN-GUCHUNG BONG-HOONLEE JONG-SEOG
    • SOHN IL-RYOUNGKIM JONG-SANGPARK JOONG-CHULCHO YEOL-RAEOH JIN-KEUNCHO HAN-GUCHUNG BONG-HOONLEE JONG-SEOG
    • C23C2/06C22C38/00C23C2/02C23C2/28
    • C23C2/28C22C38/001C22C38/04C23C2/02C23C2/06C23C2/40C23C8/10Y10T428/12799Y10T428/12917Y10T428/12924Y10T428/12931Y10T428/12937Y10T428/12951Y10T428/12958
    • In one aspect of the present invention, provided is a zinc-plated steel sheet for hot pressing having outstanding surface characteristics, comprising: a steel foundation plate comprising a surface diffusion layer of a metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, within a depth of 1 µm from the surface; an aluminium-rich layer containing at least 30 wt.% of aluminium formed on the surface diffusion layer of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr; and a zinc plating layer formed on the aluminium-rich layer; wherein annealing oxides having a mean thickness of no more than 150 nm are distributed in a non-continuous fashion between the surface diffusion layer and the aluminium-rich layer, and there is a content of at least 0.1 wt.% of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, within a depth of 1 µm from the surface of the steel foundation plate. In this way, a metal having a low affinity for oxygen is coated to an effective thickness prior to annealing and thus the creation of annealing oxides at the surface of the steel sheet is suppressed and a uniform zinc plating layer is formed, and alloying of the zinc plating layer is promoted during press-processing heat treatment such that the melt temperature of the zinc plating layer is increased within a short time, thereby making it possible to prevent deterioration of the plating layer and to minimise the occurrence of internal oxides formed after hot press moulding. Also, according to another aspect of the present invention, an oxide layer able to prevent deterioration of the zinc plating layer is formed on the surface of the plating layer during hot press heating, and a three element phase of Zn, Fe and the metal is formed in the plating layer such that the zinc plating layer can be kept stable, a good surface condition is ensured and the phosphatability is outstanding, the plating properties during electrodeposition plating and film adhesion can be ensured even without carrying out a separate phosphating process, and workability can be improved as cracking in the steel foundation plate during hot press moulding is prevented.
    • 在本发明的一个方面,提供了一种具有优异表面特性的用于热压的镀锌钢板,包括:钢基础板,其包括金属的表面扩散层,其每摩尔氧的吉布斯自由能降低 在距离表面1μm的深度内氧化小于Cr, 在金属的表面扩散层上形成含有至少30重量%的铝的富铝层,其中氧化期间每摩尔氧的吉布斯自由能降低小于Cr; 以及形成在富铝层上的镀锌层; 其中平均厚度不超过150nm的退火氧化物以非连续的方式分布在表面扩散层和富铝层之间,并且其含量至少为其重量的0.1重量% 在氧化期间每摩尔氧的吉布斯自由能降低小于Cr的距离,距离钢基板的表面1μm以下。 以这种方式,在退火之前将对氧的亲和力低的金属涂覆到有效厚度,因此在钢板表面产生退火氧化物,并形成均匀的镀锌层,并且合金化 在加压热处理中促进镀锌层,使得镀锌层的熔融温度在短时间内增加,从而可以防止镀层的劣化,并使热镀后形成的内部氧化物的发生最小化 压模。 此外,根据本发明的另一方面,在热压加热期间,在镀层的表面上形成能够防止镀锌层劣化的氧化物层,Zn,Fe和金属的三元相为 形成在镀层中,使得镀锌层可以保持稳定,良好的表面状态得到确保并且磷酸盐性突出,即使不进行单独的磷化工艺,也可以确保电沉积电镀和膜粘附期间的电镀性能, 可以提高加工性,因为防止热压成型时的钢基板的龟裂。
    • 8. 发明申请
    • ZINC-PLATED STEEL SHEET FOR HOT PRESSING HAVING OUTSTANDING SURFACE CHARACTERISTICS, HOT-PRESSED MOULDED PARTS OBTAINED USING THE SAME, AND A PRODUCTION METHOD FOR THE SAME
    • 用于具有出色表面特性的热压的镀锌钢板,使用其获得的热压成型部件及其制造方法
    • WO2011081392A3
    • 2011-12-01
    • PCT/KR2010009392
    • 2010-12-28
    • POSCOSOHN IL-RYOUNGKIM JONG-SANGPARK JOONG-CHULCHO YEOL-RAEOH JIN-KEUNCHO HAN-GUCHUNG BONG-HOONLEE JONG-SEOG
    • SOHN IL-RYOUNGKIM JONG-SANGPARK JOONG-CHULCHO YEOL-RAEOH JIN-KEUNCHO HAN-GUCHUNG BONG-HOONLEE JONG-SEOG
    • C23C2/06C22C38/00C23C2/02C23C2/28
    • C23C2/28C22C38/001C22C38/04C23C2/02C23C2/06C23C2/40C23C8/10Y10T428/12799Y10T428/12917Y10T428/12924Y10T428/12931Y10T428/12937Y10T428/12951Y10T428/12958
    • In one aspect of the present invention, provided is a zinc-plated steel sheet for hot pressing having outstanding surface characteristics, comprising: a steel foundation plate comprising a surface diffusion layer of a metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, within a depth of 1 µm from the surface; an aluminium-rich layer containing at least 30 wt.% of aluminium formed on the surface diffusion layer of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr; and a zinc plating layer formed on the aluminium-rich layer; wherein annealing oxides having a mean thickness of no more than 150 nm are distributed in a non-continuous fashion between the surface diffusion layer and the aluminium-rich layer, and there is a content of at least 0.1 wt.% of the metal of which the Gibbs free energy reduction per mole of oxygen during oxidation is less than that of Cr, within a depth of 1 µm from the surface of the steel foundation plate. In this way, a metal having a low affinity for oxygen is coated to an effective thickness prior to annealing and thus the creation of annealing oxides at the surface of the steel sheet is suppressed and a uniform zinc plating layer is formed, and alloying of the zinc plating layer is promoted during press-processing heat treatment such that the melt temperature of the zinc plating layer is increased within a short time, thereby making it possible to prevent deterioration of the plating layer and to minimise the occurrence of internal oxides formed after hot press moulding. Also, according to another aspect of the present invention, an oxide layer able to prevent deterioration of the zinc plating layer is formed on the surface of the plating layer during hot press heating, and a three element phase of Zn, Fe and the metal is formed in the plating layer such that the zinc plating layer can be kept stable, a good surface condition is ensured and the phosphatability is outstanding, the plating properties during electrodeposition plating and film adhesion can be ensured even without carrying out a separate phosphating process, and workability can be improved as cracking in the steel foundation plate during hot press moulding is prevented.
    • 在本发明的一个方面中,提供了一种具有优异表面特性的用于热压的镀锌钢板,其包括:钢基础板,其包括金属的表面扩散层,其中在每个摩尔氧期间吉布斯自由能降低 在离表面1μm的深度内氧化比Cr的氧化少; 在金属的表面扩散层上形成的含有至少30重量%铝的富铝层,其中在氧化过程中每摩尔氧的吉布斯自由能降低小于Cr的摩尔数; 以及在富铝层上形成的镀锌层; 其中平均厚度不超过150nm的退火氧化物以不连续的方式分布在表面扩散层和富铝层之间,并且其中金属的含量至少为0.1重量% 在距离钢基板表面1μm的深度内,氧化期间每摩尔氧的Gibbs自由能降低小于Cr的Gibbs自由能降低。 这样,在退火之前将对氧的亲和力低的金属涂覆成有效厚度,从而抑制了钢板表面处的退火氧化物的产生,并形成了均匀的镀锌层,并且合金化了 在压制加工热处理期间促进镀锌层,使得锌镀层的熔融温度在短时间内增加,由此使得可以防止镀层的劣化并且使热后形成的内部氧化物的发生最小化 压模成型。 此外,根据本发明的另一方面,在热压加热过程中,在镀层的表面上形成能够防止镀锌层劣化的氧化物层,并且Zn,Fe和金属的三元素相为 形成在镀层中,使得锌镀层能够保持稳定,确保良好的表面条件,并且可磷化性优异,即使不进行单独的磷化处理也能确保电沉积镀覆和膜粘合期间的镀覆性能,并且 防止了在热压模制过程中钢基板的开裂,可以提高可操作性。