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    • 3. 发明申请
    • METHOD OF FABRICATING HIGH-EFFICIENCY Cu(In,Ga)(Se,S)2 THIN FILMS FOR SOLAR CELLS
    • 制造用于太阳能电池的高效Cu(In,Ga)(Se,S)2薄膜的方法
    • WO1996025768A1
    • 1996-08-22
    • PCT/US1995001923
    • 1995-02-16
    • MIDWEST RESEARCH INSTITUTENOUFI, RommelGABOR, Andrew, M.TUTTLE, John, R.TENNANT, Andrew, L.CONTRERAS, Miguel, A.ALBIN, David, S.CARAPELLA, Jeffrey, J.
    • MIDWEST RESEARCH INSTITUTE
    • H01L31/0296
    • H01L31/0322Y02E10/541Y02P70/521Y10S438/93
    • A process for producing a slightly Cu-poor thin film of Cu(In,Ga)(Se,S)2 comprises depositing a first layer (16) of (In,Ga)x(Se,S)y followed by depositing just enough Cu+(Se,S) or Cux(Se,S) to produce the desired slightly Cu-poor material layer (18). In variation, most, but not all, (about 90 % to 99 %) of the (In,Ga)x(Se,S)y layer (20) is deposited first, followed by deposition of all the Cu+(Se,S) or Cux(Se,S) layer (22) to go near stoichiometric, possibly or even preferably slightly Cu-rich, and then in turn followed by deposition of the remainder (about 1 % to 10 %) of the (In,Ga)x(Se,S)y layer (24) to end with a slightly Cu-poor composition. In yet another variation, a small portion (about 1 % to 10 %) of the (In,Ga)x(Se,S)y is first deposited as a seed layer (26), followed by deposition of all of the Cu+(Se,S) or Cux(Se,S) to make a very Cu-rich mixture layer (28), and then followed deposition of the remainder of the (In,Ga)x(Se,S)y layer (30) to go slightly Cu-poor in the final Cu(In,Ga)(Se,S)2 thin film.
    • 用于制造Cu(In,Ga)(Se,S)2的略微Cu不良薄膜的方法包括沉积(In,Ga)x(Se,S)y的第一层(16),然后沉积刚好 Cu +(Se,S)或Cux(Se,S)以产生所需的稍微不良铜的材料层(18)。 在变化中,首先沉积(In,Ga)x(Se,S)y层(20)的大部分但不是全部(约90%至99%),然后沉积所有Cu +(Se,S )或Cux(Se,S)层(22)接近化学计量,可能甚至优选略微富Cu,然后依次沉积(In,Ga)的余量(约1%至10%) )x(Se,S)y层(24)以稍微不合铜的组成结束。 在另一变型中,首先将(In,Ga)x(Se,S)y的一小部分(约1%至10%)沉积为籽晶层(26),然后沉积所有Cu + Se,S)或Cux(Se,S),以形成非常富Cu的混合层(28),然后将剩余的(In,Ga)x(Se,S)y层(30)沉积到 在最终的Cu(In,Ga)(Se,S)2薄膜中略微Cu-poor。
    • 5. 发明申请
    • THIN-FILM SOLAR CELL FABRICATED ON A FLEXIBLE METALLIC SUBSTRATE
    • 薄膜太阳能电池组合在柔性金属基底上
    • WO2003007386A1
    • 2003-01-23
    • PCT/US2001/022192
    • 2001-07-13
    • MIDWEST RESEARCH INSTITUTETUTTLE, John, R.NOUFI, RommelHASOON, Falah, S.
    • TUTTLE, John, R.NOUFI, RommelHASOON, Falah, S.
    • H01L31/0336
    • H01L31/0749H01L31/02008H01L31/0392H01L31/03928Y02E10/541Y02P70/521
    • A thin-film solar cell (10) is provided. The thin-film solar cell (10) comprises a flexible metallic substrate (12) having a first surface and a second surface. A back metal contact layer (16) is deposited on the first surface of the flexible metallic substrate (12). A semiconductor absorber layer (14) is deposited on the back metal contact. A photoactive film deposited on the semiconductor absorber layer (14) forms a heterojunction structure and a grid contact (24) deposited on the heterjunction structure. The flexible metal substrate (12) can be constructed of either aluminium or stainless steel. Furthermore, a method of constructing a solar cell is provided. The method comprises providing an aluminum substrate (12), depositing a semiconductor absorber layer (14) on the aluminum substrate (12), and insulating the aluminum substrate (12) from the semiconductor absorber layer (14) to inhibit reaction between the aluminum substrate (12) and the semiconductor absorber layer (14).
    • 提供薄膜太阳能电池(10)。 薄膜太阳能电池(10)包括具有第一表面和第二表面的柔性金属基底(12)。 在柔性金属基板(12)的第一表面上沉积背金属接触层(16)。 半导体吸收层(14)沉积在背面金属触点上。 沉积在半导体吸收层(14)上的光活性膜形成异相结构和沉积在异质结结构上的栅极接触(24)。 柔性金属基底(12)可由铝或不锈钢构成。 此外,提供了构造太阳能电池的方法。 该方法包括提供铝基板(12),在铝基板(12)上沉积半导体吸收层(14),并将铝基板(12)与半导体吸收层(14)绝缘,以抑制铝基板 (12)和半导体吸收层(14)。