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1. 发明授权

US06982312B2 Process for producing polyarylene sulfide 失效
标题翻译：生产聚芳硫醚的方法
公开(公告)号：US06982312B2
公开(公告)日：2006-01-03
申请号：US10471663
申请日：2002-03-04
申请人： Minoru Senga , Masaya Okamoto , Mikiya Hayashi
发明人： Minoru Senga , Masaya Okamoto , Mikiya Hayashi
IPC分类号： C08G75/00
CPC分类号： C08G75/025 , C08G75/0254
摘要： There is disclosed a process for producing a polyarylene sulfide (PAS) which comprises reacting a sulfur source with a dihalogenated aromatic compound in the presence of an aprotic organic solvent, characterized in that the process comprises at least one polymerization reaction step wherein a polymer phase as a dispersed phase is in the form of spherical droplets. It is made possible by the continuous polymerization process to discharge the polymer phase and solvent phase from a polymerization vessel at a constant ratio and as a result, to maintain PAS composition (concentration) at a constant level at all times, and thus to provide a continuous PAS production process which is effective for enhancing its molecular weight and stabilizing the same.
摘要翻译：公开了一种生产聚芳硫醚（PAS）的方法，该方法包括在非质子有机溶剂存在下使硫源与二卤代芳族化合物反应，其特征在于该方法包括至少一个聚合反应步骤，其中聚合物相为分散相是球形液滴的形式。通过连续聚合方法可以以恒定比例从聚合容器中排出聚合物相和溶剂相，结果，始终保持PAS组成（浓度）在恒定水平，从而提供一种连续的PAS生产工艺，对于提高其分子量和稳定分子量是有效的。

2. 发明授权

US07026439B2 Process for continuous production of polyarylene sulfide 失效
标题翻译：连续生产聚芳硫醚的工艺
公开(公告)号：US07026439B2
公开(公告)日：2006-04-11
申请号：US10473366
申请日：2002-03-15
申请人： Minoru Senga , Masaya Okamoto , Mikiya Hayashi
发明人： Minoru Senga , Masaya Okamoto , Mikiya Hayashi
IPC分类号： C08G75/00 , C08G75/14 , C08G75/18
CPC分类号： C08G75/025
摘要： There is disclosed a process for continuously producing a polyarylene sulfide which comprises reacting a sulfur source with a dihalogenated aromatic compound in an aprotic organic solvent, characterized by maintaining the content of the dihalogenated aromatic compound in the polymerization liquid after the substantial completion of the polymerization reaction at 5 mg/g or higher. It is made possible by the process according to the present invention to efficiently produce the polyarylene sulfide which has a high molecular weight and is excellent in thermal stability.
摘要翻译：公开了一种连续生产聚芳硫醚的方法，其包括在非质子有机溶剂中使硫源与二卤代芳族化合物反应，其特征在于在聚合反应基本上完成后维持聚合液中的二卤代芳族化合物的含量在5mg / g以上。通过本发明的方法可以有效地制备分子量高且热稳定性优异的聚芳硫醚。

3. 发明申请

US20060122363A1 Process for the production of polyarylene sulfide 审中-公开
标题翻译：聚芳硫醚生产工艺
公开(公告)号：US20060122363A1
公开(公告)日：2006-06-08
申请号：US10529631
申请日：2003-10-01
申请人： Mikiya Hayashi , Minoru Senga
发明人： Mikiya Hayashi , Minoru Senga
IPC分类号： C08G75/00
CPC分类号： C08G75/0254 , C08G75/0231 , C08G75/025 , C08G75/14
摘要： The production process of the present invention for polyarylene sulfide is characterized by that in a process for continuously producing polyarylene sulfide by reacting a sulfur source with a dihalogenated aromatic compound in an aprotic organic solvent, it comprises at least one polymerization reaction step in which two phases of a polymer phase and a solvent phase are separated and in which the polymer phase corresponding to a dispersion phase is a dispersion phase comprising globular droplets and that an end terminator is used in the above polymerization reaction step. According to the present invention, a polymer can be prevented from being adhered onto a polymerization reaction bath to thereby make it possible to discharge a polymer phase and a solvent phase from the polymerization bath in a constant proportion; resultingly, a PAS composition (concentration) in the polymerization bath can always be maintained at a constant value; and polyarylene sulfide having a raised and stabilized molecular weight can continuously be produced.
摘要翻译：本发明的聚芳硫醚的制造方法的特征在于，通过在非质子性有机溶剂中使硫源与二卤代芳香族化合物反应而连续生成聚芳硫醚的方法，其包括至少一个聚合反应步骤，其中两相分离聚合物相和溶剂相，其中对应于分散相的聚合物相是包含球状液滴的分散相，并且在上述聚合反应步骤中使用终止终止剂。根据本发明，可以防止聚合物粘附在聚合反应槽上，从而可以以一定的比例从聚合浴中排出聚合物相和溶剂相; 因此，聚合槽中的PAS组成（浓度）总能保持在恒定值; 并且可以连续生产具有升高和稳定的分子量的聚芳硫醚。

4. 发明授权

US5149581A Polyether copolymers, resin compositions containing them, and molded articles formed from them 失效
标题翻译：聚乙烯共聚物，含有它们的树脂组合物和从它们形成的成型品
公开(公告)号：US5149581A
公开(公告)日：1992-09-22
申请号：US612609
申请日：1990-11-13
申请人： Shigeru Matsuo , Shigeru Murakami , Shinji Chino , Hiroyuki Higuchi , Mikiya Hayashi
发明人： Shigeru Matsuo , Shigeru Murakami , Shinji Chino , Hiroyuki Higuchi , Mikiya Hayashi
IPC分类号： B32B27/04 , C08G65/40 , C08J5/18 , C08L71/00 , D01F6/78
CPC分类号： C08J5/18 , B32B27/04 , C08G65/4031 , C08L71/00 , D01F6/78 , C08G2650/64 , C08J2371/00 , C08L2205/05 , Y10S428/91 , Y10T428/2913 , Y10T428/31855 , Y10T428/31909 , Y10T428/31935 , Y10T442/30 , Y10T442/40
摘要： A polyether copolymer comprising the repeating units represented by the following general formula (I) ##STR1## and the repeating units represented by the following formula (II) ##STR2## the molar ratio of (I)/{(I)+(II)} being from 0.1 to 0.8 and the polyether copolymer having a melt viscosity of at least 500 poise as measured at 400.degree. C. is produced by allowing a dihalogenobenzonitrile, 1,4-bis(4'-halobenzoyl)benzene, and 4,4'-biphenol to react with each other in an aprotic polar solvent in the presence of an alkali metal compound. The polyether copolymer exhibits excellent heat-resistance, solvent resistance, and mechanical strength, and is suitable as a material for resin compositions, heat-resistant laminates, fiber, and film.

5. 发明授权

US07060785B2 Process for continuous production of branched polyarylene sulfides 失效
标题翻译：连续生产支化聚亚芳基硫化物的方法
公开(公告)号：US07060785B2
公开(公告)日：2006-06-13
申请号：US10513467
申请日：2003-04-21
申请人： Mikiya Hayashi , Kouichi Suga
发明人： Mikiya Hayashi , Kouichi Suga
IPC分类号： C08G75/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： A process for continuous production of a branched polyarylene sulfide, which includes pre-polymerizing a sulfur source with a dihalogenated aromatic compound in such a manner that the reaction rate of the dihalogenated aromatic compound is less than 95% so as to produce a polyarylene sulfide, prepolymer, and polymerizing the prepolymer in the presence of a branching agent while dispersing the phase of the polymer into the form of spherical droplets in the phase of a solvent. When the prepolymer is added to the solvent phase to which a phase separator is beforehand added, spherical droplets of the polymer phase can be produced.
摘要翻译：一种连续生产支化聚芳硫醚的方法，其包括以二卤代芳族化合物的反应速率小于95％的方式使二硫代芳族化合物预硫化以产生聚芳硫醚，预聚物，并且在支化剂存在下使预聚物聚合，同时在溶剂相中将聚合物相分散成球形液滴的形式。当将预聚物加入到预先加入相分离器的溶剂相中时，可以制备聚合物相的球形液滴。

6. 发明申请

US20060025632A1 Process for continuous production of branched polyarylene sulfides 失效
公开(公告)号：US20060025632A1
公开(公告)日：2006-02-02
申请号：US10513467
申请日：2003-04-21
申请人： Mikiya Hayashi , Kouichi Suga
发明人： Mikiya Hayashi , Kouichi Suga
IPC分类号： C07C319/14
CPC分类号： C08G75/0254 , C08G75/0231
摘要： A process for continuous production of a branched polyarylene sulfide, which includes pre-polymerizing a sulfur source with a dihalogenated aromatic compound in such a manner that the reaction rate of the dihalogenated aromatic compound is less than 95% so as to produce a polyarylene sulfide, prepolymer, and polymerizing the prepolymer in the presence of a branching agent while dispersing the phase of the polymer into the form of spherical droplets in the phase of a solvent. When the prepolymer is added to the solvent phase to which a phase separator is beforehand added, spherical droplets of the polymer phase can be produced.

7. 发明申请

US20050159562A1 Polyaryl ether copolymer, process for the production thereof, and polymer electrolytic film formed of the same 审中-公开
标题翻译：聚芳醚共聚物，其制备方法和由其形成的聚合物电解质膜
公开(公告)号：US20050159562A1
公开(公告)日：2005-07-21
申请号：US11036391
申请日：2005-01-18
申请人： Mikiya Hayashi , Yutaka Obata , Toru Bando
发明人： Mikiya Hayashi , Yutaka Obata , Toru Bando
IPC分类号： C08G2/00 , C08G65/34 , C08G65/40 , C08G65/48 , C08J5/22 , C08L71/10 , H01M8/10
CPC分类号： C08G65/40 , C08G65/48 , C08L71/10
摘要： A polyaryl ether copolymer which has the following formula (1) and contains at least 0.1% by weight of a hydrophilic group, Ar1—O—Ar2—OnAr3—O—Ar4—Om (1) each of Ar1 and Ar3 independently represents a group selected from the following groups, each of Ar2 and Ar4 independently represents a group selected from the following groups, the hydrophilic group is substituted on at least one of Ar1, Ar2, Ar3 and Ar4, and each of n and m represents a copolymerization compositional ratio.
摘要翻译：具有下式（1）并且含有至少0.1重量％的亲水基团的聚芳基醚共聚物<β在线式描述=“在线式”末端=“lead”→>Ar< N 1 -O-Ar 2 -O - - - - - - - - - - - - - - - - - - - - - - - - - - - （1）<？in-line-formula description =“In-line Formulas”end =“tail”？>每个Ar 1＆lt; 1＆lt; 1＆gt;和 Ar 3 3独立地表示选自以下基团的基团，Ar 2和Ar 4中的每一个独立地表示选自以下基团的基团，亲水基团在Ar 1，Ar 2，Ar 3和Ar 4中的至少一个上被取代， n和m各自表示共聚组成比。

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