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    • 4. 发明授权
    • Finish composition for coating and protecting a reinforcing substrate
    • 用于涂覆和保护增强基材的涂饰组合物
    • US5389440A
    • 1995-02-14
    • US251036
    • 1994-05-31
    • Michel ArpinPaul PetitAndre Vagnon
    • Michel ArpinPaul PetitAndre Vagnon
    • C08K5/09C03C25/30C08J3/03C08K9/04C08L51/06B32B9/00
    • C08J3/03C03C25/30C08J2351/06Y10T428/2962Y10T428/31938
    • An aqueous emulsion for use in forming a weight average sizing coating for treating a surface of a substrate. The emulsion comprises at least one polyolefin having a molecular weight greater than 10,000; an acid material selected from the group consisting of saturated fatty acids, unsaturated fatty acids which do not includ any hydroxyl groups and mixtures thereof; at least one base; optionally, an emulsifying agent; and a sufficient amount of water to form an aqueous phase emulsion comprising from about 10-50% of solid materials. The emulsion is formed by combining the polyolefin with the fatty acid at a temperature higher than the melting point of the polyolefin to form a first mixture, adding to the first mixture a sufficient amount of base to neutralize the polyolefin and the fatty acid together with the water and optionally the emulsifying agent to form a second mixture; stirring the second mixture at an elevated pressure and at a temperature above the melting point of the polyolefin and subsequently cooling the mixture to a temperature below the melting point of the polyolefin. The emulsion is particularly useful as a component of a sizing for coating and protecting glass fibers for reinforcing polymeric materials.
    • 一种用于形成用于处理基材表面的重均匀施胶涂层的水性乳液。 该乳液包含至少一种分子量大于10,000的聚烯烃; 选自饱和脂肪酸,不包括任何羟基的不饱和脂肪酸及其混合物的酸性物质; 至少一个基地; 任选的乳化剂; 和足够量的水以形成包含约10-50%的固体材料的水相乳液。 通过在高于聚烯烃熔点的温度下将聚烯烃与脂肪酸组合形成第一混合物形成乳液,向第一混合物中加入足量的碱以中和聚烯烃和脂肪酸 水和任选的乳化剂以形成第二混合物; 在升高的压力和高于聚烯烃熔点的温度下搅拌第二混合物,随后将混合物冷却到低于聚烯烃熔点的温度。 该乳液特别可用作用于涂覆和保护用于增强聚合材料的玻璃纤维的施胶剂的组分。
    • 6. 发明授权
    • Aqueous polyolefin emulsions and method of forming same
    • 水性聚烯烃乳液及其形成方法
    • US5242969A
    • 1993-09-07
    • US758442
    • 1991-09-05
    • Michel ArpinPaul PetitAndre Vagnon
    • Michel ArpinPaul PetitAndre Vagnon
    • C03C25/30C08J3/03
    • C08J3/03C03C25/30C08J2351/06
    • An aqueous emulsion for use in forming a sizing coating for treating a surface of a substrate. The emulsion comprises at least one polyolefin having a weight average molecular weight greater than 10,000; an acid material selected from the group consisting of saturated fatty acids, unsaturated fatty acids which do not includ any hydroxyl groups and mixtures thereof; at least one base; optionally, an emulsifying agent; and a sufficient amount of water to form an aqueous phase emulsion comprising from about 10-50% of solid materials. The emulsion is formed by combining the polyolefin with the fatty acid at a temperature higher than the melting point of the polyolefin to form a first mixture, adding to the first mixture a sufficient amount of base to neutralize the polyolefin and the fatty acid together with the water and optionally the emulsifying agent to form a second mixture; stirring the second mixture at an elevated pressure and at a temperature above the melting point of the polyolefin and subsequently cooling the mixture to a temperature below the melting point of the polyolefin. The emulsion is particularly useful as a component of a sizing for coating and protecting glass fibers for reinforcing polymeric materials.
    • 一种用于形成用于处理基材表面的施胶涂层的水性乳液。 乳液包含至少一种重均分子量大于10,000的聚烯烃; 选自饱和脂肪酸,不包括任何羟基的不饱和脂肪酸及其混合物的酸性物质; 至少一个基地; 任选的乳化剂; 和足够量的水以形成包含约10-50%的固体材料的水相乳液。 通过在高于聚烯烃熔点的温度下将聚烯烃与脂肪酸组合形成第一混合物形成乳液,向第一混合物中加入足量的碱以中和聚烯烃和脂肪酸 水和任选的乳化剂以形成第二混合物; 在升高的压力和高于聚烯烃熔点的温度下搅拌第二混合物,随后将混合物冷却到低于聚烯烃熔点的温度。 该乳液特别可用作用于涂覆和保护用于增强聚合材料的玻璃纤维的施胶剂的组分。