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    • 4. 发明授权
    • Mono-and Bis-acylphosphine oxide photoinitiator combinations
    • 单 - 和二 - 酰基氧化膦光引发剂组合
    • US06486228B2
    • 2002-11-26
    • US09820105
    • 2001-03-28
    • Manfred KöhlerJean-Pierre WolfAndré LitzlerGuido TolottiNils Hoeck
    • Manfred KöhlerJean-Pierre WolfAndré LitzlerGuido TolottiNils Hoeck
    • C08K322
    • C09D175/16B33Y70/00C07F9/3264C08F2/48C08F2/50C08F2222/1086C09D4/00
    • Photoinitiator combinations comprising at least one compound of formula (I)  wherein R1 is C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy or halogen; R3 is, for example, C1-C20alkyl, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl or biphenylyl or an O-, S- or N-containing 5- or 6-membered heterocyclic ring; and at least one compound of formula (II)  wherein R1 and R2 are as defined above; R9 is, for example, C1-C20alkyl, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl, biphenylyl or an O-, S- or N-containing 5- or 6-membered heterocyclic ring; and R10 is, for example, C1-C20alkyl, C2-C20alkyl interrupted by one or more O atoms, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl, biphenylyl or an O-, S- or N-containing 5- or 6-membered heterocyclic ring; are reactive photohardeners causing only a low degree of yellowing in the cured substrates.
    • 包含至少一种式(I)化合物的光引发剂组合,其中R 1是C 1 -C 4烷基,C 1 -C 4烷氧基或卤素; R2是氢,C1-C4烷基,C1-C4烷氧基或卤素; R 3是例如C 1 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基或联苯基或含O-,S-或N的5-或6-元杂环; 和至少一种式(II)的化合物,其中R 1和R 2如上所定义; R 9是例如C 1 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基,联苯基或含O-,S-或N的5-或6-元杂环; R 10为例如C 1 -C 20烷基,被一个或多个O原子间隔的C 2 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基,联苯基或含O-,S-或N的5-或6 杂环; 是在固化的基底中仅引起低度黄化的活性光固化剂。
    • 5. 发明授权
    • Photoinitiator combinations
    • 光引发剂组合
    • US06251963B1
    • 2001-06-26
    • US09453356
    • 1999-12-01
    • Manfred KöhlerJean-Pierre WolfAndré LitzlerGuido TolottiNils Hoeck
    • Manfred KöhlerJean-Pierre WolfAndré LitzlerGuido TolottiNils Hoeck
    • C08F246
    • C09D175/16B33Y70/00C07F9/3264C08F2/48C08F2/50C08F2222/1086C09D4/00
    • Photoinitiator combinations comprising at least one compound of formula (I) R1 is C1-C4alkyl, C1-C4alkoxy or halogen; R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy or halogen; R3 is, for example, C1-C20alkyl, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl or biphenylyl or an O—, S— or N-containing 5- or 6-membered heterocyclic ring; and at least one compound of formula (II) R1 and R2 are as defined above; R9 is, for example, C1-C20alkyl, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl, biphenylyl or an O—, S— or N-containing 5- or 6-membered heterocyclic ring; and R10 is, for example, C1-C20alkyl, C2-C20alkyl interrupted by one or more O atoms, cyclopentyl, cyclohexyl, phenyl-C1-C4alkyl, naphthyl, biphenylyl or an O—, S— or N-containing 5- or 6-membered heterocyclic ring; are reactive photo hardeners causing only a low degree of yellowing in the cured substrates.
    • 包含至少一种式(I)R 1的化合物的光引发剂组合是C 1 -C 4烷基,C 1 -C 4烷氧基或卤素; R 2是氢,C 1 -C 4烷基,C 1 -C 4烷氧基或卤素; R 3是例如C 1 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基或联苯基或O-,S-或N- 或6元杂环; 并且至少一种式(II)化合物R 1和R 2如上所定义; R 9是例如C 1 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基,联苯基或含O-,S-或N的5-或6-元杂环; R 10为例如C 1 -C 20烷基,被一个或多个O原子间隔的C 2 -C 20烷基,环戊基,环己基,苯基-C 1 -C 4烷基,萘基,联苯基或含O-,S-或N的5-或6 杂环; 是在固化的基底中仅引起低度黄化的活性光固化剂。