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    • 6. 发明申请
    • PROCESS AND REACTOR FOR THE PRODUCTION OF HYDROGEN AND CARBON DIOXIDE AND A FUEL CELL SYSTEM
    • 生产二氧化碳和二氧化碳和燃料电池系统的过程和反应器
    • WO2008000782A2
    • 2008-01-03
    • PCT/EP2007/056453
    • 2007-06-28
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.ASSINK, Gerrit Jan BarendKRAMER, Gert JanNIJMEIJER, ArianVAN SINT ANNALAND, Martin
    • ASSINK, Gerrit Jan BarendKRAMER, Gert JanNIJMEIJER, ArianVAN SINT ANNALAND, Martin
    • C01B32/50
    • C01B3/501B01D63/06B01D2315/08B01J8/009B01J8/18C01B3/384C01B32/50C01B2203/0233C01B2203/041C01B2203/0475
    • The invention relates to a process for the production of hydrogen and carbon dioxide from a hydrocarbonaceous feedstock, comprising: a) supplying a gaseous hydrocarbonaceous feedstock and steam to a reaction zone comprising a steam reforming catalyst and catalytically reforming the hydrocarbonaceous feedstock to produce a reformed gas comprising hydrogen and carbon dioxide; b) supplying a molecular oxygen-comprising gas to the permeate side of a first hydrogen separation membrane; c) contacting a part of the hydrogen with a first hydrogen separation membrane, allowing the hydrogen to permeate through the first hydrogen separation membrane and combusting the hydrogen with the molecular oxygen at a permeate side of the first hydrogen separation membrane to produce all heat necessary for catalytic reforming the hydrocarbonaceous feedstock; d) contacting the remainder of the hydrogen with a second hydrogen separation membrane, which is separate from the first hydrogen separation membrane, and allowing the hydrogen to permeate through the second hydrogen separation membrane to obtain a first effluent comprising a substantially pure stream of hydrogen; and e) removing a stream rich in carbon dioxide from the reaction zone as a second effluent. The invention further related to a reactor for such process and to a fuel cell system comprising in series such reactor and a fuel cell.
    • 本发明涉及一种用于从烃原料生产氢气和二氧化碳的方法,包括:a)将气态含烃原料和蒸汽供应到包含蒸汽重整催化剂的反应区,并催化重整含烃原料以产生重整气体 包括氢和二氧化碳; b)向第一氢分离膜的渗透侧供应含分子氧的气体; c)使一部分氢与第一氢分离膜接触,允许氢穿过第一氢分离膜并在第一氢分离膜的渗透侧将氢与分子氧一起燃烧以产生所需的全部热量 催化重整含烃原料; d)使氢的剩余部分与第二氢分离膜分开,第二氢分离膜与第一氢分离膜分离,并允许氢渗透通过第二氢分离膜以获得包含基本上纯的氢气流的第一流出物; 和e)作为第二流出物从反应区除去富含二氧化碳的物流。 本发明还涉及用于这种方法的反应器和一种包括串联的这种反应器和燃料电池的燃料电池系统。