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1. 发明申请

WO2010079057A1 MULTI STAGE PROCESS FOR PRODUCING HYDROCARBONS FROM SYNGAS 审中-公开
标题翻译：从SYNGAS生产石油烃的多阶段工艺
公开(公告)号：WO2010079057A1
公开(公告)日：2010-07-15
申请号：PCT/EP2009/067245
申请日：2009-12-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BRACHT, Maarten , HESSELINK, Maarten , NIJST, Christiaan , REMANS, Thomas Joris
发明人： BRACHT, Maarten , HESSELINK, Maarten , NIJST, Christiaan , REMANS, Thomas Joris
IPC分类号： C10G2/00
CPC分类号： C10G2/30 , C10K3/06
摘要： The invention pertains to a multi-stage process for the production of hydrocarbons from syngas comprising hydrogen and carbon monoxide, which comprises the steps of : a) providing a fresh syngas feed to a first stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products at a temperature in the range from 125 to 400°C and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h; b) feeding the effluent from the first stage reactor to a separation unit; c) removing a gasous effluent stream comprising hydrogen and CO from the separation unit; d) removing one or more other streams comprising hydrocarbon and/or water from the separation unit; e) conveying a first portion of the gaseous effluent stream to a second stage Fischer-Tropsch reactor and allowing CO and hydrogen to convert into hydrocarbon products in the second stage Fischer-Tropsch reactor at a temperature in the range from 125 to 400°C and a pressure in the range from 5 to 150 bar absolute, and a gaseous hourly space velocity in the range from 500 to 10000 Nl/l/h, whereby the first stage Fischer-Tropsch reactor and the second stage Fischer-Tropsch reactor are separate reactors; f) feeding the effluent from the second stage Fischer- Tropsch reactor to the separation unit; g) removing a second portion of the gaseous effluent stream as off-gas.
摘要翻译：本发明涉及用于从包含氢气和一氧化碳的合成气生产碳氢化合物的多级方法，其包括以下步骤：a）向新的第一阶段费 - 托反应器提供新的合成气进料并允许CO和氢转化在125至400℃的温度和5至150巴绝对压力范围内的气体产物中，并且气时空速在500至10000Nl / l / h的范围内; b）将来自第一级反应器的流出物供给到分离单元; c）从分离单元中除去包含氢和CO的气体流出物流; d）从分离单元去除包含烃和/或水的一种或多种其它流; e）将第一部分气态流出物流输送到第二级费 - 托反应器，并允许CO和氢在第二级费 - 托反应器中在125-400℃的温度范围内转化成烃产物，以及 5至150巴绝对压力和500至10000Nl / l / h范围内的气时空速，其中第一级费 - 托反应器和第二级费 - 托反应器是分离的反应器 ; f）将来自第二级费 - 托反应器的流出物供给到分离单元; g）除去作为废气的气态流出物流的第二部分。

2. 发明申请

WO2008144514A3 POLYOL-BASED POLYMERS 审中-公开
标题翻译：基于聚合物的聚合物
公开(公告)号：WO2008144514A3
公开(公告)日：2009-03-12
申请号：PCT/US2008063900
申请日：2008-05-16
申请人： MASSACHUSETTS INST TECHNOLOGY , GEN HOSPITAL CORP , BRUGGEMAN JOOST P , NIJST CHRISTIAAN , KOHANE DANIEL S , LANGER ROBERT S
发明人： BRUGGEMAN JOOST P , NIJST CHRISTIAAN , KOHANE DANIEL S , LANGER ROBERT S
IPC分类号： C08G63/21 , C08G63/668
CPC分类号： C08G63/668 , A61L27/16 , A61L27/38 , A61L27/52 , A61L27/54 , A61L27/58 , A61L2300/604 , C08G63/21 , C08L33/02
摘要： The present invention provides inventive polyol-based polymers, materials, pharmaceutical compositions, and methods of making and using the inventive polymers and materials. In certain aspects of the invention, an inventive polymer corresponds to a polymer depicted below. Exemplary inventive polymers includes those prepared using polyol units (e.g., xylitol, mannitol, sorbitol, or maltitol) condensed with polycarboxylic acid units (e.g., citric acid, glutaric acid, or sebacic acid). The inventive polymers may be further derivatized or modified. For example, the polymer may be made photocrosslinkable by adding methacrylate moieties to the polymer.
摘要翻译：本发明提供本发明的多元醇基聚合物，材料，药物组合物以及制备和使用本发明的聚合物和材料的方法。在本发明的某些方面，本发明的聚合物对应于下面描述的聚合物。示例性的本发明聚合物包括使用与多元羧酸单元（例如柠檬酸，戊二酸或癸二酸）缩合的多元醇单元（例如木糖醇，甘露糖醇，山梨糖醇或麦芽糖醇）制备的那些聚合物。本发明的聚合物可进一步衍生或修饰。例如，可以通过向聚合物中加入甲基丙烯酸酯部分使聚合物可光交联。

3. 发明申请

WO2007082304A3 BIODEGRADABLE ELASTOMERS 审中-公开
公开(公告)号：WO2007082304A3
公开(公告)日：2007-07-19
申请号：PCT/US2007/060529
申请日：2007-01-12
申请人： MASSACHUSETTS INSTITUTE OF TECHNOLOGY , BETTINGER, Christopher, J. , KARP, Jeffrey , KIM, Sonia, J. , LANGER, Robert, S. , ZUMBUEHL, Andreas , BRUGGEMAN, Joost, P. , DA SILVA-FERREIRA, Lino , NIJST, Christiaan , BURDICK, Jason
发明人： BETTINGER, Christopher, J. , KARP, Jeffrey , KIM, Sonia, J. , LANGER, Robert, S. , ZUMBUEHL, Andreas , BRUGGEMAN, Joost, P. , DA SILVA-FERREIRA, Lino , NIJST, Christiaan , BURDICK, Jason
IPC分类号： C08F220/06 , C08L31/00
摘要： The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a prepolymer.. which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polyrøer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.

4. 发明申请

WO2008144514A2 POLYOL-BASED POLYMERS 审中-公开
标题翻译：基于聚合物的聚合物
公开(公告)号：WO2008144514A2
公开(公告)日：2008-11-27
申请号：PCT/US2008/063900
申请日：2008-05-16
申请人： MASSACHUSETTS INSTITUTE OF TECHNOLOGY , BRUGGEMAN, Joost, P. , NIJST, Christiaan , KOHANE, Daniel, S. , LANGER, Robert, S.
发明人： BRUGGEMAN, Joost, P. , NIJST, Christiaan , KOHANE, Daniel, S. , LANGER, Robert, S.
CPC分类号： C08G63/668 , A61L27/16 , A61L27/38 , A61L27/52 , A61L27/54 , A61L27/58 , A61L2300/604 , C08G63/21 , C08L33/02
摘要： The present invention provides inventive polyol-based polymers, materials, pharmaceutical compositions, and methods of making and using the inventive polymers and materials. In certain aspects of the invention, an inventive polymer corresponds to a polymer depicted below. Exemplary inventive polymers includes those prepared using polyol units (e.g., xylitol, mannitol, sorbitol, or maltitol) condensed with polycarboxylic acid units (e.g., citric acid, glutaric acid, or sebacic acid). The inventive polymers may be further derivatized or modified. For example, the polymer may be made photocrosslinkable by adding methacrylate moieties to the polymer.
摘要翻译：本发明提供本发明的多元醇基聚合物，材料，药物组合物以及制备和使用本发明的聚合物和材料的方法。在本发明的某些方面，本发明的聚合物对应于下面描述的聚合物。示例性的本发明聚合物包括使用与多元羧酸单元（例如柠檬酸，戊二酸或癸二酸）缩合的多元醇单元（例如，木糖醇，甘露糖醇，山梨糖醇或麦芽糖醇）制备的那些聚合物。本发明的聚合物可进一步衍生或修饰。例如，可以通过向聚合物中加入甲基丙烯酸酯部分使聚合物可光交联。

5. 发明申请

WO2007082305A2 BIODEGRADABLE ELASTOMERS 审中-公开
标题翻译：生物可降解弹性体
公开(公告)号：WO2007082305A2
公开(公告)日：2007-07-19
申请号：PCT/US2007060532
申请日：2007-01-12
申请人： MASSACHUSETTS INST TECHNOLOGY , BETTINGER CHRISTOPHER J , KARP JEFFREY , KIM SONIA J , LANGER ROBERT S , ZUMBUEHL ANDREAS , BRUGGEMAN JOOST P , DA SILVA-FERREIRA LINO , NIJST CHRISTIAAN , BURDICK JASON
发明人： BETTINGER CHRISTOPHER J , KARP JEFFREY , KIM SONIA J , LANGER ROBERT S , ZUMBUEHL ANDREAS , BRUGGEMAN JOOST P , DA SILVA-FERREIRA LINO , NIJST CHRISTIAAN , BURDICK JASON
IPC分类号： C08G63/46
CPC分类号： A61L31/06 , A61K35/12 , A61K35/48 , A61K45/06 , A61L27/18 , A61L27/38 , A61L27/58 , A61L31/148 , C08G63/6854 , C08J3/24 , C08J3/246 , C08J2367/00 , C08J2367/07 , C08K5/0025 , C12N11/08 , C08L67/00 , C08L67/07
摘要： The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a pre-polymer, which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polymer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.
摘要翻译：本发明在各方面提供弹性可生物降解的聚合物。在各种实施方案中，聚合物通过多官能醇或醚和双官能或更高级酸的反应形成以形成预聚物，其被交联以形成弹性可生物降解的聚合物。在优选的实施方案中，通过用乙烯基官能化预聚物主链上的一个或多个OR基团进行交联，然后进行光聚合以形成弹性可生物降解的聚合物组合物或材料。优选地，使用丙烯酸酯将一种或多种乙烯基加成到预聚物的主链上以形成丙烯酸酯化的预聚物。在各种实施方案中，丙烯酸酯化的预聚物与一种或多种丙烯酸酯化共聚物共聚。

6. 发明申请

WO2010089342A1 PROCESS TO CONVERT BIOMASS 审中-公开
标题翻译：处理生物量的过程
公开(公告)号：WO2010089342A1
公开(公告)日：2010-08-12
申请号：PCT/EP2010/051343
申请日：2010-02-04
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BOERRIGTER, Harold , NIJST, Christiaan , VAN PAASEN, Sander , VENDERBOSCH, Robertus Hendrikus
发明人： BOERRIGTER, Harold , NIJST, Christiaan , VAN PAASEN, Sander , VENDERBOSCH, Robertus Hendrikus
IPC分类号： F26B3/28 , F26B9/10 , C10L5/44
CPC分类号： F26B9/10 , C10B53/02 , C10J3/466 , C10J2300/0903 , C10J2300/0916 , C10J2300/0926 , C10J2300/1659 , C10J2300/1665 , C10L5/361 , C10L5/363 , C10L5/44 , C10L9/083 , F26B3/286 , Y02B40/74 , Y02E50/10 , Y02E50/14 , Y02E50/15 , Y02E50/18 , Y02E50/30 , Y02P20/129
摘要： The invention is directed to a process to prepare a fuel or an intermediate to a fuel from residues as obtained in a palm oil process wherein shredded agricultural residue having a water content of between 40 and 75 wt% water is dried to obtain a dried agricultural residue having a water content of between 5 and 40 wt% and then is compacted into pellets, cubes, or small briquettes having a two dimensional size of between 5 and 1000 mm and a thickness of between 5 and 300 mm and a density of between 200 and 1200 kg/m 3 .
摘要翻译：本发明涉及一种从棕榈油工艺中获得的残留物制备燃料或燃料中间体的方法，其中干燥含水量为40至75重量％的水的切碎的农业残余物以获得干燥的农业残留物具有5至40重量％的含水量，然后压实成具有5至1000mm的二维尺寸和5至300mm之间的密度在200和200之间的颗粒，立方体或小团块 1200 kg / m3。

7. 发明申请

WO2007082305A3 BIODEGRADABLE ELASTOMERS 审中-公开
公开(公告)号：WO2007082305A3
公开(公告)日：2007-07-19
申请号：PCT/US2007/060532
申请日：2007-01-12
申请人： MASSACHUSETTS INSTITUTE OF TECHNOLOGY , BETTINGER, Christopher, J. , KARP, Jeffrey , KIM, Sonia, J. , LANGER, Robert, S. , ZUMBUEHL, Andreas , BRUGGEMAN, Joost, P. , DA SILVA-FERREIRA, Lino , NIJST, Christiaan , BURDICK, Jason
发明人： BETTINGER, Christopher, J. , KARP, Jeffrey , KIM, Sonia, J. , LANGER, Robert, S. , ZUMBUEHL, Andreas , BRUGGEMAN, Joost, P. , DA SILVA-FERREIRA, Lino , NIJST, Christiaan , BURDICK, Jason
IPC分类号： A61F2/00
摘要： The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a pre-polymer, which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polymer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.

8. 发明申请

WO2007082304A2 BIODEGRADABLE ELASTOMERS 审中-公开
标题翻译：生物可降解弹性体
公开(公告)号：WO2007082304A2
公开(公告)日：2007-07-19
申请号：PCT/US2007060529
申请日：2007-01-12
申请人： MASSACHUSETTS INST TECHNOLOGY , BETTINGER CHRISTOPHER J , KARP JEFFREY , KIM SONIA J , LANGER ROBERT S , ZUMBUEHL ANDREAS , BRUGGEMAN JOOST P , DA SILVA-FERREIRA LINO , NIJST CHRISTIAAN , BURDICK JASON
发明人： BETTINGER CHRISTOPHER J , KARP JEFFREY , KIM SONIA J , LANGER ROBERT S , ZUMBUEHL ANDREAS , BRUGGEMAN JOOST P , DA SILVA-FERREIRA LINO , NIJST CHRISTIAAN , BURDICK JASON
IPC分类号： C08G63/46
CPC分类号： A61L31/06 , A61K35/12 , A61K35/48 , A61K45/06 , A61L27/18 , A61L27/38 , A61L27/58 , A61L31/148 , C08G63/6854 , C08J3/24 , C08J3/246 , C08J2367/00 , C08J2367/07 , C08K5/0025 , C12N11/08 , C08L67/00 , C08L67/07
摘要： The present inventions in various aspects provide elastic biodegradable polymers. In various embodiments, the polymers are formed by the reaction of a multifunctional alcohol or ether and a difunctional or higher order acid to form a prepolymer.. which is cross-linked to form the elastic biodegradable polymer. In preferred embodiments, the cross-linking is performed by functionalization of one or more OR groups on the pre-polymer backbone with vinyl, followed by photopolymerization to form the elastic biodegradable polymer composition or material. Preferably, acrylate is used to add one or more vinyls to the backbone of the pre-polymer to form an acrylated pre-polyrøer. In various embodiments, acrylated pre-polymers are co-polymerized with one or more acrylated co-polymers.
摘要翻译：本发明在各个方面提供弹性生物可降解聚合物。在各种实施方案中，聚合物通过多官能醇或醚与双官能或更高级酸反应形成预聚物而形成，所述预聚物交联形成弹性生物可降解聚合物。在优选的实施方案中，通过用乙烯基使预聚物骨架上的一个或多个OR基团官能化，然后光聚合形成弹性可生物降解的聚合物组合物或材料来进行交联。优选地，使用丙烯酸酯将一种或多种乙烯基添加到预聚物的骨架中以形成丙烯酸酯化预聚合物。在各种实施方案中，丙烯酸酯化预聚物与一种或多种丙烯酸酯化共聚物共聚。

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