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    • 5. 发明申请
    • Sulfuric acid electrolysis process
    • 硫酸电解过程
    • US20090321272A1
    • 2009-12-31
    • US12459161
    • 2009-06-26
    • Masaaki KatoYusuke OgawaHiroki DomonNaoya HayamizuMakiko TangeYoshiaki KurokawaNobuo Kobayashi
    • Masaaki KatoYusuke OgawaHiroki DomonNaoya HayamizuMakiko TangeYoshiaki KurokawaNobuo Kobayashi
    • C25B15/00
    • C25B1/285
    • Sulfuric acid electrolysis process wherein; a temperature of electrolyte containing sulfuric acid to be supplied to an anode compartment and a cathode compartment is controlled to 30 degree Celsius or more; a flow rate F1 (L/min.) of the electrolyte containing sulfuric acid to be supplied to said anode compartment is controlled to 1.5 times or more (F1/Fa≧1.5) a flow rate Fa (L/min.) of gas formed on an anode side as calculated from Equation (1) shown below and a flow rate F2(L/min.) of said electrolyte containing sulfuric acid to be supplied to said cathode compartment is controlled to 1.5 times or more (F2/Fc≧1.5) a flow rate Fe (L/min.) of gas formed on a cathode side as calculated from Equation (2) shown below. Fa=(I×S×R×T)/(4×Faraday constant)   Equation (I) Fe=(I×S×R×T)/(2×Faraday constant)   Equation (2) I: Electrolytic current (A)S: Time: 60 second (Fixed)R: Gas constant (0.082 1·atm/K/mol)K: Absolute temperature (273.15 degree Celsius+T degree Celsius)T: Electrolysis temperature (degree Celsius)Faraday constant: (C/mol)
    • 硫酸电解法其中; 供给阳极室和阴极室的含有硫酸的电解质的温度控制在30摄氏度以上; 将供给到阳极室的含有硫酸的电解质的流量F1(L / min)控制为气体的流量Fa(L / min)的1.5倍以上(F1 / Fa> 1.5) 形成在阳极侧,由下述式(1)算出,将含有供给阴极室的硫酸的电解质的流量F2(L / min)控制在1.5倍以上(F2 / Fc> = 1.5)由下面所示的等式(2)计算的在阴极侧形成的气体的流速Fe(L / min)。 Fa =(IxSxRxT)/(4xFaraday常数)等式(I)Fe =(IxSxRxT)/(2xFaraday常数)等式(2)I:电解电流(A)S:时间:60秒(固定)R:气体常数(0.082 1.atm / K / mol)K:绝对温度(273.15摄氏度+ T摄氏度)T:电解温度(摄氏度)法拉第常数:(C / mol)