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1. 发明授权

US07482412B2 Process for manufacturing cycloolefin addition polymer 有权
标题翻译：制备环烯加成聚合物的方法
公开(公告)号：US07482412B2
公开(公告)日：2009-01-27
申请号：US11869221
申请日：2007-10-09
申请人： Kenzo Ohkita , Nobuyuki Sakabe
发明人： Kenzo Ohkita , Nobuyuki Sakabe
IPC分类号： C08F2/38 , C08F32/04
CPC分类号： C08F2/38 , C08F32/00
摘要： A process for manufacturing a cycloolefin addition polymer includes polymerizing monomers containing a cycloolefin compound using a catalyst containing a nickel compound or a palladium compound by addition polymerization in the presence of a molecular weight controlling agent in two steps, that is a step of a initiating the polymerization reaction using the monomers in an amount of not more than 80 wt % of the total monomers and a step of supplying the remaining monomers to the reaction system during the polymerization reaction. A cycloolefin addition polymer with a uniform quality, having a narrow molecular weight distribution and a controlled molecular weight, and excellently balanced processability and mechanical strength can be obtained at a high polymerization conversion rate using the process. The process can be operated at a highly controlled polymerization temperature, and is thus suitable for industrially manufacturing a cycloolefin addition polymer.
摘要翻译：制备环烯加成聚合物的方法包括使用含有镍化合物或钯化合物的催化剂在含有分子量控制剂的两步加成聚合中使含有环烯烃化合物的单体聚合，即，使用单体的聚合反应的量不大于总单体的80重量％，以及在聚合反应期间将剩余的单体供应到反应体系的步骤。使用该方法可以以高聚合转化率获得具有均匀质量的具有均匀质量的环烯烃加成聚合物，具有窄的分子量分布和受控的分子量，并且具有优异的加工性能和机械强度。该方法可以在高度控制的聚合温度下操作，因此适用于工业生产环烯加成聚合物。

2. 发明授权

US3953409A Process for producing conjugated diolefinic polymers 失效
标题翻译：制备共轭二烯聚合物的方法
公开(公告)号：US3953409A
公开(公告)日：1976-04-27
申请号：US39569
申请日：1970-05-21
申请人： Koei Komatsu , Shigeyuki Nishiyama , Nobuyuki Sakabe , Akira Kogure
发明人： Koei Komatsu , Shigeyuki Nishiyama , Nobuyuki Sakabe , Akira Kogure
IPC分类号： C08F36/04 , C08F236/16 , C08F236/18
CPC分类号： C08F36/04
摘要： Conjugated diolefinic polymers having a molecular weight of less than 1,000,000 can be produced at high polymerization rates and in high yields by polymerizing a conjugated diolefin or copolymerizing a conjugated diolefin with a vinyl aromatic hydrocarbon in the presence of an alfin catalyst, in which as a molecular weight regulator is used a halogenated unsaturated hydrocarbon represented by the formula, ##EQU1## wherein R is an alkyl group having 1 to 7 carbon atoms, a vinyl group, a phenyl group, an alkyl-substituted phenyl group, a halogen atom or a hydrogen atom, and X, Y and Z which may be same or different are individually a hydrogen atom, a halogen atom or an alkyl group having 1 to 4 carbon atoms, at least one of the R, X, Y and Z being a halogen atom. The above-mentioned molecular weight regulator not only displays a prominent molecular weight-regulating effect, even when used in a small amount, but also is easily commercially obtainable and inexpensive, so that marked commercial advantages can be attained according to the above-mentioned process.
摘要翻译：分子量小于1,000,000的共轭二烯烃聚合物可以在高聚合速率下以高收率产生，通过聚合共轭二烯烃或共轭二烯烃与乙烯基芳族烃在烯属催化剂存在下共聚，其中作为分子使用由式RY ANGLE C = C ANGLE XZ表示的卤代不饱和烃，其中R是具有1至7个碳原子的烷基，乙烯基，苯基，烷基取代的苯基，卤素原子或氢原子，X，Y和Z可以相同或不同，分别为氢原子，卤素原子或碳原子数1〜4的烷基，R，X，Y和Z中的至少一个是卤素原子。上述分子量调节剂即使在少量使用的情况下也显示出突出的分子量调节作用，而且容易商业上可获得并且价廉，因此可以根据上述方法获得显着的商业优点。

3. 发明申请

US20080125556A1 Method For Producing Cyclic Olefin Addition Copolymer, Cyclic Olefin Addition Copolymer And Use Thereof 审中-公开
标题翻译：生产环烯烃加成共聚物，环烯烃加成共聚物及其用途的方法
公开(公告)号：US20080125556A1
公开(公告)日：2008-05-29
申请号：US11722525
申请日：2005-12-05
申请人： Kenzo Ohkita , Noboru Oshima , Nobuyuki Sakabe , Katsutoshi Sawada
发明人： Kenzo Ohkita , Noboru Oshima , Nobuyuki Sakabe , Katsutoshi Sawada
IPC分类号： C08F4/60
CPC分类号： C08F230/08
摘要： The present invention provides a method for producing a cyclic olefin addition copolymer wherein a monomer composition containing 5 to 80 mol % of a cyclic olefin having a substituent selected from alkyl groups, alkylsilyl group, and alkylsilylmethyl group represented by formula (1) below and 20 to 95 mol % of a cyclic olefin represented by formula (2) below is addition-copolymerized in the presence of a palladium-based multicomponent catalyst containing a specific palladium compound (i), a specific phosphorus compound (ii), and an ionic boron compound or an ionic aluminum compound (iii): (one of A1 to A4 is a C4-5 alkyl group, trimethylsilyl group, or trimethylsilylmethyl group, and the others each independently are a hydrogen atom, halogen atom, or methyl group) (B1 to B4 are each independently a hydrogen atom, methyl group, or halogen atom.)
摘要翻译：本发明提供一种环状烯烃加成共聚物的制造方法，其中含有5〜80摩尔％的具有选自下述式（1）表示的烷基，烷基甲硅烷基和烷基甲硅烷基甲基的取代基的环状烯烃的单体组合物和20 至（95）摩尔％的由下式（2）表示的环状烯烃在含有特定的钯化合物（i），特定的磷化合物（ⅱ）和离子性硼的离子性硼的钯系多组分催化剂的存在下进行加成共聚化合物或离子型铝化合物（iii）：（A 1〜4中的一个）为C 4〜5〜5个烷基，三甲基甲硅烷基或三甲基甲硅烷基甲基，其余各自独立地为氢原子，卤素原子或甲基）（B 1至B 4）各自独立地为氢原子，甲基基团或卤原子。）

4. 发明授权

US4861851A Vinylidene fluoride-acrylic acid ester copolymer, process for producing the same and composition containing the same 失效
标题翻译：偏二氟乙烯 - 丙烯酸酯共聚物，其制造方法和含有它们的组合物
公开(公告)号：US4861851A
公开(公告)日：1989-08-29
申请号：US145103
申请日：1988-01-19
申请人： Toshio Miyabayashi , Nobuyuki Sakabe , Shinichiro Zen
发明人： Toshio Miyabayashi , Nobuyuki Sakabe , Shinichiro Zen
IPC分类号： C08F14/22 , C08F214/22 , C08F220/10 , C08F220/12
CPC分类号： C08F220/10 , C08F214/225
摘要： A substantially random, linear vinylidene fluoride-acrylic acid ester copolymer comprising:(A) 5-85% by weight of a vinylidene fluoride unit,(B) 15-95% by weight of at least one unit selected from the group consisting of an alkyl acrylate unit and an alkoxy-substituted alkyl acrylate unit, and(C) optionally 10% by weight or less, based on the total weight of (A), (B) and (C), of a crosslinking monomer unit, and having an intrinsic viscosity of 0.01-10 dl/g as measured at 30.degree. C. in N,N-dimethylformamide. Said copolymer has not only excellent heat resistance, ozone resistance and sour gasoline resistance but also excellent resistance to gasoline permeation.

5. 发明授权

US4194156A FM tuner 失效
标题翻译： FM调谐器
公开(公告)号：US4194156A
公开(公告)日：1980-03-18
申请号：US911172
申请日：1978-05-31
申请人： Nobuyuki Sakabe
发明人： Nobuyuki Sakabe
IPC分类号： H03J3/14 , H04B1/16
CPC分类号： H03J3/14
摘要： An FM tuner comprising means for producing an intermediate frequency signal, a frequency discriminator circuit having "S" characteristics, a differential amplifier circuit, and detector means. The bias of said differential amplifier circuit is controlled in accordance with the direct current component of the output of said frequency discriminator circuit, and part of said intermediate frequency signal is passed to said detector means through said differential amplifier circuit, whereby that frequency position of said intermediate frequency signal which corresponds to the center of said direct current component is detected. Thus, it is possible to determine whether or not the FM tuner is in an optimum tuned state.
摘要翻译：一种FM调谐器，包括用于产生中频信号的装置，具有“S”特性的鉴频器电路，差分放大器电路和检测器装置。所述差分放大器电路的偏置根据所述鉴频器电路的输出的直流分量进行控制，并且所述中频信号的一部分通过所述差分放大器电路传送到所述检测器装置，由此所述差分放大器电路的频率位置检测对应于所述直流分量的中心的中频信号。因此，可以确定FM调谐器是否处于最佳调谐状态。

6. 发明授权

US4072907A Amplifier circuit 失效
标题翻译：放大器电路
公开(公告)号：US4072907A
公开(公告)日：1978-02-07
申请号：US740979
申请日：1976-11-11
申请人： Mamoru Sekiya , Nobuyuki Sakabe
发明人： Mamoru Sekiya , Nobuyuki Sakabe
IPC分类号： H03F3/30 , H03F3/45
CPC分类号： H03F3/3071 , H03F3/45085 , H03F2203/45472 , H03F2203/45496 , H03F2203/45598 , H03F2203/45601 , H03F2203/45701
摘要： An amplifier circuit comprising a differential circuit including means for preventing base bias voltages applied to driver transistors connected with the transistors constituting the differential amplifier from becoming unbalanced. Means is also provided which is adapted to prevent so-called shock noise from appearing at the output of the amplifier circuit. Such means may be constructed by using a delay circuit.
摘要翻译：一种包括差分电路的放大器电路，包括用于防止施加到与构成差分放大器的晶体管连接的驱动晶体管的基极偏置电压变得不均衡的装置。还提供了适于防止所谓的冲击噪声出现在放大器电路的输出端的装置。这种装置可以通过使用延迟电路构成。

7. 发明授权

US5093426A Hydrogenated copolymer rubber, rubber composition comprising said rubber and rubber product obtained from the rubber 失效
标题翻译：加氢共聚物橡胶，橡胶组合物，包括从橡胶中获得的橡胶和橡胶产品
公开(公告)号：US5093426A
公开(公告)日：1992-03-03
申请号：US424085
申请日：1989-10-19
申请人： Nobuyuki Sakabe , Toshio Ohhara , Toshio Miyabayashi , Hiroshi Ise
发明人： Nobuyuki Sakabe , Toshio Ohhara , Toshio Miyabayashi , Hiroshi Ise
IPC分类号： C08C19/02 , C08F8/04
CPC分类号： C08C19/02 , C08F8/04
摘要： A hydrogenated copolymer rubber which is a hydrogenation product of a random copolymer rubber consisting of:(A) 30-70 mole % of a unit derived from at least one monomer selected from the group consisting of alkyl acrylates and alkoxy-substituted alkyl acrylates,(B) 20-70 mole % of a unit derived from at least one conjugated diene, and(C) 0-10 mole % of a unit derived from at least one other ethylenically unsaturated compound copolymerizable with the components (A) and (B) [(A)+(B)+(C)=100 mole %] wherein at least 90% of the double bonds of the conjugated diene unit is hydrogenated; a crosslinkable rubber composition comprising said hydrogenated copolymer rubber and a crosslinking agent; and a thermoplastic polymer comprising said hydrogenated copolymer rubber and a thermoplastic resin. These rubbers and compositions are superior in low-temperature resistance, heat resistance, ozone resistance, mechanical strengths, compression set, impact resilience and oil resistance.
摘要翻译：一种氢化共聚物橡胶，其是由以下组成的无规共聚物橡胶的氢化产物：（A）30-70摩尔％的源自至少一种选自丙烯酸烷基酯和烷氧基取代的丙烯酸烷基酯的单体的单元， B）20-70摩尔％的衍生自至少一种共轭二烯的单元，和（C）0-10摩尔％衍生自可与组分（A）和（B）共聚的至少一种其它烯属不饱和化合物的单元， [（A）+（B）+（C）= 100摩尔％]其中至少90％的共轭二烯单元的双键被氢化; 包含所述氢化共聚物橡胶和交联剂的可交联橡胶组合物; 和包含所述氢化共聚物橡胶和热塑性树脂的热塑性聚合物。这些橡胶和组合物的耐低温性，耐热性，耐臭氧性，机械强度，压缩永久变形，抗冲击性和耐油性都优异。

8. 发明授权

US4925907A Vinylidene fluoride-acrylic acid ester copolymer, process for producing the same and composition containing the same 失效
标题翻译：偏二氟乙烯 - 丙烯酸酯共聚物，其制造方法和含有它们的组合物
公开(公告)号：US4925907A
公开(公告)日：1990-05-15
申请号：US334568
申请日：1989-04-07
申请人： Toshio Miyabayashi , Nobuyuki Sakabe , Shinichiro Zen
发明人： Toshio Miyabayashi , Nobuyuki Sakabe , Shinichiro Zen
IPC分类号： C08F14/22 , C08F214/22 , C08F220/10 , C08F220/12
CPC分类号： C08F220/10 , C08F214/225
摘要： A substantially random, linear vinylidene fluoride-acrylic acid ester copolymer comprising:(A) 5-85% by weight of a vinylidene fluoride unit,(B) 15-95% by weight of at least one unit selected from the group consisting of an alkyl acrylate unit and an alkoxy-substituted alkyl acrylate unit, and(C) optionally 10% by weight or less, based on the total weight of (A), (B) and (C), of a crosslinking monomer unit, and having an intrinsic viscosity of 0.01-10 dl/g as measured at 30.degree. C. in N,N-dimethylformamide. Said copolymer has not only excellent heat resistance, ozone resistance and sour gasoline resistance but also excellent resistance to gasoline permeation.

9. 发明授权

US4675362A Multi-component copolymer rubber, a process for producing the same and a rubber composition containing the multi-component copolymer rubber 失效
标题翻译：多组分共聚物橡胶，其制备方法和含有多组分共聚物橡胶的橡胶组合物
公开(公告)号：US4675362A
公开(公告)日：1987-06-23
申请号：US847451
申请日：1986-04-03
申请人： Toshio Miyabayashi , Nobuyuki Sakabe , Yoshiyuki Udagawa , Hiroji Enyo , Yasuhiko Takemura
发明人： Toshio Miyabayashi , Nobuyuki Sakabe , Yoshiyuki Udagawa , Hiroji Enyo , Yasuhiko Takemura
IPC分类号： C08F220/12 , C08F220/34 , F02B75/02 , C08F20/34
CPC分类号： C08F220/34 , C08F220/12 , F02B2075/027
摘要： A multi-component copolymer rubber consisting essentially of (A) 20 to 69.5% by weight of a cyano-substituted alkyl (meth)acrylate, (B) 30 to 79.5% by weight of an alkyl acrylate, (C) 0.5 to 10% by weight of a crosslinkable monomer and (D) 0 to 10% by weight of other ethylenically unsaturated monomer copolymerizable with (A), (B) and (C), excels in heat resistance, ozone resistance, sour gasoline resistance and sour gasohol resistance. There properties of said multi-component copolymer rubber can further be improved by incorporating into the copolymer rubber a crosslinking agent, a metal salt, a vinylidene fluoride polymer, a vinyl chloride resin or other multi-component copolymer rubber.

10. 发明授权

US06639021B2 Composition of cyclic olefin addition copolymer and cross-linked material 失效
标题翻译：环烯烃加成共聚物和交联材料的组成
公开(公告)号：US06639021B2
公开(公告)日：2003-10-28
申请号：US09968529
申请日：2001-10-02
申请人： Noboru Oshima , Yooichiroh Maruyama , Nobuyuki Sakabe , Katsutoshi Sawada , Kenzo Ohkita , Yuuichi Hashiguchi , Tarou Kanamori , Kouji Kawahara
发明人： Noboru Oshima , Yooichiroh Maruyama , Nobuyuki Sakabe , Katsutoshi Sawada , Kenzo Ohkita , Yuuichi Hashiguchi , Tarou Kanamori , Kouji Kawahara
IPC分类号： C08L4500
CPC分类号： C08G61/08
摘要： A composition comprising a cyclic olefin addition copolymer containing recurring units of the following formulas (1) and (2), and at least one compound selected from (A) a compound acting as an acid when heated to 50° C. or higher, (B) a metal compound of an alkoxy compound, aryloxy compound, carboxyl compound, &bgr;-diketone compound, halogen compound, or oxide, (C) an organic carboxylic acid, organic phosphoric acid, organic sulfonic acid, ammonia, primary to tertiary amine compound, or quaternary ammonium hydroxide compound. The composition exhibits excellent optical transparency, solvent resistance, dimensional stability, heat resistance, and adhesion to metals and inorganic materials, and suitable for use in optical transparent materials and electronic material parts, to a cross-linked product obtained by crosslinking the composition via siloxane bonds, and to a film, sheet, or coating made from the composition.
摘要翻译：包含含有下式（1）和（2）的重复单元的环烯烃加成共聚物的组合物和至少一种选自（A）加热至50℃或更高的作为酸的化合物的化合物（ B）烷氧基化合物，芳氧基化合物，羧基化合物，β-二酮化合物，卤素化合物或氧化物的金属化合物，（C）有机羧酸，有机磷酸，有机磺酸，氨，伯至叔胺化合物，或季铵氢氧化物。该组合物对通过硅氧烷交联组合物获得的交联产物表现出优异的光学透明性，耐溶剂性，尺寸稳定性，耐热性和与金属和无机材料的粘合性，并且适用于光学透明材料和电子材料部件粘合，以及由该组合物制成的薄膜，薄片或涂层。

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