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    • 6. 发明授权
    • Vinyl chloride resin, process for producing the same, and molded object
    • 氯乙烯树脂,其制造方法和成型体
    • US06583221B1
    • 2003-06-24
    • US09807840
    • 2001-07-13
    • Takahiro OmuraNoriki Fujii
    • Takahiro OmuraNoriki Fujii
    • C08F28500
    • C08L51/003C08F265/04C08F265/06C08F285/00C08L27/06C08L51/00C08F214/06C08L2666/24C08L2666/04C08L2666/02
    • This invention is related to a vinyl chloride resin as obtainable by graft-copolymerizing an acrylic copolymer (a) having a mean particle diameter of 60 to 250 nm with a vinyl monomer (b) predominantly composed of vinyl chloride, said acrylic copolymer (a) being obtainable by graft-copolymerizing 40 to 90 weight % of a copolymer (a−1) with 10 to 60 weight % of a mixture monomer (a−2), said copolymer (a−1) being composed of 100 weight parts of a radical-polymerizable monomer which gives a homopolymer having a glass transition point of not lower than −140° C. but lower than −60° C. and 0.1 to 1 weight part of a polyfunctional monomer, and said mixture monomer (a−2) comprising 100 weight parts of a radical-polymerizable monomer predominantly comprised of a (meth) acrylate which gives a homopolymer having a glass transition point of not lower than −55° C. but lower than −10° C. and 1.5 to 10 weight parts of a polyfunctional monomer.
    • 本发明涉及通过将平均粒径为60至250nm的丙烯酸共聚物(a)与主要由氯乙烯组成的乙烯基单体(b)接枝共聚获得的氯乙烯树脂,所述丙烯酸共聚物(a) 通过以40〜90重量%的共聚物(a-1)与10〜60重量%的混合单体(a-2)接枝共聚而获得,所述共聚物(a-1)由100重量份的 得到玻璃化转变温度不低于-140℃但低于-60℃的均聚物和0.1至1重量份多官能单体的自由基聚合单体,所述混合单体(a-2) 包含100重量份主要由(甲基)丙烯酸酯组成的自由基聚合性单体,其得到玻璃化转变温度不低于-55℃但低于-10℃的均聚物和1.5至10重量份 的多官能单体。