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1. 发明申请

WO2004013193A2 HIGHLY STEREOREGULAR POLYPROPYLENE WITH IMPROVED PROPERTIES 审中-公开
标题翻译：具有改进性能的高度立体聚丙烯
公开(公告)号：WO2004013193A2
公开(公告)日：2004-02-12
申请号：PCT/EP0308491
申请日：2003-07-30
申请人： BASELL POLIOLEFINE SPA , MEESTERS ELS , NEWS JEAN , GUIDICINI ALESSANDRO
发明人： MEESTERS ELS , NEWS JEAN , GUIDICINI ALESSANDRO
IPC分类号： C08F10/06 , C08F4/65 , C08F4/651 , C08F110/06 , C08F10/00
CPC分类号： C08F110/06 , Y10T428/31909 , C08F4/6465 , C08F4/6555 , C08F4/651 , C08F4/6545 , C08F2500/15 , C08F2500/12 , C08F2500/04 , C08F2500/26
摘要： Propylene polymers having a content of isotactic pentads (mmmm) higher than 97%, molecular weight distribution, expressed by the formula (a) ratio, equal to or higher than 6 and a value of formula (b) ratio equal to or lower than 5.5. The said polymers are prepared in the presence of a particular combination of Ziegler-Natta solid catalyst components and highly stereoregulating electron-donor compounds. Laminated articles, in particular bi-axially oriented films and sheets, can be prepared with the said polymers.
摘要翻译：具有高于97％的全同立构五单元组含量（mmmm），由式（a）表示的分子量分布等于或大于6且式（b）的值等于或低于5.5的丙烯聚合物。所述聚合物在齐格勒 - 纳塔固体催化剂组分和高度立体调节电子给体化合物的特定组合存在下制备。可以用所述聚合物制备层压制品，特别是双轴取向的薄膜和片材。

2. 发明申请

WO2006125720A1 POLYOLEFINIC COMPOSITIONS HAVING GOOD WHITENING RESISTANCE 审中-公开
标题翻译：具有良好耐光性的聚合物组合物
公开(公告)号：WO2006125720A1
公开(公告)日：2006-11-30
申请号：PCT/EP2006/062094
申请日：2006-05-05
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
发明人： MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
IPC分类号： C08L23/14 , C08L23/10
CPC分类号： C08L23/10 , C08L23/14 , C08L2205/03 , C08L2666/06 , C08F210/06 , C08F4/6492 , C08F4/651 , C08F2/001
摘要： A polypropylene composition comprising 65-77 wt% of a crystalline propylene polymer, 8 to less than 13 wt% of an elastomeric copolymer and 10-23 wt% of polyethylene. The said composition exhibits a flexural modulus value higher than 1300 MPa, stress-whitening resistance values corresponding to a diameter of the whitened area of at most 1.7 cm caused by a ram falling from a 76 cm height and a diameter of the whitened area of at most 1.2 cm caused by a ram falling from a 20 cm height, and a value of Izod impact resistance at 23° C more than 14 kJ/m2 and the one at -20° C at least 5 kJ/m2.
摘要翻译：包含65-77重量％的结晶丙烯聚合物，8至小于13重量％的弹性体共聚物和10-23重量％的聚乙烯的聚丙烯组合物。所述组合物显示高于1300MPa的弯曲模量值，对应于由高度76厘米的白垩层的直径和白色区域的白度范围由高度为20cm的冲头引起的最大的1.2cm，23℃下的Izod耐冲击性值大于14kJ / m 2，-20℃下的抗冲击强度值至少为5kJ / m 2。

3. 发明申请

WO2005113672A1 IMPACT RESISTANT POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：耐冲击聚烯烃组合物
公开(公告)号：WO2005113672A1
公开(公告)日：2005-12-01
申请号：PCT/EP2005/004957
申请日：2005-05-04
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
发明人： MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
IPC分类号： C08L23/10
CPC分类号： C08L23/12 , C08L23/06 , C08L23/0807 , C08L23/10 , C08L23/14 , C08L23/16 , C08L2205/02 , C08L2314/02 , C08L2666/06
摘要： A heterophasic polyolefin composition comprising (percent by weight): (A) 50-0% of a crystalline propylene polymer having a polydispersity index value from 5.2 to 10 and a content of isotactic pentads (mmmm) higher than 97.5 molar%; said polymer containing at least 95% of recurring units deriving from propylene; (B) 5-20% of a first elastomeric copolymer of ethylene with at least a C 3 -C 8 α-olefin comonomer, said copolymer containing from 25 to less than 40% of ethylene, and being soluble in xylene at room temperature in an amount from higher 85 to 95 wt% the intrinsic viscosity [η] of the xylene soluble fraction ranging from 2.5 to 4.5 dL/g; and (C) 10-45% of a second elastomeric copolymer of ethylene with at least a C 3 -C 8 α-olefin comonomer, said copolymer containing from 50 up to 75% of ethylene, and being soluble in xylene at room temperature in an amount from 50 to 85 wt%, the intrinsic viscosity [η] of the xylene soluble fraction ranging from 1.8 to 4.0 dL/g; wherein the sum of amounts of copolymer (B) and copolymer (C) ranges from 20 to 50% based on the total amount of components (A) to (C), the total amount of ethylene based on the total amount of components (A) to (C) is up to 23% by weight and the ratio between the ethylene content of the fraction insoluble in xylene at room temperature (C 2 xif) multiplied by the weight percentage of the fraction insoluble in xylene at room temperature (%XIF) and the ethylene content of the fraction soluble in xylene at room temperature (C 2 xsf) multiplied by the weight percentage of fraction soluble in xylene at room temperature (%SXF), i.e. (C 2 xif %XIF)/(C 2 xsf •%SXF), satisfies the following relation (I), wherein x is the total amount of ethylene.
摘要翻译：包含（重量％）的多相聚烯烃组合物：（A）50-0％的多分散指数值为5.2〜10的结晶丙烯聚合物和高于97.5摩尔％的全同立构五单元组（mmmm）的含量; 所述聚合物含有至少95％来自丙烯的重复单元; （B）乙烯与至少一种C 3 -C 8α-烯烃共聚单体的第一弹性体共聚物的5-20％，所述共聚物含有25至小于40％的乙烯，并且在室温下可溶于二甲苯中从85至95重量％，二甲苯可溶部分的特性粘度η为2.5至4.5dL / g; 和（C）10-45％的乙烯与至少一种C 3 -C 8α-烯烃共聚单体的第二弹性体共聚物，所述共聚物含有50至75％的乙烯，并且在室温下以可溶于二甲苯的量 50至85重量％，二甲苯可溶部分的特性粘度η为1.8至4.0dL / g; 其中共聚物（B）和共聚物（C）的量的总量相对于组分（A）至（C）的总量为20至50％，基于组分（A）的总量的乙烯的总量）至（C）至（C）为23重量％，室温下不溶于二甲苯的馏分的乙烯含量（C2×10）乘以在室温下不溶于二甲苯的馏分的重量百分比（％XIF）和在室温下可溶于二甲苯的馏分（C2xsf）与室温下可溶于二甲苯的馏分的重量百分比（％SXF）即（C2xif％XIF）/（C2xsf。％SXF）的乙烯含量满足下列条件：关系式（I），其中x是乙烯的总量。

4. 发明申请

WO2008061843A1 POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：聚烯烃组合物
公开(公告)号：WO2008061843A1
公开(公告)日：2008-05-29
申请号：PCT/EP2007/060756
申请日：2007-10-10
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
发明人： MARZOLLA, Roberta , CIARAFONI, Marco , GRAZZI, Michele , MASSARI, Paola , NEWS, Jean
IPC分类号： C08L23/10 , C08J5/18 , C08L23/08
CPC分类号： C08J5/18 , C08F210/06 , C08J2323/10 , C08L23/08 , C08L23/10 , C08L2666/06 , C08F2/001 , C08F4/6492 , C08F110/06 , C08F2500/12 , C08F210/16 , C08F210/08 , C08F2500/17
摘要： Polyo lefin compositions, comprising (percent by weight): 1) 55-80% of a homopolymer or copolymer of propylene, said copolymer containing up to 15% of ethylene and/or C4-C10 -olefin(s). 2) 20-45% of a copolymer of ethylene with one or more C4-C10 -olefin(s) containing from 10 to 40% of said C4-C10 -olefin(s); said compositions having values of MFR (230 °C, 2.16 kg) up to 20 g/10 min, a total content of ethylene of 20% or more, a total content of C4-C10 -olefin(s) of 4.5% or more, a ratio of the total content of ethylene to the total content of C4-C10 -olefin(s) of 2.3 or more, a total fract ion soluble in xylene at room temperature of 18 wt% or higher and flexural modulus, referred to the composition as a reactor grade, of more than 700 MPa.
摘要翻译：包含（重量％）的多元醇组合物：1）55-80％的丙烯均聚物或共聚物，所述共聚物含有至多15％的乙烯和/或C 4 -C 10α-烯烃。 2）乙烯与一种或多种含有10-40％所述C 4 -C 10α-烯烃的C 4 -C 10α-烯烃的共聚物的20-45％; 所述组合物的MFR（230℃，2.16kg）至多20g / 10min，乙烯的总含量为20％以上，C4-C10-烯烃的总含量为4.5％以上，乙烯的总含量与C4-C10-烯烃的总含量的比例为2.3以上，在室温下可溶于二甲苯的总分解离子的总重量为18重量％以上，弯曲弹性模量，称为组成为反应器级，超过700MPa。

5. 发明申请

WO2007060114A1 IMPACT RESISTANT POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：耐冲击聚烯烃组合物
公开(公告)号：WO2007060114A1
公开(公告)日：2007-05-31
申请号：PCT/EP2006/068423
申请日：2006-11-14
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
发明人： MASSARI, Paola , NEWS, Jean , CIARAFONI, Marco
IPC分类号： C08L23/10 , B29C45/00 , C08F10/06 , C08L23/08 , C08L23/14
CPC分类号： C08F210/06 , C08F110/06 , C08L23/0815 , C08L23/10 , C08L23/14 , C08L2205/03 , C08F2/001 , C08L2666/06 , C08F2500/12 , C08F2500/04 , C08F2500/15 , C08F210/16 , C08F2500/17 , C08F2500/11
摘要： The present invention provides polyolefin composition comprising a 50-80 wt% of propylene omopolymer or copolymer and a first and a second ethylene/alpha-olefin copolymer, said composition having good stress whitening resistance and gloss, in combination with a good balance of mechanical properties.
摘要翻译：本发明提供了包含50-80重量％丙烯含量聚合物或共聚物和第一和第二乙烯/α-烯烃共聚物的聚烯烃组合物，所述组合物具有良好的耐应力增白性和光泽，以及机械性能的良好平衡。

6. 发明申请

WO2006067023A1 POLYOLEFINIC COMPOSITIONS HAVING GOOD WHITENING RESISTANCE 审中-公开
标题翻译：具有良好耐光性的聚合物组合物
公开(公告)号：WO2006067023A1
公开(公告)日：2006-06-29
申请号：PCT/EP2005/056264
申请日：2005-11-28
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
发明人： MASSARI, Paola , CIARAFONI, Marco , NEWS, Jean
IPC分类号： C08L23/14 , C08L23/10
CPC分类号： C08L23/10 , C08L23/04 , C08L23/06 , C08L23/08 , C08L23/12 , C08L23/142 , C08L23/16 , C08L2205/03 , C08L2666/02 , C08F210/06 , C08F2/001 , C08F4/6492 , C08F4/651
摘要： A polypropylene composition comprising (per cent by weight) (a) 50-77% of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C, higher than 97.5 molar % and a polydispersity index ranging from 4 to 10; (b) 13-28% of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 70% and being partially soluble in xylene at ambient temperature, the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2 to 4 dl/g; and (c) 10-22% of polyethylene having an intrinsic viscosity value ranging from 1 to 3 dl/g, in said composition component (b) plus component (c) being in amounts of at least 25 wt%. The polymer composition exhibits good impact resistant, whitening resistance and relatively low stiffness.
摘要翻译：包含（重量百分数）（a）50-77％的具有全同立构五单元组（Mwmm）的结晶丙烯聚合物的聚丙烯组合物，其通过13C-MNR测量在25℃下不溶于二甲苯的级分，高于 97.5摩尔％，多分散指数为4〜10; （b）13-28％的乙烯和丙烯的弹性体共聚物，该共聚物具有一定量的衍生自乙烯的重复单元，范围为30至70％，并且在环境温度下部分溶于二甲苯，聚合物馏分可溶于二甲苯环境温度的特性粘度值范围为2至4dl / g; 和（c）所述组合物组分（b）加组分（c）的特性粘度值为1至3dl / g的聚乙烯的10-22％的量为至少25重量％。聚合物组合物表现出良好的抗冲击性，耐白化性和相对低的刚度。

7. 发明申请

WO2004087807A1 IMPACT RESISTANT POLYOLEFIN COMPOSITIONS 审中-公开
标题翻译：耐冲击聚烯烃组合物
公开(公告)号：WO2004087807A1
公开(公告)日：2004-10-14
申请号：PCT/EP2004/003307
申请日：2004-03-29
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , NEWS, Jean , MASSARI, Paola , ZIMMERMANN, Hans-Jürgen
发明人： NEWS, Jean , MASSARI, Paola , ZIMMERMANN, Hans-Jürgen
IPC分类号： C08L23/12
CPC分类号： C08F10/00 , C08F210/16 , C08L23/0815 , C08L23/10 , C08L23/16 , Y10S526/905 , C08F4/651 , C08L2666/06 , C08F210/06 , C08F2500/12 , C08F2500/17 , C08F2500/04
摘要： Olefin polymer composition comprising (by weight, unless otherwise specified): A) 60 - 95% of a propylene homopolymer or copoloymer having a Polydispersity Index (P.I.) value of from 4.6 to 10 and a content of isotactic pentads (mmmm), measured by 13C NMR on the fraction insoluble in xylene at 25 °C, higher than 98 molar; B) 5 - 40% of a copolymer of ethylene containing from 40% to 70% of propylene or C 4 -C 10 α-olefins) or of combinations thereof, and optionally minor proportions of a diene; said composition having a Temperature Rising Elution Fractionation (TREF) profile, obtained by fractionation in xylene and collection of fractions at temperatures of 40 °C, 80°C and 90 °C, in which the ethylene content Y of the fraction collected at 90 °C satisfies the following relation (I): Y≤ -0.8 + 0.035X + 0.0091X 2 wherein X is the ethylene content of the fraction collected at 40 °C and both X and Y are expressed in percent by weight, and a value of intrinsic viscosity [η] of the fraction soluble in xylene at 25 °C of from 1.8 to 4.2 dl/g.
摘要翻译：烯烃聚合物组合物包含（按重量计，除非另有说明）：A）60-95％的多分散指数（PI）值为4.6至10的丙烯均聚物或共聚合物和全同立构五单元组的含量（mmmm），通过对25℃不溶于二甲苯的级分，高于98摩尔的13C NMR; B）5-40％的含有40％至70％的丙烯或C 4 -C 10α-烯烃的乙烯的共聚物或其组合，以及任选的较小比例的二烯; 所述组合物具有通过在二甲苯中分馏并在40℃，80℃和90℃的温度下收集级分获得的升温洗脱分馏（TREF）分布，其中在90°收集的级分的乙烯含量Y C满足以下关系式（I）：Y <= -0.8 + 0.035X + 0.0091X2其中X是在40℃下收集的馏分的乙烯含量，X和Y都以重量％表示，在25℃下可溶于二甲苯的馏分的特性粘度η为1.8至4.2dl / g。

8. 发明申请

WO2004013193A3 HIGHLY STEREOREGULAR POLYPROPYLENE WITH IMPROVED PROPERTIES 审中-公开
公开(公告)号：WO2004013193A3
公开(公告)日：2004-02-12
申请号：PCT/EP2003/008491
申请日：2003-07-30
申请人： BASELL POLIOLEFINE ITALIA S.P.A , MEESTERS, Els , NEWS, Jean , GUIDICINI, Alessandro
发明人： MEESTERS, Els , NEWS, Jean , GUIDICINI, Alessandro
IPC分类号： C08F4/651
摘要： Propylene polymers having a content of isotactic pentads (mmmm) higher than 97%, molecular weight distribution, expressed by the formula (a) ratio, equal to or higher than 6 and a value of formula (b) ratio equal to or lower than 5.5. The said polymers are prepared in the presence of a particular combination of Ziegler-Natta solid catalyst components and highly stereoregulating electron-donor compounds. Laminated articles, in particular bi-axially oriented films and sheets, can be prepared with the said polymers.

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