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1. 发明申请

WO2007068732A1 CATALYST BODIES FOR USE IN FISCHER-TROPSCH REACTIONS 审中-公开
标题翻译：催化剂在FISCHER-TROPSCH反应中的使用
公开(公告)号：WO2007068732A1
公开(公告)日：2007-06-21
申请号：PCT/EP2006/069695
申请日：2006-12-14
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , ROUTIER, Arold Marcel Albert , SCHRAUWEN, Franciscus Johannes Maria , NIESEN, Gerardus Petrus Lambertus
发明人： ROUTIER, Arold Marcel Albert , SCHRAUWEN, Franciscus Johannes Maria , NIESEN, Gerardus Petrus Lambertus
IPC分类号： C07C1/04 , C10G2/00 , B01J35/04
CPC分类号： B01J35/023 , B01J8/22 , B01J19/2485 , B01J23/462 , B01J23/745 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J23/89 , B01J35/008 , B01J35/04 , B01J35/10 , B01J37/0221 , B01J2208/00672 , C07C1/0425 , C10G2/342
摘要： The invention relates to a catalyst body comprising a Fischer-Tropsch catalyst or catalyst precursor and a porous body, said porous body being between 1-50 mm, preferably 1-30 mm in size, the catalyst body having an internal voidage between 50-95%. The invention further relates to a process comprising the steps of : (i) introducing the synthesis gas into the reactor; and (ii) contacting the synthesis gas with a non-stationary catalyst to catalytically convert the synthesis gas at an elevated temperature to obtain the normally gaseous, normally liquid, and optionally normally solid hydrocarbons from synthesis gas; wherein the catalyst of step (ii) is located on a plurality of porous bodies being 1-50 mm in size, preferably 1-30 mm in size, thus forming catalyst bodies, and wherein said catalyst bodies have an external voidage in situ in the reactor between 5-60%, and a porosity within the catalyst bodies between 50-95%. Use of catalyst bodies according to the invention provides an advantageous intermediate balance whereby such catalyst bodies are significantly easier (and therefore less costly) to separate from the products of the slurry reactor, but they are still able to be supported by the slurry, and are therefore still movable within the reactor vessel so as to seek the most even catalytic transfer and heat transfer, but without being fixed.
摘要翻译：本发明涉及包含费 - 托催化剂或催化剂前体和多孔体的催化剂体，所述多孔体的尺寸为1-50mm，优选为1-30mm，催化剂体的内部空隙率在50-95 ％。本发明还涉及一种方法，其包括以下步骤：（i）将合成气引入反应器; 和（ii）使合成气与非固定催化剂接触以在升高的温度下催化转化合成气，以从合成气中获得通常为气态的，通常为液体的和任选的通常为固体的烃; 其中步骤（ii）的催化剂位于多个多孔体上，尺寸为1-50mm，优选为1-30mm，从而形成催化剂体，并且其中所述催化剂体在反应器在5-60％之间，催化剂体内的孔隙率在50-95％之间。根据本发明的催化剂体的使用提供了有利的中间平衡，其中这样的催化剂体与浆料反应器的产物分离显着更容易（因此成本更低），但它们仍然能够被浆料支撑，并且是因此仍然可以在反应堆容器内移动，以便寻求最均匀的催化转移和热传递，但不固定。

2. 发明申请

WO2008006786A2 PROCESS FOR HYDROCARBON SYNTHESIS 审中-公开
标题翻译：烃合成方法
公开(公告)号：WO2008006786A2
公开(公告)日：2008-01-17
申请号：PCT/EP2007/056926
申请日：2007-07-09
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CHETTOUF, Abderrahmane , NIESEN, Gerardus Petrus Lambertus , REYNHOUT, Marinus Johannes , SCHADDENHORST, David
发明人： CHETTOUF, Abderrahmane , NIESEN, Gerardus Petrus Lambertus , REYNHOUT, Marinus Johannes , SCHADDENHORST, David
CPC分类号： B01J21/063 , B01J21/06 , B01J23/8892 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J37/0225 , B01J37/0228 , B01J37/0244 , B01J37/0248 , B01J37/08 , C10G2/33
摘要： A method of supporting a hydrocarbon synthesis catalyst material comprising a catalytically active metal and a carrier material on a substrate comprising the steps of: (a) applying the catalyst material to the substrate; and (b) heating the catalyst material to form a catalyst material layer fixed to the substrate, characterised in that - the catalyst carrier is a porous inorganic refractory oxide or precursor therefor; - the catalyst material applied in step (a) comprises 60 to 90 weight% solvent calculated on the total weight of the catalyst material layer; - when the catalyst material is subjected to the heating step (b) it comprises at most 10 weight% of solvent, calculated on the total weight of the catalyst material layer; - in heating step (b) the catalyst material is heated to a temperature in the range between 250°C and 800°C; - cracks having sub-millimetre widths are uniformly formed in the layer; - after step (b) the catalyst material layer has a thickness of 5-200 microns. The control of cracking of the catalyst material on the substrate, especially the presence of cracks at regular distances such that there is no continuous catalyst layer on the substrate surface, reduces any stress build-up.
摘要翻译：一种在基材上含有催化活性金属和载体材料的烃合成催化剂材料的方法，包括以下步骤：（a）将催化剂材料施加到基材上; 和（b）加热所述催化剂材料以形成固定在所述基材上的催化剂材料层，其特征在于，所述催化剂载体是多孔无机难熔氧化物或其前体; - 步骤（a）中应用的催化剂材料包含按催化剂材料层的总重量计算的60至90重量％的溶剂; - 当催化剂材料经受加热步骤（b）时，其包含至多10重量％的溶剂，以催化剂材料层的总重计算; - 在加热步骤（b）中，将催化剂材料加热到250℃和800℃之间的温度; - 在该层中均匀地形成具有亚毫米宽度的裂纹; - 步骤（b）之后，催化剂材料层的厚度为5-200微米。控制基板上的催化剂材料的裂纹，特别是在规则距离处存在裂纹，使得在基板表面上不存在连续的催化剂层，减少了任何应力积聚。

3. 发明申请

WO2004041430A1 ELONGATED SHAPED PARTICLES; USE AS A CATALYST OR SUPPORT THEREOF 审中-公开
标题翻译：长方形颗粒; 用作催化剂或其支持
公开(公告)号：WO2004041430A1
公开(公告)日：2004-05-21
申请号：PCT/EP2003/050786
申请日：2003-11-03
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , KLAVER, Hilbrand , MESTERS, Carolus, Matthias, Anna, Maria , NIESEN, Gerardus, Petrus, Lambertus , VERBIST, Guy, Lode, Magda, Maria
发明人： KLAVER, Hilbrand , MESTERS, Carolus, Matthias, Anna, Maria , NIESEN, Gerardus, Petrus, Lambertus , VERBIST, Guy, Lode, Magda, Maria
IPC分类号： B01J35/02
CPC分类号： C10G49/04 , B01J21/06 , B01J21/063 , B01J23/74 , B01J23/8892 , B01J32/00 , B01J35/026 , B01J37/0009 , C10G2/32 , C10G2/332
摘要： Elongated shaped particle comprising two protrusions each extending from and attached to a central position, wherein the central position is aligned along the longitudinal axis of the particle, the cross-section of the particle occupying the space encompassed by the outer edges of six circles around a central circle, each of the six circles touching two neighboring circles whilst two alternating circles are equidistant to the central circle and may be attached to the central circle, and the two circles adjacent to the two alternating circles (but not the common circle) touching the central circle, minus the space occupied by the four remaining outer circles and including four remaining interstitial regions.
摘要翻译：细长形状的颗粒包括从中心位置延伸并连接到中心位置的两个突起，其中中心位置沿着颗粒的纵向轴线排列，颗粒的横截面占据由六个圆的外边缘包围的空间中心圆，六个圆中的每一个接触两个相邻的圆，而两个交替的圆与中心圆等距，并且可以附接到中心圆，并且与两个交替的圆（但不是共同的圆）相邻的两个圆接触中心圆，减去四个剩余外圆所占据的空间，并包括四个剩余的间隙区域。

4. 发明申请

WO2011073237A1 PROCESS FOR PREPARING A CATALYST SUBSTRATE FROM NON-WOVEN FIBERS 审中-公开
标题翻译：从非织造纤维制备催化底物的方法
公开(公告)号：WO2011073237A1
公开(公告)日：2011-06-23
申请号：PCT/EP2010/069716
申请日：2010-12-15
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DEKKER, Desmond Marinus Cornelis , NIESEN, Gerardus Petrus Lambertus , VLAAR, Daan
发明人： DEKKER, Desmond Marinus Cornelis , NIESEN, Gerardus Petrus Lambertus , VLAAR, Daan
IPC分类号： B01J23/75 , B01J35/06 , B01J37/02 , C07C1/04 , C10G2/00
CPC分类号： B01J35/06 , B01J23/75 , B01J35/023 , B01J35/04 , B01J35/1004 , B01J35/1033 , B01J37/0009 , B01J37/0225
摘要： The invention relates to a process for manufacturing a catalyst substrate which is a shaped porous structure, said process comprising the steps of providing non-woven fibers with an average length in the range of 4-50 mm, an average diameter in the range of 5-300 microns, and a length over diameter ratio in the range of 50 to 500 into a mould to form a fibrous aggregate with volume (V), and compressing the fibrous aggregate to form a porous structure. The compression is carried out in such a manner that the volume of the fibrous aggregate in compressed state (V compressed ) is at most 90% of the volume (V) of the fibrous aggregate before compression. The invention further relates to the catalyst substrate prepared and to a catalyst and use of a catalyst comprising the catalyst substrate.
摘要翻译：本发明涉及一种用于制造成形多孔结构的催化剂基材的方法，所述方法包括以下步骤：提供平均长度在4-50mm范围内的平均直径为5至5mm的非织造纤维 -300微米，并且将长度超过直径的比率在50至500范围内变成模具以形成具有体积（V）的纤维聚集体，并且压缩纤维聚集体以形成多孔结构。以压缩状态（V压缩）的纤维聚集体的体积为压缩前的纤维集合体体积（V）的90％以下的方式进行压缩。本发明还涉及制备的催化剂底物和催化剂以及使用包含催化剂底物的催化剂。

5. 发明申请

WO2006048421A1 ATTRITION RESISTANT PARTICULATE CATALYST 审中-公开
标题翻译：耐腐蚀颗粒催化剂
公开(公告)号：WO2006048421A1
公开(公告)日：2006-05-11
申请号：PCT/EP2005/055701
申请日：2005-11-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , NIESEN, Gerardus, Petrus, Lambertus , SIJPKES, Andre, Harmen
发明人： NIESEN, Gerardus, Petrus, Lambertus , SIJPKES, Andre, Harmen
IPC分类号： B01J35/00 , B01J23/76 , C10G2/00 , G07C1/04
CPC分类号： C10G2/331 , B01J21/06 , B01J21/063 , B01J23/75 , B01J23/8892 , B01J35/023 , B01J37/0045 , C10G49/02
摘要： A spray dried particulate catalyst comprising a catalytically active component, a carrier and optionally a catalyst promoter, is described. The catalyst has a decrease in average particle diameter following the Shear Test as described herein of 25% or less. The fraction of catalyst particles being less than 10 µm in size, can also be less than 20%. The present invention also provides a method of manufacturing a particulate catalyst material comprising preparing an aqueous slurry, spray drying the aqueous slurry using a spray drier with an inlet temperature of less than 300 °C, and calcining the particulate obtained. The invention has found that catalyst strength may be improved by careful manipulation of the spray drying conditions. In particular, it has been found that a catalyst that is spray dried at a relatively low gas inlet temperature, preferably in the range of 200 °C to 250 °C, shows advantageous attrition characteristics (in terms of attrition resistance) compared to catalysts prepared by spray drying at higher temperatures.
摘要翻译：描述了包含催化活性组分，载体和任选的催化剂促进剂的喷雾干燥的颗粒催化剂。如本文所述的剪切试验后，催化剂的平均粒径降低了25％以下。催化剂颗粒尺寸小于10μm的部分也可以小于20％。本发明还提供一种制备颗粒状催化剂材料的方法，包括制备含水浆料，使用入口温度低于300℃的喷雾干燥器喷雾干燥含水浆料，并煅烧所获得的颗粒。本发明已经发现，通过仔细操作喷雾干燥条件可以提高催化剂强度。特别地，已经发现，在相对低的气体入口温度，优选在200℃至250℃的范围内喷雾干燥的催化剂与制备的催化剂相比，显示出有利的磨耗特性（耐磨性）通过在较高温度下喷雾干燥。

6. 发明申请

WO2012085225A1 PROCESS FOR MANUFACTURING A CATALYST SUPPORT AND A CATALYST 审中-公开
标题翻译：制造催化剂支持和催化剂的方法
公开(公告)号：WO2012085225A1
公开(公告)日：2012-06-28
申请号：PCT/EP2011/073833
申请日：2011-12-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DEKKER, Desmond Marinus Cornelis , NIESEN, Gerardus Petrus Lambertus , VLAAR, Daan
发明人： DEKKER, Desmond Marinus Cornelis , NIESEN, Gerardus Petrus Lambertus , VLAAR, Daan
IPC分类号： B01J23/85 , B01J35/02 , B01J35/04 , B01J35/06 , B01J37/02 , B01J35/10
CPC分类号： B01J37/0225 , B01J23/85 , B01J35/023 , B01J35/026 , B01J35/04 , B01J35/06 , B01J35/1023 , B01J35/1028 , B01J37/0207 , B25J11/00
摘要： The invention relates to a process for manufacturing a catalyst support, in which one or more fibres are fed into a mould, said fibre having a diameter in the range of 5-300 microns, and a length over diameter ratio greater than 500. The body in the mould is compressed and then contacted with a mixture comprising a liquid and a carrier material. The liquid is removed from the wetted body to provide a catalyst support comprising an entangled fibre and carrier material. A catalyst can be made using the same process and additionally adding a catalytically active metal with the mixture comprising a liquid and a carrier material. Alternatively a catalyst can be made using the process for manufacturing a catalyst support followed by impregnation with a catalytically active metal.
摘要翻译：本发明涉及一种用于制造催化剂载体的方法，其中将一种或多种纤维进料到模具中，所述纤维的直径在5-300微米的范围内，并且长度超过直径比大于500.本体在模具中被压缩，然后与包含液体和载体材料的混合物接触。将液体从润湿体移除以提供包含缠结纤维和载体材料的催化剂载体。可以使用相同的方法制备催化剂，并且另外添加催化活性金属，混合物包含液体和载体材料。或者，可以使用制备催化剂载体的方法制备催化剂，然后用催化活性金属浸渍。

7. 发明申请

WO2011080198A3 COATING METHOD FOR STRUCTURED CATALYSTS 审中-公开
公开(公告)号：WO2011080198A3
公开(公告)日：2011-07-07
申请号：PCT/EP2010/070593
申请日：2010-12-22
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BOUMENDJEL, Nariman , BUGLASS, John Graham , JENKINS, Yvette Louise , NIESEN, Gerardus Petrus Lambertus , SCHADDENHORST, David , SCHOONEBEEK, Ronald Jan , VAN KLEI, Thijmen Simon
发明人： BOUMENDJEL, Nariman , BUGLASS, John Graham , JENKINS, Yvette Louise , NIESEN, Gerardus Petrus Lambertus , SCHADDENHORST, David , SCHOONEBEEK, Ronald Jan , VAN KLEI, Thijmen Simon
IPC分类号： C10G2/00 , B01J37/02
摘要： The invention relates to a method for applying a layer comprising a carrier material to a highly porous support, said method comprising the following steps: (a) applying a mixture comprising a liquid and a carrier material to a highly porous support having a size of at least 1 mm and a porosity within the range of between 50 and 98 volume%; (b) centrifuging and spinning the support; (c) drying and/or calcining the support.

8. 发明申请

WO2011080198A2 COATING METHOD FOR STRUCTURED CATALYSTS 审中-公开
标题翻译：结构催化剂的涂覆方法
公开(公告)号：WO2011080198A2
公开(公告)日：2011-07-07
申请号：PCT/EP2010070593
申请日：2010-12-22
申请人： SHELL INT RESEARCH , BOUMENDJEL NARIMAN , BUGLASS JOHN GRAHAM , JENKINS YVETTE LOUISE , NIESEN GERARDUS PETRUS LAMBERTUS , SCHADDENHORST DAVID , SCHOONEBEEK RONALD JAN , VAN KLEI THIJMEN SIMON
发明人： BOUMENDJEL NARIMAN , BUGLASS JOHN GRAHAM , JENKINS YVETTE LOUISE , NIESEN GERARDUS PETRUS LAMBERTUS , SCHADDENHORST DAVID , SCHOONEBEEK RONALD JAN , VAN KLEI THIJMEN SIMON
IPC分类号： C10G2/00 , B01J37/02
CPC分类号： B01J37/0215 , B01J21/063 , B01J23/462 , B01J23/745 , B01J23/75 , B01J35/023 , B01J37/0221 , B01J37/0223 , B01J37/0225 , B01J37/0234 , B01J37/0242 , B01J37/0244 , C10G2/33 , C10G2/331
摘要： The invention relates to a method for applying a layer comprising a carrier material to a highly porous support, said method comprising the following steps: (a) applying a mixture comprising a liquid and a carrier material to a highly porous support having a size of at least 1 mm and a porosity within the range of between 50 and 98 volume%; (b) centrifuging and spinning the support; (c) drying and/or calcining the support.
摘要翻译：本发明涉及一种将包含载体材料的层施加到高度多孔载体上的方法，所述方法包括以下步骤：（a）将包含液体和载体材料的混合物施加到具有大小为至少1mm，孔隙率在50和98体积％之间的范围内; （b）离心并旋转载体; （c）干燥和/或煅烧载体。

9. 发明申请

WO2006048424A1 TITANIA SUPPORTS AND CATALYSTS 审中-公开
标题翻译： TITANIA支持和催化剂
公开(公告)号：WO2006048424A1
公开(公告)日：2006-05-11
申请号：PCT/EP2005/055705
申请日：2005-11-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DOGTEROM, Ronald Jan , GROTENBREG, Robert Adrianus Wilhelmus , NIESEN, Gerardus Petrus Lambertus
发明人： DOGTEROM, Ronald Jan , GROTENBREG, Robert Adrianus Wilhelmus , NIESEN, Gerardus Petrus Lambertus
IPC分类号： B01J21/06 , B01J37/00 , B01J23/889 , C10G2/00 , C01G23/047
CPC分类号： B01J21/063 , B01J23/75 , B01J23/8892 , B01J37/0009 , B01J37/04 , C01G23/047 , C01G23/0532 , C10G2/331 , C10G2/332
摘要： A process for the preparation of a titania catalyst or a titania catalyst carrier is described. It comprises the steps of : obtaining a wet filtercake of titania, the titania having been made by hydrolysis of a suitable titanium compound, optionally admixing the wet filtercake with one or more catalyst materials, extruding said filtercake or said admixture, and drying and/or calcining the so-formed extrudate. The wet filtercake of titania can be provided from any known route or source or reaction. These include the the wet chloride or sulphate processes. The present invention removes the need for current separate drying and calcination of the titania sulphate product prior to its admixture with a catalyst material. It provides a catalyst with increased strength, which catalyst has also been found to provide greater catalytic activity, especially in C5+ selectivity.
摘要翻译：描述了制备二氧化钛催化剂或二氧化钛催化剂载体的方法。其包括以下步骤：获得二氧化钛的湿滤饼，二氧化钛是通过水解合适的钛化合物制备的，任选地将湿滤饼与一种或多种催化剂材料混合，挤出所述滤饼或所述混合物，以及干燥和/或煅烧如此形成的挤出物。二氧化钛的湿滤饼可以从任何已知的路线或来源或反应提供。这些包括湿氯化物或硫酸盐工艺。本发明不需要在与催化剂材料混合之前对硫酸二氧化钛产品进行分离的干燥和煅烧。它提供了具有增强强度的催化剂，该催化剂也被发现提供更大的催化活性，特别是在C5 +选择性。

10. 发明申请

WO2007071701A1 ZIRCONIUM STABILISED FISCHER TROPSCH CATALYST AND CATALYST SUPPORT 审中-公开
标题翻译： ZIRCONIUM稳定FISCHER TROPSCH催化剂和催化剂支持
公开(公告)号：WO2007071701A1
公开(公告)日：2007-06-28
申请号：PCT/EP2006/069956
申请日：2006-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , HOEK, Arend , NIESEN, Gerardus Petrus Lambertus
发明人： HOEK, Arend , NIESEN, Gerardus Petrus Lambertus
IPC分类号： B01J21/06 , C07C1/04 , B01J23/889 , B01J35/00 , B01J37/02 , B01J23/89 , B01J23/847 , B01J23/745 , B01J23/75 , B01J37/00
CPC分类号： B01J37/0225 , B01J21/063 , B01J21/066 , B01J23/745 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J23/8896 , B01J23/89 , B01J35/1014 , B01J37/0045 , C10G2/332
摘要： The present invention relates to a method of preparing a catalyst support or a supported metal catalyst, the method comprising: (a) admixing a porous refractory oxide with a water soluble zirconium precursor in an alkaline solution, and if a supported metal catalyst is prepared, with a precursor of the metal, yielding a slurry, (b) drying the slurry, and (c) calcining; thus yielding a catalyst support or supported metal catalyst having an increased hydrothermal strength. The invention further relates to a method of preparing a catalyst body, the method comprising: (a) admixing a porous refractory oxide with a water soluble zirconium precursor in an alkaline solution, and if a supported metal catalyst is prepared, with a precursor of the metal or the metal itself, yielding a slurry, (b) coating metal with the slurry, (c) drying the coating, and (d) calcining; thus yielding a catalyst body comprising a catalyst support or supported metal catalyst having an increased hydrothermal strength In a preferred embodiment, the zirconium containing compound comprises zirconium carbonate in an ammonium solution. The improved hydrothermal strength is particularly suitable for slurry-type Fischer-Tropsch reactors.
摘要翻译：本发明涉及一种制备催化剂载体或负载型金属催化剂的方法，所述方法包括：（a）在碱性溶液中将多孔难熔氧化物与水溶性锆前体混合，如果制备负载型金属催化剂，与金属的前体一起产生浆料，（b）干燥浆料，和（c）煅烧; 从而产生具有增加的热液强度的催化剂载体或负载型金属催化剂。本发明还涉及一种制备催化剂体的方法，所述方法包括：（a）在碱性溶液中将多孔难熔氧化物与水溶性锆前体混合，如果制备负载型金属催化剂，则其前体为金属或金属本身，产生浆料，（b）用浆料涂覆金属，（c）干燥涂层，和（d）煅烧; 从而产生包含具有增加的热液强度的催化剂载体或负载型金属催化剂的催化剂体。在优选的实施方案中，含锆化合物包括在铵溶液中的碳酸锆。改进的水热强度特别适用于淤浆型费 - 托反应器。

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