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1. 发明授权

US06541663B2 Process for preparation of aminocarboxylic acids 失效
公开(公告)号：US06541663B2
公开(公告)日：2003-04-01
申请号：US09872653
申请日：2001-06-01
申请人： Bernd Siebenhaar , Milos Rusek
发明人： Bernd Siebenhaar , Milos Rusek
IPC分类号： C07C5116
CPC分类号： B01J25/00 , B01J27/188 , C07C227/02 , C07C229/16
摘要： Raney copper, which is doped (promoted) with an effective quantity of a doping (promoting) agent selected from the group boric acid, onium fluorides, salts of fluorine complex anions, and heteropoly acids, represents an outstanding oxidation catalyst for amine-group-containing primary amines to carboxylic acids.

2. 发明授权

US5206414A Process for the preparation of hydroxyphenylpropionic acid esters 失效
标题翻译：羟基苯丙酸酯的制备方法
公开(公告)号：US5206414A
公开(公告)日：1993-04-27
申请号：US876813
申请日：1992-04-29
申请人： Samuel Evans , Paul Dubs , Milos Rusek , Zdenek Mazour , Arpad Major
发明人： Samuel Evans , Paul Dubs , Milos Rusek , Zdenek Mazour , Arpad Major
IPC分类号： C07C67/03 , C07C67/347 , C07C69/732
CPC分类号： C07C67/03 , C07C67/347
摘要： A process for the preparation of compounds of the general formula ##STR1## where R.sub.1 and R.sub.2 are identical or different and are hydrogen, C.sub.1 -C.sub.18 alkyl, phenyl, C.sub.1 -C.sub.4 alkyl-substituted phenyl, C.sub.7 -C.sub.9 phenylalkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.1 -C.sub.4 alkyl-substituted C.sub.5 -C.sub.12 cycloalkyl,R.sub.3 is hydrogen or methyl,m is 0, 1, 2 or 3, andn is a number from 1 to 4 or 6, andA is as defined in the description,by reacting a compound of the formula II ##STR2## where m, R.sub.1 and R.sub.2 are as defined above, with a compound of the formula III ##STR3## where A and n are as defined in the description, which comprises carrying out the reaction in the presence of a catalyst which contains, as active material, an alkali metal compound of the formula IVM.sub.m An (IV)in whichM is Li, Na, K, Rb or Cs,m is the valency of An, andAn is a fluoride, hydroxide, phosphate, formate, acetate or --OR.sub.5 radical, andR.sub.5 is alkyl having 1 to 4 carbon atoms or phenyl,and, as support, an alkaline material which, measured in 10% strength by weight aqueous suspension, has a pH>10, selected from one or more groups of substances from the series comprising the alkaline earth metal oxides, hydroxides, aluminates or silicates.
摘要翻译：制备通式为（I）的化合物的方法，其中R 1和R 2相同或不同，为氢，C 1 -C 18烷基，苯基，C 1 -C 4烷基取代的苯基，C 7 -C 9苯基烷基，C 5 -C 12环烷基或 C 1 -C 4烷基取代的C 5 -C 12环烷基，R 3是氢或甲基，m是0,1,2或3，n是1至4或6的数，A如说明书中所定义，通过化合物式（II）其中m，R 1和R 2如上定义，与式IIIA（H）n，（III）的化合物反应，其中A和n如说明书中所定义，其包含在含有M为Li，Na，K，Rb或Cs的式IV MmAn（IV）的碱金属化合物作为活性物质的催化剂存在下进行反应，m为An的化合价，并且An是氟化物，氢氧化物，磷酸盐，甲酸盐，乙酸盐或-OR 5基团，R 5是具有1至4个碳原子的烷基或苯基，作为载体，碱性物质以10％重量百分比的含水悬浮液，pH> 10，选自一组或多组来自包含碱土金属氧化物，氢氧化物，铝酸盐或硅酸盐的系列的物质。

3. 发明授权

US4921980A Process for the preparation of N-Alkylanilines 失效
标题翻译： N-烷基苯胺的制备方法
公开(公告)号：US4921980A
公开(公告)日：1990-05-01
申请号：US53245
申请日：1987-05-22
申请人： Milos Rusek
发明人： Milos Rusek
IPC分类号： C07C209/18 , C07C213/02 , C07D307/14 , C07D307/28 , C07D309/04
CPC分类号： C07D307/28 , C07C209/18 , C07C213/02 , C07D307/14 , C07D309/04 , C07C2101/14 , Y02P20/582
摘要： A process for the preparation of N-alkylanilines is described, the most essential feature of which comprises reacting corresponding anilines at 150.degree. to 300.degree.C. with corresponding alcohols in the presence of a catalyst consisting of silica gel as carrier, of 0.2 to 10% of platinum and of 0.05 to 3% of a compound of a metal of the groups Ia and/or IIa of the Periodic Table, with the catalyst additionally containing at least one compound of an element of the groups Ib, IVa, IVb, Vb, VIIb and VIII in such an amount that the atomic ratio of platinum to the sum of these elements is 1 to 6.
摘要翻译：描述了制备N-烷基苯胺的方法，其最重要的特征包括在150-300℃的相应的苯胺与相应的醇在由硅胶作为载体的催化剂存在下反应0.2至10 的铂和0.05〜3％的周期表中的Ia和/或IIa族的金属的化合物，催化剂另外含有至少一种Ib族，IVa，IVb，Vb族元素的化合物，VIIb和VIII，其量使铂的原子比与这些元素之和为1〜6。

4. 发明授权

US4833255A Process for the preparation of indoline 失效
标题翻译：二氢吲哚的制备方法
公开(公告)号：US4833255A
公开(公告)日：1989-05-23
申请号：US71436
申请日：1987-07-09
申请人： Milos Rusek , Hermann Kny
发明人： Milos Rusek , Hermann Kny
IPC分类号： C07D209/08
CPC分类号： C07D209/08 , Y02P20/584
摘要： A process for the preparation of indoline without substantial formation of indole, comprises passing 2-(2-aminophenyl)ethanol, in a vapor phase and admixed with a carrier gas, at a temperature of from about 240.degree. to about 260.degree. C. over at least a catalytic amount of a metal silicate or aluminosilicate containing alkaline earth metal or rare earth metal ions. The carrier gas can be water in the form of steam. The passage of 2-(2-aminophenyl)ethanol over the catalyst can be periodically terminated and the catalyst reactivatd by passing a mixture of air and nitrogen over the catalyst at a temperature of from about 300.degree. to about 550.degree. C., after which the passage of 2-(2-aminophenyl)ethanol and carrier gas can be resumed.
摘要翻译：用于制备吲哚啉而不显着形成吲哚的方法包括使气相中的2-（2-氨基苯基）乙醇与载气混合，在约240°至约260℃的温度下至少催化量的含有碱土金属或稀土金属离子的金属硅酸盐或硅铝酸盐。载气可以是蒸汽形式的水。在催化剂上通过2-（2-氨基苯基）乙醇可以定期地终止，并且催化剂通过使空气和氮气的混合物在约300℃至约550℃的温度下在催化剂上通过反应，之后可以恢复2-（2-氨基苯基）乙醇和载气的通过。

5. 发明授权

US4396782A Process for producing unsaturated ethers 失效
标题翻译：生产不饱和醚的方法
公开(公告)号：US4396782A
公开(公告)日：1983-08-02
申请号：US337898
申请日：1982-01-07
申请人： Sameer H. Eldin , Milos Rusek
发明人： Sameer H. Eldin , Milos Rusek
IPC分类号： C07C43/162 , B01J23/00 , C07B61/00 , C07C41/00 , C07C41/28 , C07C67/00
CPC分类号： C07C41/28
摘要： A process for producing .alpha.,.beta.-unsaturated alkenyl ethers by cleavage of acetals in the gas phase and in the presence of a catalyst, the catalyst used being calcium oxide, the acetal cleavage being performed in the temperature range of 200.degree. to 300.degree. C. and the process being carried out preferably in a simple distilling apparatus.
摘要翻译：通过在气相中和在催化剂存在下裂解缩醛来生产α，β-不饱和烯基醚的方法，所用的催化剂是氧化钙，缩醛裂解在200-300℃的温度范围内进行并且该方法优选在简单的蒸馏装置中进行。

6. 发明授权

US4183868A Process for the preparation of 2,6-dialkyl-N-alkylanilines 失效
标题翻译： 2,6-二烷基-N-烷基苯胺的制备方法
公开(公告)号：US4183868A
公开(公告)日：1980-01-15
申请号：US899903
申请日：1978-04-26
申请人： Paul Radimerski , Milos Rusek
发明人： Paul Radimerski , Milos Rusek
IPC分类号： B01J23/00 , B01J23/89 , C07C67/00 , C07C209/00 , C07C209/18 , C07C211/46 , C07C211/48 , C07C85/06 , B01J23/64
CPC分类号： C07C209/18 , B01J23/8993
摘要： A process for the preparation of 2,6-dialkyl-N-alkylanilines is disclosed, which process comprises the reaction of a 2,6-dialkylaniline with an alkanol at 200.degree. to 350.degree. C. in the presence of a copper-containing catalyst which contains 0.05 to 10% by weight of palladium or platinum.
摘要翻译：公开了制备2,6-二烷基-N-烷基苯胺的方法，该方法包括2,6-二烷基苯胺与链烷醇在200-350℃下在含铜催化剂存在下的反应其含有0.05至10重量％的钯或铂。

7. 发明授权

US4484992A Process for the production of hydrogen by means of heterogeneous photoredox catalysis 失效
标题翻译：通过异源光催化氧化生产氢气的方法
公开(公告)号：US4484992A
公开(公告)日：1984-11-27
申请号：US342615
申请日：1982-01-25
申请人： Niklaus Buhler , Jean F. Reber , Kurt Meier , Milos Rusek
发明人： Niklaus Buhler , Jean F. Reber , Kurt Meier , Milos Rusek
IPC分类号： B01J19/12 , B01J23/00 , B01J27/00 , B01J27/02 , B01J27/04 , B01J27/057 , B01J35/02 , C01B3/04 , C07B61/00
CPC分类号： C01B3/042 , B01J27/02 , B01J27/04 , B01J27/0573 , Y02E60/364
摘要： A process is described for the selective production of hydrogen by means of heterogeneous photoredox catalysis, in which mixtures of water and alkali metal sulfites or sulfides, alkaline earth metal sulfites or sulfides or ammonium sulfites or sulfides are reacted under the action of light in a suspension of a cadmium sulfide, cadmium sulfoselenide or titanium dioxide/semiconductor powder which is at least partially coated with Cu, Cr, Ni, Co or a noble metal or mixtures thereof. The catalysts which can be employed in this process (coated semiconductor powders) are in some cases novel.
摘要翻译：描述了通过异源光氧化物催化选择性生产氢的方法，其中水和碱金属亚硫酸盐或硫化物，碱土金属亚硫酸盐或硫化物或亚硫酸铵或硫化物的混合物在光的作用下在悬浮液中反应至少部分涂覆有Cu，Cr，Ni，Co或贵金属的硫化镉，硫化镉或二氧化钛/半导体粉末或其混合物。在这种方法中可以使用的催化剂（涂覆的半导体粉末）在某些情况下是新颖的。

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