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    • 8. 发明授权
    • Neutralization of alkali metal catalysts in organopolysiloxanes
    • 碱金属催化剂在有机聚硅氧烷中的中和
    • US4625011A
    • 1986-11-25
    • US530296
    • 1983-09-08
    • Diane M. KosalMyron T. Maxson
    • Diane M. KosalMyron T. Maxson
    • C08G77/32C08G77/34C08G77/06
    • C08G77/34C08G77/32
    • A process for the neutralization of the alkali metal catalyst in a polymerized organopolysiloxane where the alkali metal content of the resulting organopolysiloxane is significantly reduced, is described. The process consists of neutralizing the alkali metal salt with a straight-chain carboxylic acid of general formula ZCOOH, where Z is a hydrocarbon group containing at least two carbon atoms, and thereafter filtering the organopolysiloxane. The same ZCOOH carboxylic acids may be added to organopolysiloxanes which have previously been neutralized with either carbon dioxide or acetic acid in order to significantly reduce the alkali metal content of the organopolysiloxane after filtration. Organopolysiloxanes containing less than 0.5 ppm K.sup.+ can be easily obtained.
    • 描述了在所得有机聚硅氧烷的碱金属含量显着降低的聚合有机聚硅氧烷中中和碱金属催化剂的方法。 该方法包括用通式ZCOOH的直链羧酸中和碱金属盐,其中Z是含有至少两个碳原子的烃基,然后过滤有机聚硅氧烷。 可以将相同的ZCOOH羧酸加入预先用二氧化碳或乙酸中和的有机聚硅氧烷中,以显着降低过滤后的有机聚硅氧烷的碱金属含量。 含有小于0.5ppm K +的有机聚硅氧烷可以容易地得到。