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1. 发明授权

US09196850B2 Organic devices, organic electroluminescent devices, organic solar cells, organic FET structures and production method of organic devices 有权
标题翻译：有机器件，有机电致发光器件，有机太阳能电池，有机FET结构和有机器件的生产方法
公开(公告)号：US09196850B2
公开(公告)日：2015-11-24
申请号：US10983857
申请日：2004-11-08
申请人： Toshio Matsumoto , Akira Yokoi , Takeshi Nakada , Norifumi Kawamura , Junji Kido
发明人： Toshio Matsumoto , Akira Yokoi , Takeshi Nakada , Norifumi Kawamura , Junji Kido
IPC分类号： H01L51/54 , H01L51/42 , H01L51/50 , H01L51/52 , H01L51/00
CPC分类号： H01L51/424 , H01L51/0051 , H01L51/0067 , H01L51/0071 , H01L51/0077 , H01L51/0078 , H01L51/0079 , H01L51/0081 , H01L51/0089 , H01L51/4253 , H01L51/5048 , H01L51/5052 , H01L51/5068 , H01L51/5088 , H01L51/5092 , H01L51/5278 , H01L2251/308 , Y02E10/549 , Y02P70/521
摘要： An organic device has a hole current-electron current conversion layer which comprises a laminate of an electron transportation section and a hole transportation section. The electron transportation section includes a charge transfer complex formed upon an oxidation-reduction reaction between a reduced low work function metal and an electron-accepting organic compound, the reduced metal being produced upon an in-situ thermal reduction reaction caused upon contact, through lamination or mixing by co-deposition, of an organic metal complex compound or an inorganic compound containing at least one metal ion selected from ions of low work function metals having a work function of not more than 4.0 eV, and a thermally reducible metal capable of reducing a metal ion contained in the organic metal complex compound or the inorganic compound in vacuum to the corresponding metal state, and the electron transportation section having the electron-accepting organic compound in the state of radical anions. The hole transportation section includes an organic compound having an ionization potential of less than 5.7 eV and an electron-donating property and an inorganic or organic substance capable of forming a charge transfer complex upon its oxidation-reduction reaction with the organic compound, the organic compound and the inorganic or organic substance being contacted through lamination or mixing, and the electron-donating organic compound is in the state of radical cations.
摘要翻译：有机器件具有空穴电流 - 电子电流转换层，其包括电子传输部分和空穴传输部分的叠层。电子传输部分包括在还原的低功函数金属和受电子有机化合物之间的氧化还原反应中形成的电荷转移络合物，所述还原金属在通过层压产生的原位热还原反应时产生或通过共沉积混合有机金属络合物或含有至少一种金属离子的无机化合物，所述金属离子选自具有不大于4.0eV的功函数的低功函数金属的离子，以及能够还原的可还原金属包含在有机金属络合物或无机化合物中的金属离子在真空中成为相应的金属状态，电子传输部分具有处于自由基阴离子状态的电子接受有机化合物。空穴传输部分包括具有小于5.7eV的电离电位和给电子性的有机化合物和能够在与有机化合物进行氧化还原反应时形成电荷转移络合物的无机或有机物质，有机化合物并且无机或有机物质通过层压或混合而接触，并且给电子有机化合物处于自由基阳离子的状态。

2. 发明申请

US20050084712A1 Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：US20050084712A1
公开(公告)日：2005-04-21
申请号：US10966251
申请日：2004-10-15
申请人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
发明人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
IPC分类号： C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/14 , H05B33/12
CPC分类号： H01L51/5088 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0081
摘要： An organic electroluminescent device includes an anode electrode layer; a cathode electrode layer opposed to the anode electrode layer; a hole injection layer provided adjacent to the anode electrode layer an organic structure including at least one light-emissive layer_or at least one light-emissive unit having at least one light-emissive layer; between the anode electrode layer and the cathode electrode layer. At least one of the anode electrode layer and the cathode electrode layer is transparent. The hole injection layer includes a mixed layer of a metal oxide and an organic compound. The mixed layer is formed upon co-deposition of the metal oxide and the organic compound.
摘要翻译：有机电致发光器件包括阳极电极层; 与阳极电极层相对的阴极电极层; 空穴注入层，与所述阳极电极层相邻设置有机结构，所述有机结构包括至少一个发光层或至少一个具有至少一个发光层的发光单元; 在阳极电极层和阴极电极层之间。阳极电极层和阴极电极层中的至少一个是透明的。空穴注入层包括金属氧化物和有机化合物的混合层。混合层是在共沉积金属氧化物和有机化合物时形成的。

3. 发明授权

US09203046B2 Organic electroluminescent device and production process thereof 有权
标题翻译：有机电致发光器件及其制造方法
公开(公告)号：US09203046B2
公开(公告)日：2015-12-01
申请号：US10966708
申请日：2004-10-15
申请人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
发明人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
IPC分类号： H01L51/50 , H01L51/00 , H01L51/52
CPC分类号： H01L51/5048 , H01L51/002 , H01L51/0052 , H01L51/0059 , H01L51/0077 , H01L51/0081 , H01L51/5092 , H01L51/5221 , Y10T428/26
摘要： An organic electroluminescent device including a substrate, the substrate includes, laminated thereon, an anode layer; an organic structure including at least one light-emissive layer or at least one light-emissive unit having at least one light-emissive layer; a low resistance electron-transporting layer including a mixed layer of an electron-donating metal dopant and an organic compound; an organometallic complex-contained layer including an organometallic complex compound containing at least one metal ion selected from the group having an alkaline metal ion, an alkaline earth metal ion and a rare earth metal ion; a reducing reaction generating layer; and a cathode layer, in that order. At least one of the anode layer and the cathode layer is transparent. The reducing reaction generating layer is a layer produced by depositing on the organometallic complex-contained layer a thermally reducible metal capable of reducing a metal ion in the organometallic complex compound in a vacuum to the corresponding metal, followed by causing an oxidation-reduction reaction therebetween.
摘要翻译：一种有机电致发光器件，包括衬底，所述衬底包括层压在其上的阳极层; 包括至少一个发光层或至少一个具有至少一个发光层的发光单元的有机结构; 包含给电子金属掺杂剂和有机化合物的混合层的低电阻电子传输层; 含有金属络合物的有机金属配合物层，其含有选自碱金属离子，碱土金属离子，稀土金属离子中的至少一种金属离子的有机金属络合物; 还原反应生成层; 和阴极层。阳极层和阴极层中的至少一个是透明的。还原反应生成层是通过在有机金属络合物含有层上沉积能够将有机金属络合物中的金属离子在真空中还原成相应金属的可热还原金属制造的层，然后在其间进行氧化还原反应。

4. 发明申请

US20050084713A1 Organic electroluminescent device and production process thereof 有权
标题翻译：有机电致发光器件及其制造方法
公开(公告)号：US20050084713A1
公开(公告)日：2005-04-21
申请号：US10966708
申请日：2004-10-15
申请人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
发明人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
IPC分类号： H01L51/00 , H01L51/30 , H01L51/40 , H01L51/50 , H01L51/52 , H05B33/10 , H05B33/14 , H05B33/22 , H05B33/26 , H05B33/12
CPC分类号： H01L51/5048 , H01L51/002 , H01L51/0052 , H01L51/0059 , H01L51/0077 , H01L51/0081 , H01L51/5092 , H01L51/5221 , Y10T428/26
摘要： An organic electroluminescent device including a substrate, the substrate includes, laminated thereon, an anode layer; an organic structure including at least one light- emissive layer or at least one light-emissive unit having at least one light-emissive layer; a low resistance electron-transporting layer including a mixed layer of an electron-donating metal dopant and an organic compound; an organometallic complex-contained layer including an organometallic complex compound containing at least one metal ion selected from the group having an alkaline metal ion, an alkaline earth metal ion and a rare earth metal ion; a reducing reaction generating layer; and a cathode layer, in that order. At least one of the anode layer and the cathode layer is transparent. The reducing reaction generating layer is a layer produced by depositing on the organometallic complex- contained layer a thermally reducible metal capable of reducing a metal ion in the organometallic complex compound in a vacuum to the corresponding metal, followed by causing an oxidation-reduction reaction therebetween.
摘要翻译：一种有机电致发光器件，包括衬底，所述衬底包括层压在其上的阳极层; 包括至少一个发光层或至少一个具有至少一个发光层的发光单元的有机结构; 包含给电子金属掺杂剂和有机化合物的混合层的低电阻电子传输层; 含有金属络合物的有机金属配合物层，其含有选自碱金属离子，碱土金属离子，稀土金属离子中的至少一种金属离子的有机金属络合物; 还原反应生成层; 和阴极层。阳极层和阴极层中的至少一个是透明的。还原反应生成层是通过在有机金属络合物含有层上沉积能够在真空中将金属离子在有机金属络合物中还原成相应金属的可热还原金属制造的层，然后在其间进行氧化还原反应。

5. 发明授权

US08227980B2 Organic EL device 有权
标题翻译：有机EL器件
公开(公告)号：US08227980B2
公开(公告)日：2012-07-24
申请号：US12736454
申请日：2009-03-31
申请人： Norifumi Kawamura , Kohichi Mori , Hideyuki Kobayashi , Hiroshi Takehisa
发明人： Norifumi Kawamura , Kohichi Mori , Hideyuki Kobayashi , Hiroshi Takehisa
IPC分类号： H01J1/62
CPC分类号： H01L51/5203
摘要： The organic EL device (1) comprises: a substrate (2); a light emitting unit formed on the substrate (2), and including an anode (11), a cathode (7) having anelectric resistance lower than that of the anode (11), an organic light emitting layer (6) formed between the anode (11) and the cathode (7); an anode terminal (12) formed on the substrate (2) and connected to the anode (11), and a cathode terminal (16) formed on the substrate (2) and connected to the cathode (7). A surface of the anode terminal (12) connected to the external is applied into an anode connecting surface (12a), and a surface of the cathode terminal (16) connected to the external is applied into a cathode connecting face (16a). The size (S1) of the anode connecting surface (12a) is larger than the size (S2) of the cathode connecting surface (16a).
摘要翻译：有机EL器件（1）包括：衬底（2）; 形成在所述基板（2）上的发光单元，并且包括阳极（11），具有比所述阳极（11）低的电阻的阴极（7）;形成在所述阳极之间的有机发光层，（11）和阴极（7）; 形成在基板（2）上并连接到阳极（11）的阳极端子（12）和形成在基板（2）上并连接到阴极（7）的阴极端子（16）。连接到外部的阳极端子（12）的表面被施加到阳极连接表面（12a）中，并且连接到外部的阴极端子（16）的表面被施加到阴极连接面（16a）。阳极连接面（12a）的尺寸（S1）大于阴极连接面（16a）的尺寸（S2）。

6. 发明申请

US20110025197A1 ORGANIC EL DEVICE 有权
标题翻译：有机EL设备
公开(公告)号：US20110025197A1
公开(公告)日：2011-02-03
申请号：US12736454
申请日：2009-03-31
申请人： Norifumi Kawamura , Kohichi Mori , Hideyuki Kobayashi , Hiroshi Takehisa
发明人： Norifumi Kawamura , Kohichi Mori , Hideyuki Kobayashi , Hiroshi Takehisa
IPC分类号： H01L51/52
CPC分类号： H01L51/5203
摘要： The organic EL device (1) comprises: a substrate (2); a light emitting unit formed on the substrate (2), and including an anode (11), a cathode (7) having anelectric resistance lower than that of the anode (11), an organic light emitting layer (6) formed between the anode (11) and the cathode (7); an anode terminal (12) formed on the substrate (2) and connected to the anode (11), and a cathode terminal (16) formed on the substrate (2) and connected to the cathode (7). A surface of the anode terminal (12) connected to the external is applied into an anode connecting surface (12a), and a surface of the cathode terminal (16) connected to the external is applied into a cathode connecting face (16a). The size (S1) of the anode connecting surface (12a) is larger than the size (S2) of the cathode connecting surface (16a).
摘要翻译：有机EL器件（1）包括：衬底（2）; 形成在所述基板（2）上的发光单元，并且包括阳极（11），具有比所述阳极（11）低的电阻的阴极（7）;形成在所述阳极之间的有机发光层，（11）和阴极（7）; 形成在基板（2）上并连接到阳极（11）的阳极端子（12）和形成在基板（2）上并连接到阴极（7）的阴极端子（16）。连接到外部的阳极端子（12）的表面被施加到阳极连接表面（12a）中，并且连接到外部的阴极端子（16）的表面被施加到阴极连接面（16a）。阳极连接面（12a）的尺寸（S1）大于阴极连接面（16a）的尺寸（S2）。

7. 发明申请

US20050098207A1 Organic devices, organic electroluminescent devices, organic solar cells, organic FET structures and production method of organic devices 有权
标题翻译：有机器件，有机电致发光器件，有机太阳能电池，有机FET结构和有机器件的生产方法
公开(公告)号：US20050098207A1
公开(公告)日：2005-05-12
申请号：US10983857
申请日：2004-11-08
申请人： Toshio Matsumoto , Akira Yokoi , Takeshi Nakada , Norifumi Kawamura , Junji Kido
发明人： Toshio Matsumoto , Akira Yokoi , Takeshi Nakada , Norifumi Kawamura , Junji Kido
IPC分类号： C09K11/06 , H01L29/80 , H01L51/00 , H01L51/05 , H01L51/10 , H01L51/30 , H01L51/40 , H01L51/42 , H01L51/50 , H01L51/52 , H05B33/10 , H01L31/00 , H01J1/62 , H01J63/04
CPC分类号： H01L51/424 , H01L51/0051 , H01L51/0067 , H01L51/0071 , H01L51/0077 , H01L51/0078 , H01L51/0079 , H01L51/0081 , H01L51/0089 , H01L51/4253 , H01L51/5048 , H01L51/5052 , H01L51/5068 , H01L51/5088 , H01L51/5092 , H01L51/5278 , H01L2251/308 , Y02E10/549 , Y02P70/521
摘要： An organic device has a hole current-electron current conversion layer which comprises a laminate of an electron transportation section and a hole transportation section. The electron transportation section includes a charge transfer complex formed upon an oxidation-reduction reaction between a reduced low work function metal and an electron-accepting organic compound, the reduced metal being produced upon an in-situ thermal reduction reaction caused upon contact, through lamination or mixing by co-deposition, of an organic metal complex compound or an inorganic compound containing at least one metal ion selected from ions of low work function metals having a work function of not more than 4.0 eV, and a thermally reducible metal capable of reducing a metal ion contained in the organic metal complex compound or the inorganic compound in vacuum to the corresponding metal state, and the electron transportation section having the electron-accepting organic compound in the state of radical anions. The hole transportation section includes an organic compound having an ionization potential of less than 5.7 eV and an electron-donating property and an inorganic or organic substance capable of forming a charge transfer complex upon its oxidation-reduction reaction with the organic compound, the organic compound and the inorganic or organic substance being contacted through lamination or mixing, and the electron-donating organic compound is in the state of radical cations.
摘要翻译：有机器件具有空穴电流 - 电子电流转换层，其包括电子传输部分和空穴传输部分的叠层。电子传输部分包括在还原的低功函数金属和受电子有机化合物之间的氧化还原反应中形成的电荷转移络合物，所述还原金属在通过层压产生的原位热还原反应时产生或通过共沉积混合有机金属络合物或含有至少一种金属离子的无机化合物，所述金属离子选自具有不大于4.0eV的功函数的低功函数金属的离子，以及能够还原的可还原金属包含在有机金属络合物或无机化合物中的金属离子在真空中成为相应的金属状态，电子传输部分具有处于自由基阴离子状态的电子接受有机化合物。空穴传输部分包括具有小于5.7eV的电离电位和给电子性的有机化合物和能够在与有机化合物进行氧化还原反应时形成电荷转移络合物的无机或有机物质，有机化合物并且无机或有机物质通过层压或混合而接触，并且给电子有机化合物处于自由基阳离子的状态。

8. 发明授权

US08558451B2 Organic electroluminescent device 有权
标题翻译：有机电致发光器件
公开(公告)号：US08558451B2
公开(公告)日：2013-10-15
申请号：US10966251
申请日：2004-10-15
申请人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
发明人： Junji Kido , Toshio Matsumoto , Takeshi Nakada , Norifumi Kawamura
IPC分类号： H01L51/50
CPC分类号： H01L51/5088 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/0077 , H01L51/0081
摘要： An organic electroluminescent device includes an anode electrode layer; a cathode electrode layer opposed to the anode electrode layer; a hole injection layer provided adjacent to the anode electrode layer an organic structure including at least one light-emissive layer or at least one light-emissive unit having at least one light-emissive layer; between the anode electrode layer and the cathode electrode layer. At least one of the anode electrode layer and the cathode electrode layer is transparent. The hole injection layer includes a mixed layer of a metal oxide and an organic compound. The mixed layer is formed upon co-deposition of the metal oxide and the organic compound.
摘要翻译：有机电致发光器件包括阳极电极层; 与阳极电极层相对的阴极电极层; 空穴注入层，其与所述阳极电极层相邻设置有有机结构，所述有机结构包括至少一个发光层或至少一个具有至少一个发光层的发光单元; 在阳极电极层和阴极电极层之间。阳极电极层和阴极电极层中的至少一个是透明的。空穴注入层包括金属氧化物和有机化合物的混合层。混合层是在共沉积金属氧化物和有机化合物时形成的。

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