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    • 2. 发明申请
    • Graphite-base hydrogen storage material and production method thereof
    • 石墨基储氢材料及其制备方法
    • US20060019162A1
    • 2006-01-26
    • US11175521
    • 2005-07-05
    • Minoru ShirahigeKoji YonetaJunji KatamuraMikio KawaiMasaharu HatanoMasashi Ito
    • Minoru ShirahigeKoji YonetaJunji KatamuraMikio KawaiMasaharu HatanoMasashi Ito
    • H01M4/58C01B31/02
    • H01M8/065B82Y30/00C01B3/0021C01B32/22Y02E60/325
    • Disclosed is a hydrogen storage material and a production method thereof. The hydrogen storage material has a carbon material having: an interlayer space for hydrogen occlusion, produced by removal at least a portion of an organic compound from a graphite intercalation compound comprising graphite and the organic compound intercalated in the graphite; and an active point at which hydrogen is adsorbed, being produced on the remaining organic compound and/or a part of the hexagonal carbon layers defining the interlayer space. It has a layered lattice structure with hexagonal carbon layers and an expanded interlayer space, and its density determined in accordance with He equilibrium pressure density measuring method changes according as pre-equilibrium He pressures and falls in a range of 0.2 to 1.2 g/cm3 at pre-equilibrium pressures of 0.2 MPa and 0.8 MPa. The hydrogen storage material is produced by; preparing an organic-graphite intercalation compound; and reducing the organic-graphite intercalation compound to remove at least a portion of the inserted organic compound from the organic-graphite intercalation compound, thereby forming an interlayer space.
    • 公开了一种储氢材料及其制造方法。 储氢材料具有碳材料,其具有:通过从包含石墨的石墨插层化合物和插入石墨中的有机化合物除去至少一部分有机化合物而产生的用于氢气闭塞的层间空间; 以及在剩余的有机化合物和/或限定层间空间的六方碳层的一部分上产生吸附氢的活性点。 它具有具有六方碳层和扩展的层间空间的层状晶格结构,并且其根据He平衡压力密度测量方法确定的密度根据平衡前He He压力而变化并且在0.2-1.2g / cm 2的范围内变化, 在0.2MPa和0.8MPa的平衡前压力下,SUP> 3。 储氢材料由 制备有机 - 石墨插层化合物; 并且还原有机 - 石墨插层化合物以从有机 - 石墨插入化合物中除去至少一部分插入的有机化合物,由此形成层间空间。