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1. 发明授权

US08692032B2 Methods of using tungsten carbide catalysts in preparation of ethylene glycol 有权
标题翻译：使用碳化钨催化剂制备乙二醇的方法
公开(公告)号：US08692032B2
公开(公告)日：2014-04-08
申请号：US13539041
申请日：2012-06-29
申请人： Tao Zhang , Na Ji , Mingyuan Zheng , Aiqin Wang , Yuying Shu , Xiaodong Wang , Jingguang Chen
发明人： Tao Zhang , Na Ji , Mingyuan Zheng , Aiqin Wang , Yuying Shu , Xiaodong Wang , Jingguang Chen
IPC分类号： C07C27/00 , C07C29/00
CPC分类号： B01J37/0201 , B01J21/18 , B01J23/6527 , B01J23/888 , B01J27/22 , B01J37/08 , C07C29/00 , Y02P20/52 , C07C31/202
摘要： Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy.
摘要翻译：通过氢化纤维素的降解，使用碳化钨催化剂制备乙二醇。催化剂包括碳化钨作为主要催化活性组分，添加少量一种或多种过渡金属如镍，钴，铁，钌，铑，钯，锇，铱，铂和铜作为第二金属，负载在用于将纤维素转化为乙二醇的一种或多种多孔复合物载体如活性炭，氧化铝，二氧化硅，二氧化钛，碳化硅，氧化锆。催化剂在120-300℃，氢气压力1-10MPa，水热条件下，纤维素向乙二醇的转化率高，效率高，选择性高，产率高。与现有的以乙烯为原料的乙二醇工业合成方法相比，本发明具有使用可再生原料资源，环保工艺，原子经济优良的优点。

2. 发明申请

US20120283487A1 METHODS OF USING TUNGSTEN CARBIDE CATALYSTS IN PREPARATION OF ETHYLENE GLYCOL 有权
标题翻译：使用碳纳米管催化剂制备乙二醇的方法
公开(公告)号：US20120283487A1
公开(公告)日：2012-11-08
申请号：US13539041
申请日：2012-06-29
申请人： Tao Zhang , Na JI , Mingyuan Zheng , Aiqin WANG , Yuying SHU , Xiaodong WANG , Jingguang CHEN
发明人： Tao Zhang , Na JI , Mingyuan Zheng , Aiqin WANG , Yuying SHU , Xiaodong WANG , Jingguang CHEN
IPC分类号： C07C29/132
CPC分类号： B01J37/0201 , B01J21/18 , B01J23/6527 , B01J23/888 , B01J27/22 , B01J37/08 , C07C29/00 , Y02P20/52 , C07C31/202
摘要： Tungsten carbide catalysts are used in preparation of ethylene glycol by hydrogenating degradation of cellulose. The catalyst includes tungsten carbide as main catalytic active component, added with small amount of one or more transition metals such as nickel, cobalt, iron, ruthenium, rhodium, palladium, osmium, iridium, platinum, and copper as the second metal, supported on one or more porous complex supports such as active carbon, alumina, silica, titanium dioxide, silicon carbide, zirconium oxide, for conversion of cellulose to ethylene glycol. The catalyst realizes high efficiency, high selectivity, and high yield in the conversion of cellulose to ethylene glycol at the temperature of 120-300° C., hydrogen pressure of 1-10 MPa, and hydrothermal conditions. Compared to the existing industrial synthetic method of ethylene glycol using ethylene as feedstock, the invention has the advantages of using renewable raw material resources, environment friendly process, and excellent atom economy.
摘要翻译：通过氢化纤维素的降解，使用碳化钨催化剂制备乙二醇。催化剂包括碳化钨作为主要催化活性组分，添加少量一种或多种过渡金属如镍，钴，铁，钌，铑，钯，锇，铱，铂和铜作为第二金属，负载在用于将纤维素转化为乙二醇的一种或多种多孔复合物载体如活性炭，氧化铝，二氧化硅，二氧化钛，碳化硅，氧化锆。催化剂在120-300℃，氢气压力1-10MPa，水热条件下，纤维素向乙二醇的转化率高，效率高，选择性高，产率高。与现有的以乙烯为原料的乙二醇工业合成方法相比，本发明具有使用可再生原料资源，环保工艺，原子经济优良的优点。

3. 发明申请

US20110046419A1 METHOD FOR PRODUCING ETHYLENE GLYCOL FROM POLYHYDROXY COMPOUND 有权
标题翻译：从聚羟基化合物生产乙烯甘油的方法
公开(公告)号：US20110046419A1
公开(公告)日：2011-02-24
申请号：US12916625
申请日：2010-10-31
申请人： Tao ZHANG , Mingyuan ZHENG , Aiqin WANG , Na JI , Jifeng PANG , Zhijun TAI , Likun ZHOU , Jingguang CHEN , Xiaodong WANG
发明人： Tao ZHANG , Mingyuan ZHENG , Aiqin WANG , Na JI , Jifeng PANG , Zhijun TAI , Likun ZHOU , Jingguang CHEN , Xiaodong WANG
IPC分类号： C07C29/00
CPC分类号： B01J23/6525 , B01J21/04 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/24 , B01J37/0205 , B01J37/18 , C07C29/00 , C07C29/132 , Y02P20/52 , C07C31/202 , C07C31/26
摘要： A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stiffing. The catalyst includes a first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof. The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300° C. for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
摘要翻译：一种生产乙二醇的方法，包括（a）在密封的高压反应器中加入多羟基化合物和水，（b）除去空气和引入氢，和（c）使多羟基化合物在催化剂存在下反应同时僵硬。催化剂包括第一活性成分和第二活性成分。第一活性成分包括选自铁，钴，镍，钌，铑，钯，铱和铂的第8,9或10族的过渡金属和/或它们的混合物。第二活性成分包括钼和/或钨的金属状态，或其碳化物，氮化物或磷化物。该方法在1-12MPa的氢气压力下，在120-300℃的温度下在一步催化反应中不少于5分钟进行。乙二醇的效率，选择性和产率高。制备过程简单，使用的材料是可再生的。

4. 发明申请

US20130181143A1 MICROSCOPY WITH ADAPTIVE OPTICS 有权
标题翻译：具有自适应光学的显微镜
公开(公告)号：US20130181143A1
公开(公告)日：2013-07-18
申请号：US13550250
申请日：2012-07-16
申请人： Eric Betzig , Na Ji
发明人： Eric Betzig , Na Ji
IPC分类号： G01N21/64
CPC分类号： G01N21/6458 , G02B21/0032 , G02B21/06 , G02B26/06
摘要： A method of manipulating a focused light beam includes focusing a beam of excitation light with a lens to a focal spot within a sample, where a cross-section of the beam includes individual beamlets. Directions and/or relative phases of the individual beamlets of the excitation beam at a rear pupil of the lens are individually varied with a wavefront modulating element, and emission light emitted from the focal spot is detected while the directions or relative phases of individual beamlets are varied. The directions of individual beamlets are controlled to either maximize or minimize the emission light from the focal spot, and the relative phases of individual beamlets are controlled to increase the emission light from the focal spot.
摘要翻译：操纵聚焦光束的方法包括将具有透镜的激发光束聚焦到样品内的焦点，其中束的横截面包括单个子束。在透镜的后瞳孔处的激发光束的各个子束的方向和/或相对相位分别随着波前调制元件而变化，并且从焦斑发射的发射光被检测到，而各个子束的方向或相对相位是多变。控制各个子束的方向以最大化或最小化来自焦点的发射光，并且控制各个子束的相对相位以增加来自焦点的发射光。

5. 发明申请

US20100256424A1 METHOD OF PREPARING ETHYLENE GLYCOL CELLULOSE 有权
标题翻译：制备乙二醇纤维素的方法
公开(公告)号：US20100256424A1
公开(公告)日：2010-10-07
申请号：US12734601
申请日：2008-10-31
申请人： Tao Zhang , Mingyuan Zheng , Na Ji , Aigin Wang , Yuying Shu , Hui Wang , Xiaodong Wang , Jingguang Chen
发明人： Tao Zhang , Mingyuan Zheng , Na Ji , Aigin Wang , Yuying Shu , Hui Wang , Xiaodong Wang , Jingguang Chen
IPC分类号： C07C29/00
CPC分类号： C07C29/00 , B01J21/063 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/25 , Y02P20/52 , C07C31/202
摘要： A method for preparing ethylene glycol from cellulose uses the cellulose as the feed for the reaction. The cellulose conversion is performed over catalysts which are composed of the metallic state, carbides, nitrides, or phosiphides of molybdenum or tungsten, and metallic cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum of the group 8, 9, or 10 transition metals. The catalytic conversion of cellulose is conducted at 120 to 300° C. and hydrogen pressure 1 to 12 MPa under the hydrothermal conditions to achieve the high efficiency, high selectivity, and high yield of ethylene glycol. Compared to the existing method of preparing ethylene glycol from ethylene, the method, using the renewable raw material for the reaction, is friendly to the environment, and has high atom economy.
摘要翻译：从纤维素制备乙二醇的方法使用纤维素作为反应的进料。纤维素转化在由金属状态，碳化物，氮化物或钼或钨的高温以及金属钴，镍，钌，铑，钯，铱和铂组成的催化剂上进行，第8,9或9族 10个过渡金属。在水热条件下，纤维素的催化转化率为120〜300℃，氢压为1〜12MPa，达到乙二醇的高效率，高选择性和高产率。与从乙烯制备乙二醇的现有方法相比，使用可再生原料进行反应的方法对环境友好，原子经济性好。

6. 发明授权

US08324433B2 Method for producing ethylene glycol from polyhydroxy compound 有权
标题翻译：从多羟基化合物制备乙二醇的方法
公开(公告)号：US08324433B2
公开(公告)日：2012-12-04
申请号：US12916625
申请日：2010-10-31
申请人： Tao Zhang , Mingyuan Zheng , Aiqin Wang , Na Ji , Jifeng Pang , Zhijun Tai , Likun Zhou , Jingguang Chen , Xiaodong Wang
发明人： Tao Zhang , Mingyuan Zheng , Aiqin Wang , Na Ji , Jifeng Pang , Zhijun Tai , Likun Zhou , Jingguang Chen , Xiaodong Wang
IPC分类号： C07C29/132 , C07C29/60
CPC分类号： B01J23/6525 , B01J21/04 , B01J21/06 , B01J21/063 , B01J21/08 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/24 , B01J37/0205 , B01J37/18 , C07C29/00 , C07C29/132 , Y02P20/52 , C07C31/202 , C07C31/26
摘要： A method for producing ethylene glycol, including (a) adding a polyhydroxy compound and water to a sealed high-pressure reactor, (b) removing air and introducing hydrogen, and (c) allowing the polyhydroxy compound to react in the presence of a catalyst while stiffing. The catalyst includes a first active ingredient and a second active ingredient. The first active ingredient includes a transition metal of Group 8, 9, or 10 selected from iron, cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum, and/or a mixture thereof. The second active ingredient includes a metallic state of molybdenum and/or tungsten, or a carbide, nitride, or phosphide thereof. The method is carried out at a hydrogen pressure of 1-12 MPa, at a temperature of 120-300° C. for not less than 5 min in a one-step catalytic reaction. The efficiency, selectivity, and the yield of ethylene glycol are high. The preparation process is simple and the materials used are renewable.
摘要翻译：一种生产乙二醇的方法，包括（a）在密封的高压反应器中加入多羟基化合物和水，（b）除去空气和引入氢，和（c）使多羟基化合物在催化剂存在下反应同时僵硬。催化剂包括第一活性成分和第二活性成分。第一活性成分包括选自铁，钴，镍，钌，铑，钯，铱和铂的第8,9或10族的过渡金属和/或它们的混合物。第二活性成分包括钼和/或钨的金属状态，或其碳化物，氮化物或磷化物。该方法在1-12MPa的氢气压力下，在120-300℃的温度下在一步催化反应中不少于5分钟进行。乙二醇的效率，选择性和产率高。制备过程简单，使用的材料是可再生的。

7. 发明授权

US08718106B2 Nonlinear imaging using passive pulse splitters 有权
标题翻译：使用无源脉冲分离器的非线性成像
公开(公告)号：US08718106B2
公开(公告)日：2014-05-06
申请号：US13099475
申请日：2011-05-03
申请人： Na Ji , Eric Betzig
发明人： Na Ji , Eric Betzig
IPC分类号： H01S3/10
CPC分类号： H01S3/0057 , G01N21/6408 , G01N21/6458 , G01N2021/653 , G01N2021/656 , H01S3/025 , H01S3/1625 , H01S3/1636
摘要： An apparatus includes a pulsed laser source that produces a pulsed laser beam at an input repetition rate and an input pulse power; a passive pulse splitter that receives the pulsed laser beam and outputs a signal including a plurality of sub-pulses for each input pulse of the pulsed laser beam, where the sub-pulses have a repetition rate that is greater than the input repetition rate and at least two of the sub-pulses have power less than the input pulse power; a sample accommodating structure configured to accommodate a sample placed in the path of a sample beam that is formed from the beam that exits the pulse splitter; and a detector that receives a signal of interest emitted from a sample accommodated by the sample accommodating structure based on the incident sample beam.
摘要翻译：一种装置包括脉冲激光源，其以输入重复频率和输入脉冲功率产生脉冲激光束; 被动脉冲分离器，其接收脉冲激光束并输出包括用于脉冲激光束的每个输入脉冲的多个子脉冲的信号，其中子脉冲具有大于输入重复频率的重复率，并且在至少两个子脉冲的功率小于输入脉冲功率; 样品容纳结构，其构造成容纳放置在由离开所述脉冲分离器的光束形成的样品光束的路径中的样品; 以及检测器，其基于所述入射样本光束接收从由所述样本容纳结构容纳的样本发射的感兴趣的信号。

8. 发明授权

US07960594B2 Method of preparing ethylene glycol from cellulose 有权
标题翻译：从纤维素制备乙二醇的方法
公开(公告)号：US07960594B2
公开(公告)日：2011-06-14
申请号：US12734601
申请日：2008-10-31
申请人： Tao Zhang , Mingyuan Zheng , Na Ji , Aigin Wang , Yuying Shu , Hui Wang , Xiaodong Wang , Jingguang Chen
发明人： Tao Zhang , Mingyuan Zheng , Na Ji , Aigin Wang , Yuying Shu , Hui Wang , Xiaodong Wang , Jingguang Chen
IPC分类号： C07C29/00
CPC分类号： C07C29/00 , B01J21/063 , B01J21/18 , B01J23/652 , B01J23/6527 , B01J23/85 , B01J23/888 , B01J27/19 , B01J27/22 , B01J27/25 , Y02P20/52 , C07C31/202
摘要： A method for preparing ethylene glycol from cellulose uses the cellulose as the feed for the reaction. The cellulose conversion is performed over catalysts which are composed of the metallic state, carbides, nitrides, or phosiphides of molybdenum or tungsten, and metallic cobalt, nickel, ruthenium, rhodium, palladium, iridium, and platinum of the group 8, 9, or 10 transition metals. The catalytic conversion of cellulose is conducted at 120 to 300° C. and hydrogen pressure 1 to 12 MPa under the hydrothermal conditions to achieve the high efficiency, high selectivity, and high yield of ethylene glycol. Compared to the existing method of preparing ethylene glycol from ethylene, the method, using the renewable raw material for the reaction, is friendly to the environment, and has high atom economy.
摘要翻译：从纤维素制备乙二醇的方法使用纤维素作为反应的进料。纤维素转化在由金属状态，碳化物，氮化物或钼或钨的高温以及金属钴，镍，钌，铑，钯，铱和铂组成的催化剂上进行，第8,9或9族 10个过渡金属。在水热条件下，纤维素的催化转化率为120〜300℃，氢压为1〜12MPa，达到乙二醇的高效率，高选择性和高产率。与从乙烯制备乙二醇的现有方法相比，使用可再生原料进行反应的方法对环境友好，原子经济性好。

9. 发明授权

US08730573B2 Adaptive optics microscopy with phase control of beamlets of a light beam 有权
标题翻译：具有光束子束相位控制的自适应光学显微镜
公开(公告)号：US08730573B2
公开(公告)日：2014-05-20
申请号：US12833767
申请日：2010-07-09
申请人： Eric Betzig , Na Ji
发明人： Eric Betzig , Na Ji
IPC分类号： G01D5/30 , G02B21/00
CPC分类号： G02B26/06 , G01J9/00 , G02B21/361
摘要： Microscopy techniques in which a rear pupil of an optical system is segmented and the segments are individually controlled with a wavefront modulating device to control the direction and phase of individual beamlets of an excitation or emission beam in the optical system, thereby providing an adaptive optics correction to sample and system induced aberrations.
摘要翻译：显微镜技术，其中光学系统的后光瞳被分割，并且段被波前调制装置单独控制，以控制光学系统中的激发或发射光束的各个子束的方向和相位，由此提供自适应光学校正样品和系统诱导的像差。

10. 发明授权

US08629413B2 Microscopy with adaptive optics 有权
标题翻译：显微镜与自适应光学
公开(公告)号：US08629413B2
公开(公告)日：2014-01-14
申请号：US13550250
申请日：2012-07-16
申请人： Eric Betzig , Na Ji
发明人： Eric Betzig , Na Ji
IPC分类号： G01N21/64
CPC分类号： G01N21/6458 , G02B21/0032 , G02B21/06 , G02B26/06
摘要： A method of manipulating a focused light beam includes focusing a beam of excitation light with a lens to a focal spot within a sample, where a cross-section of the beam includes individual beamlets. Directions and/or relative phases of the individual beamlets of the excitation beam at a rear pupil of the lens are individually varied with a wavefront modulating element, and emission light emitted from the focal spot is detected while the directions or relative phases of individual beamlets are varied. The directions of individual beamlets are controlled to either maximize or minimize the emission light from the focal spot, and the relative phases of individual beamlets are controlled to increase the emission light from the focal spot.
摘要翻译：操纵聚焦光束的方法包括将具有透镜的激发光束聚焦到样品内的焦点，其中束的横截面包括单个子束。在透镜的后瞳孔处的激发光束的各个子束的方向和/或相对相位分别随着波前调制元件而变化，并且从焦斑发射的发射光被检测到，而各个子束的方向或相对相位是多变。控制各个子束的方向以最大化或最小化来自焦点的发射光，并且控制各个子束的相对相位以增加来自焦点的发射光。

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