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    • 9. 发明授权
    • Zn-Co-W alloy electroplated steel sheet with excellent corrosion resistance and weldability, and electrolyte for plating same
    • 具有优异的耐腐蚀性和焊接性的Zn-Co-W合金电镀钢板和用于电镀的电解质
    • US06677057B2
    • 2004-01-13
    • US10204512
    • 2002-08-21
    • Myung-Su Kim
    • Myung-Su Kim
    • C25D322
    • C25D3/565Y10S428/935Y10T428/12799Y10T428/1284
    • A Zn—Co—W alloy electroplated steel sheet with excellent corrosion resistance and weldability, and an electrolyte for manufacturing same are provided. The plating layer consisting of Co: 0.1-3.0 wt %, and zinc: balance, is formed on the steel sheet and all tungsten plating is carried out with metallic tungsten; an electrolyte for manufacturing a Zn—Co—W alloy electroplated steel sheet, comprising zinc chloride: 60-200 g/l, cobalt chloride: 0.1-6.0 g/l, tungsten: 0.1-4.0 g/l, citric acid: 0.5-10.0 g/l, polyethylene glycol: 0.1-2.0 m/l and electric conductive aid: 30-400 g/l, wherein substantially all of the tungsten ions form a complex compound with citric acid, thereby preventing formation of sludge; and a Zn—Co—W alloy electroplated steel sheet, on which a plating layer is formed by electroplating the steel in the electrolyte.
    • 提供具有优异的耐腐蚀性和焊接性的Zn-Co-W合金电镀钢板及其制造用电解液。 在钢板上形成由Co:0.1-3.0重量%和锌平衡的组成的镀层,并用金属钨进行所有的钨镀层; 一种用于制造Zn-Co-W合金电镀钢板的电解质,包括氯化锌:60-200g / l,氯化钴:0.1-6.0g / l,钨:0.1-4.0g / l,柠檬酸: 10.0g / l,聚乙二醇:0.1-2.0m / l和导电助剂:30-400g / l,其中基本上所有的钨离子与柠檬酸形成络合物,从而防止污泥的形成; 和Zn-Co-W合金电镀钢板,通过在电解液中电镀钢而形成镀层。